Calculations predict a large inverse H/D kinetic isotope effect on the rate of tunneling in the ring opening of cyclopropylcarbinyl radical.
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Kinetic isotope effects in asymmetric reactionsAtom Tunneling in Chemistry.Investigating inner-sphere reorganization via secondary kinetic isotope effects in the C-H cleavage reaction catalyzed by soybean lipoxygenase: tunneling in the substrate backbone as well as the transferred hydrogen.Der Tunneleffekt von Atomen in der Chemie
P2860
Calculations predict a large inverse H/D kinetic isotope effect on the rate of tunneling in the ring opening of cyclopropylcarbinyl radical.
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Calculations predict a large i ...... f cyclopropylcarbinyl radical.
@en
Calculations predict a large i ...... f cyclopropylcarbinyl radical.
@nl
type
label
Calculations predict a large i ...... f cyclopropylcarbinyl radical.
@en
Calculations predict a large i ...... f cyclopropylcarbinyl radical.
@nl
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Calculations predict a large i ...... f cyclopropylcarbinyl radical.
@en
Calculations predict a large i ...... f cyclopropylcarbinyl radical.
@nl
P2093
P356
P1476
Calculations predict a large i ...... f cyclopropylcarbinyl radical.
@en
P2093
David A Hrovat
Weston Thatcher Borden
P304
16002-16003
P356
10.1021/JA907406Q
P407
P50
P577
2009-11-01T00:00:00Z