How constant are Ritchie's "constant selectivity relationships"? A general reactivity scale for n-, pi-, and sigma-nucleophiles.
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Cofactor mobility determines reaction outcome in the IMPDH and GMPR (β-α)8 barrel enzymesElectrophilicity versus electrofugality of tritylium ions in aqueous acetonitrile.Characterization of the nucleophilic reactivities of thiocarboxylate, dithiocarbonate and dithiocarbamate anions.Concerning the selective protection of (Z)-1,5-syn-ene-diols and (E)-1,5-anti-ene-diols as allylic triethylsilyl ethersThe basicity of unsaturated hydrocarbons as probed by hydrogen-bond-acceptor ability: bifurcated N-H+ ...pi hydrogen bondingFarewell to the HSAB treatment of ambident reactivity.The dynamic determinants of reaction specificity in the IMPDH/GMPR family of (β/α)(8) barrel enzymes.Reactivity-Tuning in Frustrated Lewis Pairs: Nucleophilicity and Lewis Basicity of Sterically Hindered Phosphines.A quantitative approach to polar organic reactivity.A DFT-based model for calculating solvolytic reactivity. The nucleofugality of aliphatic carboxylates in terms of Nf parameters.Solvation Accounts for the Counterintuitive Nucleophilicity Ordering of Peroxide Anions.Nucleophilicity of Alkyl Zirconocene and Titanocene Precatalysts, and Kinetics of Activation by Carbenium Ions and by B(C6 F5 )3.Structures, Lewis Acidities, Electrophilicities, and Protecting Group Abilities of Phenylfluorenylium and Tritylium Ions.Nucleophilicity parameters for amines, amino acids and peptides in water. Variations in selectivities for quinone methides.Limitations of the s(E+N) and related equations: solvent dependence of electrophilicity.Nucleophilicities and carbon basicities of pyridines.Solvatation als Ursache für die unerwartete Nucleophilie-Reihung von Peroxid-Anionen
P2860
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P2860
How constant are Ritchie's "constant selectivity relationships"? A general reactivity scale for n-, pi-, and sigma-nucleophiles.
description
2003 nî lūn-bûn
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2003年の論文
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2003年学术文章
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2003年学术文章
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2003年学术文章
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2003年学术文章
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name
How constant are Ritchie's "co ...... , pi-, and sigma-nucleophiles.
@en
How constant are Ritchie's "co ...... , pi-, and sigma-nucleophiles.
@nl
type
label
How constant are Ritchie's "co ...... , pi-, and sigma-nucleophiles.
@en
How constant are Ritchie's "co ...... , pi-, and sigma-nucleophiles.
@nl
prefLabel
How constant are Ritchie's "co ...... , pi-, and sigma-nucleophiles.
@en
How constant are Ritchie's "co ...... , pi-, and sigma-nucleophiles.
@nl
P356
P1476
How constant are Ritchie's "co ...... , pi-, and sigma-nucleophiles.
@en
P2093
Herbert Mayr
Shinya Minegishi
P304
P356
10.1021/JA021010Y
P407
P577
2003-01-01T00:00:00Z