Reaction of [P(2)N(2)]Ta==CH(2)(Me) with ethylene: synthesis of [P(2)N(2)]Ta(C(2)H(4))Et, a neutral species with a beta-agostic ethyl group in equilibrium with an alpha-agostic ethyl group ([P(2)N(2)] = PhP(CH(2)SiMe(2)CH(2))(2)PPh).
about
Isolation of two agostic isomers of an organometallic cation: different structures and colors.Bis(imino)pyridine cobalt alkyl complexes and their reactivity towards ethylene: a model system for beta-hydrogen chain transfer.Synthesis and reactivity of Li and TaMe3 complexes supported by N,N'-bis(2,6-diisopropylphenyl)-o-phenylenediamido ligands.Reversible α-Hydrogen and α-Alkyl Elimination in PC(sp(3))P Pincer Complexes of Iridium.Group 5 Metal-Metal BondsGeneration and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium(iii) alkyls
P2860
Reaction of [P(2)N(2)]Ta==CH(2)(Me) with ethylene: synthesis of [P(2)N(2)]Ta(C(2)H(4))Et, a neutral species with a beta-agostic ethyl group in equilibrium with an alpha-agostic ethyl group ([P(2)N(2)] = PhP(CH(2)SiMe(2)CH(2))(2)PPh).
description
2001 nî lūn-bûn
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2001年の論文
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Reaction of [P(2)N(2)]Ta==CH(2 ...... PhP(CH(2)SiMe(2)CH(2))(2)PPh).
@en
Reaction of [P(2)N(2)]Ta==CH(2 ...... PhP(CH(2)SiMe(2)CH(2))(2)PPh).
@nl
type
label
Reaction of [P(2)N(2)]Ta==CH(2 ...... PhP(CH(2)SiMe(2)CH(2))(2)PPh).
@en
Reaction of [P(2)N(2)]Ta==CH(2 ...... PhP(CH(2)SiMe(2)CH(2))(2)PPh).
@nl
prefLabel
Reaction of [P(2)N(2)]Ta==CH(2 ...... PhP(CH(2)SiMe(2)CH(2))(2)PPh).
@en
Reaction of [P(2)N(2)]Ta==CH(2 ...... PhP(CH(2)SiMe(2)CH(2))(2)PPh).
@nl
P2093
P356
P1476
Reaction of [P(2)N(2)]Ta==CH(2 ...... PhP(CH(2)SiMe(2)CH(2))(2)PPh).
@en
P2093
P304
P356
10.1021/JA0021621
P407
P577
2001-02-01T00:00:00Z