about
P185
IrII(ethene): metal or carbon radical?Molecular and Electronic Structures of Bis(pyridine-2,6-diimine)metal Complexes [ML2](PF6)n(n= 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)†Redox Noninnocence of Carbene Ligands: Carbene Radicals in (Catalytic) C−C Bond FormationLigand-centred reactivity of bis(picolyl)amine iridium: sequential deprotonation, oxidation and oxygenation of a "non-innocent" ligand.Rhodium(0) metalloradicals in binuclear C-H activation.Experimental evidence for cobalt(III)-carbene radicals: key intermediates in cobalt(II)-based metalloradical cyclopropanation.Unraveling the electronic structures of low-valent naphthalene and anthracene iron complexes: X-ray, spectroscopic, and density functional theory studies.Exchange of organic radicals with organo-cobalt complexes formed in the living radical polymerization of vinyl acetate.Hydrogen-atom transfer in reactions of organic radicals with [Co(II)(por)]* (por = porphyrinato) and in subsequent addition of [Co(H)(por)] to olefins.Electromeric rhodium radical complexes.Carbene radicals in cobalt(II)-porphyrin-catalysed carbene carbonylation reactions; a catalytic approach to ketenes.Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species.Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions.Reactivity of a Ruthenium-Carbonyl Complex in the Methanol Dehydrogenation Reaction.Metalloradical approach to 2H-chromenes.C1 polymerisation and related C-C bond forming 'carbene insertion' reactions.Synthesis of functional 'polyolefins': state of the art and remaining challenges.Complexes with nitrogen-centered radical ligands: classification, spectroscopic features, reactivity, and catalytic applications.Transition metal catalysis in confined spaces.Transition Metal-Free Cleavage of CO.Homogeneously catalysed conversion of aqueous formaldehyde to H2 and carbonate.Electronic Structure and Magnetic Anisotropy of an Unsaturated Cyclopentadienyl Iron(I) Complex with 15 Valence Electrons.Catalytic Synthesis of N-Heterocycles via Direct C(sp3)-H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand.A Stable Aminyl Radical Coordinated to Cobalt.Metal-Catalysed Azidation of Organic MoleculesReversible Redox Chemistry and Catalytic C(sp(3))-H Amination Reactivity of a Paramagnetic Pd Complex Bearing a Redox-Active o-Aminophenol-Derived NNO Pincer Ligand.Cobalt-Porphyrin-Catalysed Intramolecular Ring-Closing C-H Amination of Aliphatic Azides: A Nitrene-Radical Approach to Saturated Heterocycles.[Ni(cod)2][Al(OR(F))4], a Source for Naked Nickel(I) ChemistrySelective Co-Encapsulation Inside an M6 L4 Cage.Diastereoselective Radical-Type Cyclopropanation of Electron-Deficient Alkenes Mediated by the Highly Active Cobalt(II) Tetramethyltetraaza[14]annulene Catalyst.Hydrogen-atom transfer in open-shell organometallic chemistry: the reactivity of Rh(II)(cod) and Ir(II)(cod) radicals.Carbon-carbon bond activation of 2,2,6,6-tetramethyl-piperidine-1-oxyl by a Rh(II) metalloradical: a combined experimental and theoretical study.Metalloradical Reactivity of RuI and Ru0 Stabilized by an Indole-Based Tripodal Tetraphosphine Ligand.Homoleptic diphosphacyclobutadiene complexes [M(η(4)-P2C2R2)2]x- (M = Fe, Co; x = 0, 1).'Carbene radicals' in Co(II)(por)-catalyzed olefin cyclopropanation.Versatile new C(3)-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu(I) and Rh(I) species and tune their reactivity.Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine-phosphonite rhodium complexes.Nitrene Radical Intermediates in Catalytic Synthesis.Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions.Ligand-controlled magnetic interactions in Mn(4) clusters.
P50
Q28306569-E102B2DA-A126-43CD-8C0B-4D5126078355Q29999036-B090312C-3F2F-4FA1-B425-302434621EBEQ30051819-64B8E41E-8CA4-4AC4-9EE8-A59DA1E4CED6Q33507576-D9F62125-CD3B-4CC9-A21B-51A00598CC6DQ34087375-391DA9F3-71CA-4B2E-A8F8-D1B19FA588AEQ34184471-097CAE52-B5AE-4567-9DCD-D5DF76717561Q34284232-A576D31D-5321-4105-B1F8-E7EC4330ADE6Q34824415-506A8D62-E98F-4EDE-AA6F-7502BAF3392AQ34957986-3C23D065-6B31-48A7-863B-10D3825B2720Q35015810-C4AD6AB9-8D36-45E6-A5C5-DFD837C671C7Q35153979-6CEED725-1748-4DC5-A67E-B93BAE63E881Q36134408-A1664FD4-2177-4A17-B990-8CE518BEFD89Q36570787-D6669C51-45EE-4C8D-98CC-2D0A02A7BAF1Q37456346-0BA87CE0-A0C0-4819-8419-D252F947F4A1Q37605771-518C095A-EE7F-4C6E-80B7-3EC46BFF9F8CQ37737103-EAFAB8ED-3EB4-4DC4-BC46-AA4A5B13E56AQ38100063-5DC16183-5EB6-4ECC-B63A-62AED33A7198Q38161491-C9FEB453-7449-4194-9166-1A5CE7B68B68Q38262226-6EF0F9A2-9E98-4B88-BCF9-56D9F01C632FQ38620616-7593C0B2-A7AE-430F-985E-7ACB82381539Q38689874-B3ECBB74-D0A6-4AC9-AC7C-BB51102880C5Q38756865-DEBA0FA0-BC90-4D3A-9BD1-9DBE944119C0Q38905373-DB619BB2-C602-423C-8E60-BAB5A4D3510AQ38977495-0B683626-9608-47BF-B0BF-6D6D2E45FA34Q39201456-C699DC0D-0C5B-4D09-BC61-A23A17A285A3Q39489772-5102D846-89B1-4176-8D6C-2ABD2FF62B2DQ41019640-EECA4BC7-1387-46AA-A3B7-26AE1C8EB260Q41155274-379C4795-698B-483B-9521-EE9737A4581FQ41675480-5FE83E15-65FC-42CC-8B01-5F646A7E5D9EQ42271761-EF3CBC05-6E5D-4D80-8961-CF017E33AAA6Q42608773-F2EBA863-68F0-4BD1-ADE3-8C8CDAFFC040Q42642831-8D1DA6DE-6EE3-42BF-BEA0-FD88EE7804A5Q42702418-257B359D-AAEB-4CCF-A380-185D41138EEDQ42787649-CCAA9B1F-5D96-4FEE-A6DF-A3A4958A85CDQ42948136-E0752756-7F4D-4AA1-8FA0-72EEFEEFCF0BQ43019063-6527807C-0D2C-47D5-AA79-DB6D50A794D0Q43070746-522BA5A5-83CC-4B3F-9797-F334EDDE21C6Q43129522-9700AAF7-1C8B-4FD0-8E05-BB24A79CD5BCQ43165821-5A210D5A-044F-4A65-9593-ED3C6ED00473Q43241450-D0622258-2415-478B-9753-58CA8CE630FC
P50
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Nederlands onderzoeker
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Bas de Bruin
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Bas de Bruin
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Bas de Bruin
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0000-0002-3482-7669
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1971-04-21T00:00:00Z
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viaf-282649436