Monoiron hydrogenase catalysis: hydrogen activation with the formation of a dihydrogen, Fe-H(delta-)...H(delta+)-O, bond and methenyl-H4MPT+ triggered hydride transfer.
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Crystal structures of [Fe]-hydrogenase in complex with inhibitory isocyanides: implications for the H2-activation siteFe-H/D stretching and bending modes in nuclear resonant vibrational, Raman and infrared spectroscopies: comparisons of density functional theory and experiment.Regioselectivity of H cluster oxidation.Iron acyl thiolato carbonyls: structural models for the active site of the [Fe]-hydrogenase (Hmd).Formation of Gas-Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions.Amidine dications as superelectrophilesRadical SAM-dependent carbon insertion into the nitrogenase M-clusterHydrogen tunneling in enzymes and biomimetic models.Evolution in the understanding of [Fe]-hydrogenase.Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.Mechanistic Insights and Computational Design of Transition-Metal Catalysts for Hydrogenation and Dehydrogenation Reactions.An iron(II) carbonyl thiolato complex bearing 2-methoxy-pyridine: a structural model of the active site of [Fe] hydrogenase.Ferracyclic carbamoyl complexes related to the active site of [Fe]-hydrogenase.Computational Design of Iron Diphosphine Complexes with Pendant Amines for Hydrogenation of CO2 to Methanol: A Mimic of [NiFe] Hydrogenase.Bio-inspired computational design of iron catalysts for the hydrogenation of carbon dioxide.Effect of the ortho-Hydroxyl Groups on a Bipyridine Ligand of Iridium Complexes for the High-Pressure Gas Generation from the Catalytic Decomposition of Formic Acid.Reconstitution of [Fe]-hydrogenase using model complexes.Z-H Bond Activation in (Di)hydrogen Bonding as a Way to Proton/Hydride Transfer and H2 Evolution.Reversible dimerization of mononuclear models of [Fe]-hydrogenase.Ruthenium complexes bearing an unsymmetrical pincer ligand with a 2-hydroxypyridylmethylene fragment: active catalysts for transfer hydrogenation of ketones.Toward functional type III [Fe]-hydrogenase biomimics for H2 activation: insights from computation.Nitrogen heterocyclic carbene containing pentacoordinate iron dicarbonyl as a [Fe]-hydrogenase active site model.Unusual non-bifunctional mechanism for Co-PNP complex catalyzed transfer hydrogenation governed by the electronic configuration of metal center.Substitution reactions of iron(ii) carbamoyl-thioether complexes related to mono-iron hydrogenase.Structural and functional synthetic model of mono-iron hydrogenase featuring an anthracene scaffold.Synthesis and reactivity of mononuclear iron models of [Fe]-hydrogenase that contain an acylmethylpyridinol ligand.Hydrogen-activation mechanism of [Fe] hydrogenase revealed by multi-scale modelingHydrogenases and oxygenAn enquiry into theoretical bioinorganic chemistry: How heuristic is the character of present-day quantum chemical methods?Oxygen Coordination to the Active Site of Hmd in Relation to [FeFe] Hydrogenase
P2860
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P2860
Monoiron hydrogenase catalysis: hydrogen activation with the formation of a dihydrogen, Fe-H(delta-)...H(delta+)-O, bond and methenyl-H4MPT+ triggered hydride transfer.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
@wuu
2009年学术文章
@zh
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
@zh-hant
name
Monoiron hydrogenase catalysis ...... T+ triggered hydride transfer.
@en
Monoiron hydrogenase catalysis ...... T+ triggered hydride transfer.
@nl
type
label
Monoiron hydrogenase catalysis ...... T+ triggered hydride transfer.
@en
Monoiron hydrogenase catalysis ...... T+ triggered hydride transfer.
@nl
prefLabel
Monoiron hydrogenase catalysis ...... T+ triggered hydride transfer.
@en
Monoiron hydrogenase catalysis ...... T+ triggered hydride transfer.
@nl
P356
P1476
Monoiron hydrogenase catalysis ...... T+ triggered hydride transfer.
@en
P2093
Xinzheng Yang
P304
10901-10908
P356
10.1021/JA902689N
P407
P577
2009-08-01T00:00:00Z