A diruthenium catalyst for selective, intramolecular allylic C-H amination: reaction development and mechanistic insight gained through experiment and theory.
about
Copper-catalyzed oxidative amination and allylic amination of alkenes.Selective intermolecular amination of C-H bonds at tertiary carbon centers.Metal-catalyzed nitrogen-atom transfer methods for the oxidation of aliphatic C-H bonds.An expedient synthesis of maraviroc (UK-427,857) via C-H functionalization.Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom sourceMonoprotected l-Amino Acid (l-MPAA), Accelerated Bromination, Chlorination, and Iodination of C(sp2 )-H Bonds by Iridium(III) Catalysis.Catalytic enantioselective allylic amination of unactivated terminal olefins via an ene reaction/[2,3]-rearrangementIron(II) bromide-catalyzed intramolecular C-H bond amination [1,2]-shift tandem reactions of aryl azides.Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization.Tunable differentiation of tertiary C-H bonds in intramolecular transition metal-catalyzed nitrene transfer reactions.Evolution of C-H Bond Functionalization from Methane to MethodologyCarboxylate-assisted C(sp³)-H activation in olefin metathesis-relevant ruthenium complexes.A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp(3))-H amination.Intramolecular Radical Aziridination of Allylic Sulfamoyl Azides by Cobalt(II)-Based Metalloradical Catalysis: Effective Construction of Strained Heterobicyclic Structures.Tunable, chemoselective amination via silver catalysis.Chemoselective allene aziridination via Ag(I) catalysisMetal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and BenzenesA Highly Selective Vanadium Catalyst for Benzylic C-H Oxidation.Ligand-controlled, tunable silver-catalyzed C-H amination.Ru(II)-catalyzed intermolecular ortho-C-H amidation of aromatic ketones with sulfonyl azides.Ketimido metallophthalocyanines: an approach to phthalocyanine-supported mononuclear high-valent ruthenium complexes.Rhodium-Catalyzed Stereospecific C-H Amination for the Construction of Spiroaminal Cores: Reactivity Difference between Nitrenoid and Carbenoid Species against Amide Functionality.Mechanistic Insight into the Intramolecular Benzylic C-H Nitrene Insertion Catalyzed by Bimetallic Paddlewheel Complexes: Influence of the Metal Centers.Iodine-Catalyzed Decarboxylative Amidation of β,γ-Unsaturated Carboxylic Acids with Chloramine Salts Leading to Allylic Amides.Palladium-catalyzed oxidative allylation of bis[(pinacolato)boryl]methane: synthesis of homoallylic boronic esters.Manganese(iii) acetate catalyzed oxidative amination of benzylic C(sp3)-H bonds with nitriles.Tandem Oxidative Derivatization of Nitrene Insertion Products for the Highly Diastereoselective Synthesis of 1,3-aminoalcohols.Iron-Catalyzed Intramolecular Aminations of C(sp3 )-H Bonds in Alkylaryl Azides.Diastereoselective C-H Bond Amination for Disubstituted Pyrrolidines.Rhodium-Catalyzed Diastereoselective Cyclization of Allenyl-Sulfonylcarbamates: A Stereodivergent Approach to 1,3-Aminoalcohol Derivatives.Diruthenium(ii)-NNN pincer complex catalysts for transfer hydrogenation of ketones.Development of a Rhodium(II)-Catalyzed Chemoselective C(sp(3) )-H Oxygenation.Organocatalytic nitrenoid transfer: metal-free selective intermolecular C(sp3)-H amination catalyzed by an iminium salt.Stereoselective intermolecular C-H amination reactions.Efficient imidation of C(sp3)-H bonds adjacent to oxygen atoms of aryl ethers under metal-free conditions.N,N'-diamidocarbenes facilitate selective C-H insertions and transfer hydrogenations.Enantio- and regioselective intermolecular benzylic and allylic C-H bond amination.A Simple and Direct Method for the Palladium-Catalyzed Oxidative Coupling of Unactivated Allylarenes with Classic ArenesAlkali metal complexes of 6-methyl-2-pyridone: simple formulae, but not so simple structures
P2860
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P2860
A diruthenium catalyst for selective, intramolecular allylic C-H amination: reaction development and mechanistic insight gained through experiment and theory.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年学术文章
@wuu
2011年学术文章
@zh
2011年学术文章
@zh-cn
2011年学术文章
@zh-hans
2011年学术文章
@zh-my
2011年学术文章
@zh-sg
2011年學術文章
@yue
2011年學術文章
@zh-hant
name
A diruthenium catalyst for sel ...... through experiment and theory.
@en
A diruthenium catalyst for sel ...... through experiment and theory.
@nl
type
label
A diruthenium catalyst for sel ...... through experiment and theory.
@en
A diruthenium catalyst for sel ...... through experiment and theory.
@nl
prefLabel
A diruthenium catalyst for sel ...... through experiment and theory.
@en
A diruthenium catalyst for sel ...... through experiment and theory.
@nl
P2093
P356
P1476
A diruthenium catalyst for sel ...... through experiment and theory.
@en
P2093
Djamaladdin G Musaev
Mark Edwin Harvey
P304
17207-17216
P356
10.1021/JA203576P
P407
P577
2011-10-07T00:00:00Z