Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex.
about
Hydrogenations at room temperature and atmospheric pressure with mesoionic carbene-stabilized borenium catalysts.Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene.Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalystsStructurally Characterized Cationic Silver(I) and Ruthenium(II)carbene complexes of 1,2,3-Triazol-5-ylidenesStable cyclic carbenes and related species beyond diaminocarbenes.Beyond click chemistry - supramolecular interactions of 1,2,3-triazoles.Understanding the hydrogen bonds in ionic liquids and their roles in properties and reactions.Normal-to-Abnormal NHC Rearrangement of Al(III) , Ga(III) , and In(III) Trialkyl Complexes: Scope, Mechanism, Reactivity Studies, and H2 Activation.Phosphorescent Platinum(II) Complexes with Mesoionic 1H-1,2,3-Triazolylidene Ligands.A Brief Survey of our Contribution to Stable Carbene Chemistry.Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis.Rare-Earth- and Uranium-Mesoionic Carbenes: A New Class of f-Block Carbene Complex Derived from an N-Heterocyclic OlefinMesoionic thiazol-5-ylidenes as ligands for transition metal complexes.Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene.Insights into the carbene-initiated aggregation of [Fe(cot)(2)].Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs).A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene.Toward phenanthridin-2-ylidene: electrophilicity versus acidity in planar-constrained C-aryl iminium salts.Abnormal N-heterocyclic carbene main group organometallic chemistry: a debut to the homogeneous catalysis.Electronic structure trends in N-heterocyclic carbenes (NHCs) with varying number of nitrogen atoms and NHC-transition-metal bond properties.Unexpected oxidative C-C cleavage in the metallation of 2-substituted imidazolium salts to give N-heterocyclic carbene complexes.Designing the "search pathway" in the development of a new class of highly efficient stereoselective hydrosilylation catalysts.Stability and electronic properties of imidazole-based mesoionic carbenes.Fusing N-heterocyclic carbenes with carborane anions.Nickel-catalysed direct C2-arylation of N-heterocyclic carbenes.Exploring the Oxidative-Addition Pathways of Phenyl Chloride in the Presence of Pd(II) Abnormal N-Heterocyclic Carbene Complexes: A DFT Study.Platinum(II) and platinum(IV) complexes stabilized by abnormal/mesoionic C4-bound dicarbenes.Synthesis of unsymmetrical N-carboranyl NHCs: directing effect of the carborane anion.Iron(II) complexes of ditopic carbanionic carbenes.A comparative study on the N-heterocyclic carbene adducts of Ih-C60, D5h-C70 and Sc3N@Ih-C80.Calcium Hydride Reactivity: Formation of an Anionic N-Heterocyclic Olefin Ligand.Sequential Reactions of Alkynes on an Iridium(III) Single Site.Variable Reactivity of a N-Heterocyclic Phosphenium Complex: P-C Bond Activation or "Abnormal" Deprotonation.Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes.Small Molecule Activation with N,NR-MIC Platinum Complexes.1,3,2-Diazaborole-derived carbene complexes of boron.Palladium-catalyzed direct C2-arylation of an N-heterocyclic carbene: an atom-economic route to mesoionic carbene ligands.Coordination Behavior of a Planar Chiral Cyclic (Amino)(Ferrocenyl)Carbene Ligand in Iridium Complexes.Activation of C-F bonds in fluoroarenes by N-heterocyclic carbenes as an effective route to synthesize abnormal NHC complexes.Synthesis of Complexes with Abnormal "Protic" N-Heterocyclic Carbenes.
P2860
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P2860
Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex.
description
2001 nî lūn-bûn
@nan
2001年の論文
@ja
2001年学术文章
@wuu
2001年学术文章
@zh
2001年学术文章
@zh-cn
2001年学术文章
@zh-hans
2001年学术文章
@zh-my
2001年学术文章
@zh-sg
2001年學術文章
@yue
2001年學術文章
@zh-hant
name
Abnormal binding in a carbene ...... t and a metal hydride complex.
@en
Abnormal binding in a carbene ...... t and a metal hydride complex.
@nl
type
label
Abnormal binding in a carbene ...... t and a metal hydride complex.
@en
Abnormal binding in a carbene ...... t and a metal hydride complex.
@nl
prefLabel
Abnormal binding in a carbene ...... t and a metal hydride complex.
@en
Abnormal binding in a carbene ...... t and a metal hydride complex.
@nl
P2093
P356
P1476
Abnormal binding in a carbene ...... t and a metal hydride complex.
@en
P2093
Albrecht M
Crabtree RH
Gründemann S
Kovacevic A
P304
P356
10.1039/B107881J
P407
P577
2001-11-01T00:00:00Z