Mechanism of N-fluorobenzenesulfonimide promoted diamination and carboamination reactions: divergent reactivity of a Pd(IV) species.
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Cu(I)-catalyzed regioselective diamination of conjugated dienes via dual mechanistic pathways.Complementary regioselectivity in the Cu(I)-catalyzed diamination of conjugated dienes to form cyclic sulfamidesEvolution of copper(II) as a new alkene amination promoter and catalyst.Copper-promoted and copper-catalyzed intermolecular alkene diaminationCu(I)-catalyzed sequential diamination and dehydrogenation of terminal olefins: a facile approach to imidazolinones.Catalytic diamination of olefins via N-N bond activation.Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.C-H bond activation at palladium(IV) centers.Cu(I)-catalyzed diamination of conjugated dienes. Complementary regioselectivity from two distinct mechanistic pathways involving Cu(II) and Cu(III) species.Pd(II)-catalyzed para-selective C-H arylation of monosubstituted arenes.Combined oxypalladation/C-H functionalization: palladium(II)-catalyzed intramolecular oxidative oxyarylation of hydroxyalkenes.Copper-catalyzed intramolecular alkene carboetherification: synthesis of fused-ring and bridged-ring tetrahydrofurans.Enantioselective diamination with novel chiral hypervalent iodine catalysts.Catalytic asymmetric synthesis of cyclic sulfamides from conjugated dienesPalladium-catalyzed intermolecular aminoacetoxylation of alkenes and the influence of PhI(OAc)2 on aminopalladation stereoselectivityPalladium-catalyzed C-H functionalization using guanidine as a directing group: ortho arylation and olefination of arylguanidines.Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis.Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications.Methods for direct alkene diamination, new & old.Recent Developments in Pd-Catalyzed Alkene Aminoarylation Reactions for the Synthesis of Nitrogen HeterocyclesVersatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization.The syn/anti-dichotomy in the palladium-catalyzed addition of nucleophiles to alkenes.Carbon-Hydrogen (C-H) Bond Activation at Pd(IV): A Frontier in C-H Functionalization Catalysis.Reversible alkene insertion into the Pd-N bond of Pd(II)-sulfonamidates and implications for catalytic amidation reactions.Intercepting Wacker intermediates with arenes: C-H functionalization and dearomatizationUse of aryl chlorides as electrophiles in Pd-catalyzed alkene difunctionalization reactions.Pd-catalyzed carboamination of oxazolidin-2-ones: a stereoselective route to trans-2,5-disubstituted pyrrolidines.Reconciling the stereochemical course of nucleopalladation with the development of enantioselective wacker-type cyclizations.Stereocontrolled synthesis of bicyclic sulfamides via Pd-catalyzed alkene carboamination reactions. Control of 1,3-asymmetric induction by manipulating mechanistic pathways.Recent developments in the use of aza-Heck cyclizations for the synthesis of chiral N-heterocycles.Mechanistic studies of Wacker-type amidocyclization of alkenes catalyzed by (IMes)Pd(TFA)2(H2O): kinetic and stereochemical implications of proton transfer.Gold-catalyzed three-component coupling: oxidative oxyarylation of alkenes.Gold-catalyzed intramolecular aminoarylation of alkenes: C-C bond formation through bimolecular reductive elimination.Palladium-Catalyzed Intra- and Intermolecular C-H Arylation Using Mesylates: Synthetic Scope and Mechanistic Studies.Palladium-Catalyzed Alkene Carboamination Reactions of Electron-Poor Nitrogen NucleophilesSteric Crowding Makes Challenging C(sp3)-F Reductive Eliminations Feasible.Asymmetric chiral ligand-directed alkene dioxygenation.Palladium-catalyzed oxidative arylhalogenation of alkenes: synthetic scope and mechanistic insights.Charge-transfer-directed radical substitution enables para-selective C-H functionalization.Stereoselective synthesis of cis-2,5-disubstituted pyrrolidines via Wacker-type aerobic oxidative cyclization of alkenes with tert-butanesulfinamide nucleophiles.
P2860
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P2860
Mechanism of N-fluorobenzenesulfonimide promoted diamination and carboamination reactions: divergent reactivity of a Pd(IV) species.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
@wuu
2009年学术文章
@zh
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
@zh-hant
name
Mechanism of N-fluorobenzenesu ...... : divergent reactivity of a Pd
@nl
Mechanism of N-fluorobenzenesu ...... eactivity of a Pd(IV) species.
@en
type
label
Mechanism of N-fluorobenzenesu ...... : divergent reactivity of a Pd
@nl
Mechanism of N-fluorobenzenesu ...... eactivity of a Pd(IV) species.
@en
prefLabel
Mechanism of N-fluorobenzenesu ...... : divergent reactivity of a Pd
@nl
Mechanism of N-fluorobenzenesu ...... eactivity of a Pd(IV) species.
@en
P2093
P356
P1476
Mechanism of N-fluorobenzenesu ...... eactivity of a Pd(IV) species.
@en
P2093
Carolyn F Rosewall
Paul A Sibbald
Rodney D Swartz
P304
15945-15951
P356
10.1021/JA906915W
P407
P577
2009-11-01T00:00:00Z