Insertion of molecular oxygen into a palladium(II) methyl bond: a radical chain mechanism involving palladium(III) intermediates.

Insertion of molecular oxygen into a palladium(II) methyl bond: a radical chain mechanism involving palladium(III) intermediates.

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http://www.wikidata.org/entity/Q43261642
Palladium(III) in Synthesis and Catalysis.Palladium-Catalyzed Aerobic Acetoxylation of Benzene using NOx-Based Redox Mediators.C-H oxidation by platinum group metal oxo or peroxo species.Methyl Complexes of the Transition Metals.A Cyclization/Oxygenation Scheme for the Conversion of Polyenes into C3-Oxygenated Polycycles.Mechanism of the Stereoselective α-Alkylation of Aldehydes Driven by the Photochemical Activity of Enamines.Mechanistic examination of aerobic Pt oxidation: insertion of molecular oxygen into Pt-H bonds through a radical chain mechanism.Rhodium-Mediated Oxygenation of Nitriles with Dioxygen: Isolation of Rhodium Derivatives of Peroxyimidic Acids.Oxygenation of a benzyl ligand in SNS-palladium complexes with O2: acceleration by anions or Brønsted acids.Divergent reactivity of platinum(ii) and palladium(ii) methylperoxo complexes and the formation of an unusual hemi-aminal complex.A DFT-based mechanistic proposal for the light-driven insertion of dioxygen into Pt(ii)–C bonds† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc01161c.
P2860

Insertion of molecular oxygen into a palladium(II) methyl bond: a radical chain mechanism involving palladium(III) intermediates.

Item
http://www.wikidata.org/entity/Q43261642
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
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2009年学术文章
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2009年学术文章
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2009年学术文章
@zh-hans
2009年学术文章
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2009年学术文章
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2009年學術文章
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name
Insertion of molecular oxygen ...... palladium(III) intermediates.
@en
type
label
Insertion of molecular oxygen ...... palladium(III) intermediates.
@en
prefLabel
Insertion of molecular oxygen ...... palladium(III) intermediates.
@en
P1433
P1476
P2093
P304
P31
P356
P407
P433
P478
P577
P698
P356
P1433
P1476
Insertion of molecular oxygen ...... palladium(III) intermediates.
@en
P2093
P304
P31
P356
P407
P433
P478
P577
P698