First example of mu(3)-sulfido bridged mixed-valent triruthenium complex triangle Ru(III)(2)Ru(II)(O,O-acetylacetonate)(3)(mu-O,O,gamma-C-acetylacetonate)(3)(mu(3)-S) (1) incorporating simultaneous O,O- and gamma-C-bonded bridging acetylacetonate un
about
The triruthenium complex [[(acac)2Ru(II)]3(L)] containing a conjugated diquinoxaline[2,3-a:2',3'-c]phenazine (L) bridge and acetylacetonate (acac) as ancillary ligands. Synthesis, spectroelectrochemical and EPR investigation.Synthesis, structure, redox, NLO and DNA interaction aspects of [((L'-'")2RuII)3(mu3-L)]3+ and [(L')2RuII(NC5H4S-)]+[L3- = 1,3,5-triazine-2,4,6-trithiolato, L'-'" = arylazopyridine].3,6-bis(2'-pyridyl)pyridazine (L) and its deprotonated form (L - H+)- as ligands for {(acac)2Ru(n+)} or {(bpy)2Ru(m+)}: investigation of mixed valency in [{(acac)2Ru}2(mu-L - H+)]0 and [{(bpy)2Ru}2(mu-L - H+)]4+ by spectroelectrochemistry and EPR.A three-coordinate Fe(ii) center within a [3Fe-(μ3-S)] cluster that provides an accessible coordination site.Non-innocence and mixed valency in tri- and tetranuclear ruthenium complexes of a heteroquinone bridging ligand.
P2860
First example of mu(3)-sulfido bridged mixed-valent triruthenium complex triangle Ru(III)(2)Ru(II)(O,O-acetylacetonate)(3)(mu-O,O,gamma-C-acetylacetonate)(3)(mu(3)-S) (1) incorporating simultaneous O,O- and gamma-C-bonded bridging acetylacetonate un
description
2003 nî lūn-bûn
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name
First example of mu(3)-sulfido ...... ed bridging acetylacetonate un
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First example of mu(3)-sulfido ...... ed bridging acetylacetonate un
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type
label
First example of mu(3)-sulfido ...... ed bridging acetylacetonate un
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First example of mu(3)-sulfido ...... ed bridging acetylacetonate un
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prefLabel
First example of mu(3)-sulfido ...... ed bridging acetylacetonate un
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First example of mu(3)-sulfido ...... ed bridging acetylacetonate un
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P2093
P356
P1433
P1476
First example of mu(3)-sulfido ...... ed bridging acetylacetonate un
@en
P2093
Biplab Mondal
Goutam Kumar Lahiri
Mark Niemeyer
Srikanta Patra
P304
P356
10.1021/IC026221I
P407
P577
2003-02-01T00:00:00Z