about
Sc3CH@C80: selective (13)C enrichment of the central carbon atomSelf-assembly of endohedral metallofullerenes: a decisive role of cooling gas and metal-carbon bondingFullerene "superhalogen" radicals: the substituent effect on electronic properties of 1,7,11,24,27-C60X5.Synthesis, characterization, and theoretical study of stable isomers of C70(CF3)n (n = 2, 4, 6, 8, 10).Single-step gas-phase polyperfluoroalkylation of naphthalene leads to thermodynamic products.Synthesis, isolation, and spectroscopic characterization of holmium-based mixed-metal nitride clusterfullerenes: HoxSc3-xN@C80 (x=1, 2).Perfluoroalkylfullerenes.Methane as a Selectivity Booster in the Arc-Discharge Synthesis of Endohedral Fullerenes: Selective Synthesis of the Single-Molecule Magnet Dy2TiC@C80 and Its Congener Dy2TiC2@C80.(19)F NMR-, ESR-, and vis-NIR-spectroelectrochemical study of the unconventional reduction behaviour of a perfluoroalkylated fullerene: dimerization of the C70(CF3)10(-) radical anionMononuclear Clusterfullerene Single-Molecule Magnet Containing Strained Fused-Pentagons Stabilized by a Nearly Linear Metal Cyanide Cluster.Gd-Sc-based mixed-metal nitride cluster fullerenes: mutual influence of the cage and cluster size and the role of scandium in the electronic structure.Topological signatures in the electronic structure of graphene spirals.(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B-H Activation at a Single Metal Center.Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes-Sc2 TiC@Ih -C80 , Sc2 TiC@D5h -C80 and Sc2 TiC2 @Ih -C80 : Metal Size Tuning of the Ti(IV) /Ti(III) Redox Potentials.Growth of all-carbon horizontally aligned single-walled carbon nanotubes nucleated from fullerene-based structures.A platform for specific delivery of lanthanide-scandium mixed-metal cluster fullerenes into target cells.Rapid reversible borane to boryl hydride exchange by metal shuttling on the carborane cluster surface.Photoelectron spectroscopy of C60Fn- and C60Fm2- (n = 17, 33, 35, 43, 45, 47; m = 34, 46) in the gas phase and the generation and characterization of C1-C60F47- and D2-C60F44 in solution.Direct perfluorination of K(2)B(12)H(12) in acetonitrile occurs at the gas bubble-solution interface and is inhibited by HF. Experimental and DFT study of inhibition by protic acids and soft, polarizable anions.A faux hawk fullerene with PCBM-like properties.The extended view on the empty C2(3)-C82 fullerene: isolation, spectroscopic, electrochemical, and spectroelectrochemical characterization and DFT calculations.Synthesis and X-ray or NMR/DFT structure elucidation of twenty-one new trifluoromethyl derivatives of soluble cage isomers of C76, C78, C84, and C90.Endohedral fullerene with μ3-carbido ligand and titanium-carbon double bond stabilized inside a carbon cage.Understanding mechanochemical coupling in kinesins using first-passage-time processes.Seven-minute synthesis of pure C(s)-C60Cl6 from [60]fullerene and iodine monochloride: first IR, Raman, and mass spectra of 99 mol % C60Cl6.Cluster-size dependent internal dynamics and magnetic anisotropy of Ho ions in HoM2N@C80 and Ho2MN@C80 families (M = Sc, Lu, Y).Soluble chlorofullerenes C(60)Cl(2,4,6,8,10). Synthesis, purification, compositional analysis, stability, and experimental/theoretical structure elucidation, including the X-ray structure of C(1)-C(60)Cl(10).Endohedral metal or a fullerene cage based oxidation? Redox duality of nitride clusterfullerenes Ce(x)M(3-x)N@C(78-88) (x = 1, 2; M = Sc and Y) dictated by the encaged metals and the carbon cage size.Synthesis and structure of Ag(1-Me-12-SiPh3-CB11F10): selective F12 substitution in 1-Me-CB11F11- and the first Ag(arene)4+ tetrahedron.Thermally Activated Delayed Fluorescence in a Y3 N@C80 Endohedral Fullerene: Time-Resolved Luminescence and EPR Studies.Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-Ih.C78 cage isomerism defined by trimetallic nitride cluster size: a computational and vibrational spectroscopic study.An expanded family of dysprosium-scandium mixed-metal nitride clusterfullerenes: the role of the lanthanide metal on the carbon cage size distribution.Experimental and DFT Studies of the Electron-Withdrawing Ability of Perfluoroalkyl (RF ) Groups: Electron Affinities of PAH(RF )n Increase Significantly with Increasing RF Chain Length.Nanoscale x-ray investigation of magnetic metallofullerene peapods.Interplay of spin-dependent delocalization and magnetic anisotropy in the ground and excited states of [Gd2@C78]- and [Gd2@C80].π-Extended and Curved Antiaromatic Polycyclic Hydrocarbons.Copper Causes Regiospecific Formation of C4 F8 -Containing Six-Membered Rings and their Defluorination/Aromatization to C4 F4 -Containing Rings in Triphenylene/1,4-C4 F8 I2 Reactions.Magnetic anisotropy of endohedral lanthanide ions: paramagnetic NMR study of MSc2N@C80-Ih with M running through the whole 4f row.ESR-Vis/NIR spectroelectrochemical study of C70(CF3)2-(*) and C70(C2F5)2-(*) radical anions.
P50
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P50
description
hulumtues
@sq
researcher
@en
wetenschapper
@nl
հետազոտող
@hy
name
Alexey A. Popov
@ast
Alexey A. Popov
@en
Alexey A. Popov
@es
Alexey A. Popov
@nl
type
label
Alexey A. Popov
@ast
Alexey A. Popov
@en
Alexey A. Popov
@es
Alexey A. Popov
@nl
prefLabel
Alexey A. Popov
@ast
Alexey A. Popov
@en
Alexey A. Popov
@es
Alexey A. Popov
@nl
P1053
A-9937-2011
P106
P1153
7402986391
P21
P31
P3829
P496
0000-0002-7596-0378