A cyclic germadicarbene ("germylone") from germyliumylidene.
about
The IX (X=O,N,C) Double Bond in Hypervalent Iodine Compounds: Is it Real?Can low-valent germanium chemistry be practiced under ambient conditions? A tale of a water-stable yet reactive germylene monochloride complex.Donor-acceptor chemistry in the main group.Reactive p-block cations stabilized by weakly coordinating anions.Cations and dications of heavier group 14 elements in low oxidation states.Taming Silicon Congeners of CO and CO2 : Synthesis of Monomeric SiII and SiIV Chalcogenide Complexes.Unique molecular geometries of reduced 4- and 5-coordinate zinc complexes stabilised by diiminopyridine ligand.Design, Synthesis, and Structural Analysis of Divalent N(I) Compounds and Identification of a New Electron-Donating Ligand.The role of 2,6-diaminopyridine ligands in the isolation of an unprecedented, low-valent tin complex.The first bismuth-NHC complexes.Recent advances in the field of main-group mono- and diatomic "allotropes" stabilised by neutral ligands.Dative bonds in main-group compounds: a case for fewer arrows!A coordination compound of Ge(0) stabilized by a diiminopyridine ligand.Carbones as Ligands in Novel Main-Group Compounds E[C(NHC)2 ]2 (E=Be, B+ , C2+ , N3+ , Mg, Al+ , Si2+ , P3+ ): A Theoretical Study.The fate of NHC-stabilized dicarbon.A multiply functionalized base-coordinated Ge(II) compound and its reversible dimerization to the digermene.Isolation of an imino-N-heterocyclic carbene/germanium(0) adduct: a mesoionic germylene equivalent.Silavinylidene stabilized by an N-heterocyclic carbene: a theoretically predicted stable molecule.Ligand-Supported E3 Clusters (E=Si-Sn).Bonding in Heavier Group 14 Zero-Valent Complexes-A Combined Maximum Probability Domain and Valence Bond Theory Approach.Isolation and Structure of Germylene-Germyliumylidenes Stabilized by N-Heterocyclic Imines.Unexpected Photodegradation of a Phosphaketenyl-Substituted Germyliumylidene Borate Complex.Highly Bent 1,3-Digerma-2-silaallene.A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity.Reactivity of NHC Alane Adducts towards N-Heterocyclic Carbenes and Cyclic (Alkyl)(amino)carbenes: Ring Expansion, Ring Opening, and Al-H Bond Activation.One-Electron Oxidation of a Disilicon(0) Compound: An Experimental and Theoretical Study of [Si2](+) Trapped by N-Heterocyclic Carbenes.Synthesis, characterization, and electronic structures of a methyl germyliumylidene ion and germylone-group VI metal complexes.Synthesis and structural characterization of a C₄ cumulene including 4-pyridylidene units, and its reactivity towards ammonia-borane.Isolation of a germanium(II) cation and a germylene iron carbonyl complex utilizing an imidazolin-2-iminato ligand.Synthesis and structure of the azidogermyliumylidene azide complex [L(N3)Ge:](+)N3- with covalently and ionically bonded azide ligands at germanium(II) [L = bis(N-heterocyclic carbene)].A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom.Stabilization of heterodiatomic SiC through ligand donation: theoretical investigation of SiC(L)2 (L=NHC(Me) , CAAC(Me) , PMe3 ).Donor-acceptor bonding in novel low-coordinated compounds of boron and group-14 atoms C-Sn.Using N-Heterocyclic Vinyl Ligands to Access Stable Divinylgermylenes and a Germylium Cation.NHC-stabilized silagermenylidene: a heavier analogue of vinylidene.Anorganische Chemie 2013
P2860
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P2860
A cyclic germadicarbene ("germylone") from germyliumylidene.
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年学术文章
@wuu
2013年学术文章
@zh
2013年学术文章
@zh-cn
2013年学术文章
@zh-hans
2013年学术文章
@zh-my
2013年学术文章
@zh-sg
2013年學術文章
@yue
2013年學術文章
@zh-hant
name
A cyclic germadicarbene ("germylone") from germyliumylidene.
@en
A cyclic germadicarbene
@nl
type
label
A cyclic germadicarbene ("germylone") from germyliumylidene.
@en
A cyclic germadicarbene
@nl
prefLabel
A cyclic germadicarbene ("germylone") from germyliumylidene.
@en
A cyclic germadicarbene
@nl
P2093
P356
P1476
A cyclic germadicarbene ("germylone") from germyliumylidene.
@en
P2093
Gengwen Tan
Shenglai Yao
P304
P356
10.1021/JA402477W
P407
P577
2013-03-25T00:00:00Z