A synthetically useful, self-assembling MMO mimic system for catalytic alkene epoxidation with aqueous H2O2.
about
The structure of the periplasmic nickel-binding protein NikA provides insights for artificial metalloenzyme designColorimetric high-throughput assay for alkene epoxidation catalyzed by cytochrome P450 BM-3 variant 139-3.A predictably selective aliphatic C-H oxidation reaction for complex molecule synthesis.Iron-catalyzed asymmetric epoxidation of β,β-disubstituted enonesModular chemical mechanism predicts spatiotemporal dynamics of initiation in the complex network of hemostasis.Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): structure, magnetic properties, and catalytic oxidation studies.Cafestol to Tricalysiolide B and Oxidized Analogues: Biosynthetic and Derivatization Studies Using Non-heme Iron Catalyst Fe(PDP).Using chemistry and microfluidics to understand the spatial dynamics of complex biological networks.Modeling the syn disposition of nitrogen donors in non-heme diiron enzymes. Synthesis, characterization, and hydrogen peroxide reactivity of diiron(III) complexes with the syn N-donor ligand H2BPG2DEV.Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.Regio- and stereoselective monoepoxidation of dienes using methyltrioxorhenium: synthesis of allylic epoxidesRegio- and enantioselective catalytic monoepoxidation of conjugated dienes: synthesis of chiral allylic cis-epoxides.A dynamic supramolecular system exhibiting substrate selectivity in the catalytic epoxidation of olefins.Highly selective epoxidation of styrene using a transition metal-aluminium(III) complex containing the [MeAl(2-py)3]- anion (2-py = 2-pyridyl).Manganese complex-catalyzed oxidation and oxidative kinetic resolution of secondary alcohols by hydrogen peroxide.Equilibrating (L)FeIII-OOAc and (L)FeV(O) Species in Hydrocarbon Oxidations by Bio-Inspired Nonheme Iron Catalysts Using H2O2 and AcOH.Synthesis, Characterization, and Efficient Catalytic Activities of a Nickel(II) Porphyrin: Remarkable Solvent and Substrate Effects on Participation of Multiple Active Oxidants.DFT studies of the substituent effects of dimethylamino on non-heme active oxidizing species: iron(V)-oxo species or iron(IV)-oxo acetate aminopyridine cation radical species?Synthesis, characterization, and catalytic activities of nickel(II) monoamido-tetradentate complex: Evidence for NiIII-Oxo and NiIV-Oxo species.Non-heme μ-Oxo- and bis(μ-carboxylato)-bridged diiron(iii) complexes of a 3N ligand as catalysts for alkane hydroxylation: stereoelectronic factors of carboxylate bridges determine the catalytic efficiency.Exceedingly Fast Oxygen Atom Transfer to Olefins via a Catalytically Competent Nonheme Iron Species.A discrete {Co4(μ3-OH)4}(4+) cluster with an oxygen-rich coordination environment as a catalyst for the epoxidation of various olefins.ortho-Hydroxylation of aromatic acids by a non-heme Fe(V)=O species: how important is the ligand design?H2O2 activation with biomimetic non-haem iron complexes and AcOH: connecting the g = 2.7 EPR signal with a visible chromophore.Making Fe(BPBP)-catalyzed C-H and C[double bond, length as m-dash]C oxidations more affordable.Identification of a low-spin acylperoxoiron(III) intermediate in bio-inspired non-heme iron-catalysed oxidations.A Bottom Up Approach Towards Artificial Oxygenases by Combining Iron Coordination Complexes and Peptides.Dinuclear Iron(III) and Nickel(II) Complexes Containing N-(2-Pyridylmethyl)-N'-(2-hydroxyethyl)ethylenediamine: Catalytic Oxidation and Magnetic Properties.Trinuclear nickel and cobalt complexes containing unsymmetrical tripodal tetradentate ligands: syntheses, structural, magnetic, and catalytic properties.Switching on oxygen activation by cobalt complexes of pentadentate ligands.Synthesis and oxidation catalysis of a Ti-substituted phosphotungstate, and identification of the active oxygen speciesThe Iron(II) Complex [Fe(CF3SO3)2(mcp)] as a Convenient, Readily Available Catalyst for the Selective Oxidation of Methylenic Sites in AlkanesAn Iron Catalyst for Oxidation of Alkyl CH Bonds Showing Enhanced Selectivity for Methylenic SitesBioinspired Oxidations Catalyzed by Nonheme Iron and Manganese Complexes
P2860
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P2860
A synthetically useful, self-assembling MMO mimic system for catalytic alkene epoxidation with aqueous H2O2.
description
2001 nî lūn-bûn
@nan
2001年の論文
@ja
2001年学术文章
@wuu
2001年学术文章
@zh
2001年学术文章
@zh-cn
2001年学术文章
@zh-hans
2001年学术文章
@zh-my
2001年学术文章
@zh-sg
2001年學術文章
@yue
2001年學術文章
@zh-hant
name
A synthetically useful, self-a ...... epoxidation with aqueous H2O2.
@en
A synthetically useful, self-a ...... epoxidation with aqueous H2O2.
@nl
type
label
A synthetically useful, self-a ...... epoxidation with aqueous H2O2.
@en
A synthetically useful, self-a ...... epoxidation with aqueous H2O2.
@nl
prefLabel
A synthetically useful, self-a ...... epoxidation with aqueous H2O2.
@en
A synthetically useful, self-a ...... epoxidation with aqueous H2O2.
@nl
P2093
P356
P1476
A synthetically useful, self-a ...... epoxidation with aqueous H2O2.
@en
P2093
P304
P356
10.1021/JA015884G
P407
P577
2001-07-01T00:00:00Z