Reference scales for the characterization of cationic electrophiles and neutral nucleophiles.
about
Powerful Bispyridinylidene Organic Reducing Agents with Iminophosphorano π-Donor Substituents.Electrophilicity versus electrofugality of tritylium ions in aqueous acetonitrile.Quantification of the Electrophilicity of Benzyne and Related Intermediates.Generation of α,β-unsaturated iminium ions by laser flash photolysis.Characterization of the nucleophilic reactivities of thiocarboxylate, dithiocarbonate and dithiocarbamate anions.The efficiency of the metal catalysts in the nucleophilic substitution of alcohols is dependent on the nucleophile and not on the electrophile.Divergent synthesis and chemical reactivity of bicyclic lactone fragments of complex rearranged spongian diterpenes.Concise total synthesis and stereochemical revision of (+)-naseseazines A and B: regioselective arylative dimerization of diketopiperazine alkaloidsReductions of aldehydes and ketones with a readily available N-heterocyclic carbene borane and acetic acidStereochemical control in the reduction of 2-chromanolsThe basicity of unsaturated hydrocarbons as probed by hydrogen-bond-acceptor ability: bifurcated N-H+ ...pi hydrogen bondingOxidative carbon-carbon bond formation via allyldimethylsilyl enol ethers.Farewell to the HSAB treatment of ambident reactivity.Effect of the leaving group and solvent combination on the LFER reaction constants.The coordination chemistry of organo-hydride donors: new prospects for efficient multi-electron reduction.Molecular strategies to prevent, inhibit, and degrade advanced glycoxidation and advanced lipoxidation end products.Synergy, compatibility, and innovation: merging Lewis acids with stereoselective enamine catalysis.Molecular features in complex environment: Cooperative team players during excited state bond cleavageReactivity-Tuning in Frustrated Lewis Pairs: Nucleophilicity and Lewis Basicity of Sterically Hindered Phosphines.A quantitative approach to polar organic reactivity.Enantioselective catalytic alpha-alkylation of aldehydes via an SN1 pathway.Cation clock permits distinction between the mechanisms of α- and β-O- and β-C-glycosylation in the mannopyranose series: evidence for the existence of a mannopyranosyl oxocarbenium ion.Cation affinity numbers of Lewis bases.Benzhydryl phenyl sulfone.Concise Total Synthesis of (+)-Asperazine, (+)-Pestalazine A, and (+)-iso-Pestalazine A. Structure Revision of (+)-Pestalazine A.A quantitative approach to nucleophilic organocatalysis.4,4'-Bis(dimethyl-amino)benzhydryl phenyl sulfone.Umpolung reactivity of indole through gold catalysis.Kinetic evidence for the formation of oxazolidinones in the stereogenic step of proline-catalyzed reactions.Organocatalytic stereoselective alpha-alkylation of aldehydes with stable carbocations.Organocatalysis by neutral multidentate halogen-bond donors.Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles.Electrophilic alkylations of vinylsilanes: a comparison of α- and β-silyl effects.Annelated pyridines as highly nucleophilic and Lewis basic catalysts for acylation reactions.Ambident reactivities of formaldehyde N,N-dialkylhydrazones.A comprehensive microscopic picture of the benzhydryl radical and cation photogeneration and interconversion through electron transfer.In Situ-Generated Glycinyl Chloroaminals for a One-Pot Synthesis of Non-proteinogenic α-Amino Esters.A DFT-based model for calculating solvolytic reactivity. The nucleofugality of aliphatic carboxylates in terms of Nf parameters.Single-electron-transfer (SET)-induced oxidative biaryl coupling by polyalkoxybenzene-derived diaryliodonium(III) salts.On the intrinsic reactivity index for electrophilicity/nucleophilicity responses.
P2860
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P2860
Reference scales for the characterization of cationic electrophiles and neutral nucleophiles.
description
2001 nî lūn-bûn
@nan
2001年の論文
@ja
2001年学术文章
@wuu
2001年学术文章
@zh
2001年学术文章
@zh-cn
2001年学术文章
@zh-hans
2001年学术文章
@zh-my
2001年学术文章
@zh-sg
2001年學術文章
@yue
2001年學術文章
@zh-hant
name
Reference scales for the chara ...... iles and neutral nucleophiles.
@en
Reference scales for the chara ...... iles and neutral nucleophiles.
@nl
type
label
Reference scales for the chara ...... iles and neutral nucleophiles.
@en
Reference scales for the chara ...... iles and neutral nucleophiles.
@nl
prefLabel
Reference scales for the chara ...... iles and neutral nucleophiles.
@en
Reference scales for the chara ...... iles and neutral nucleophiles.
@nl
P2093
P356
P1476
Reference scales for the chara ...... iles and neutral nucleophiles.
@en
P2093
Remennikov G
P304
P356
10.1021/JA010890Y
P407
P577
2001-10-01T00:00:00Z