Cross-coupling reactions involving metal carbene: from C═C/C-C bond formation to C-H bond functionalization.
about
Formation of a C-C double bond from two aliphatic carbons. Multiple C-H activations in an iridium pincer complex.Gold-catalyzed oxidative couplings of two indoles with one aryldiazo cyanide under oxidant-free conditions.Recent advances in transition-metal-catalyzed synthesis of conjugated enynes.Palladium-Catalyzed [3+3] Annulation of Vinyl Chromium(0) Carbene Complexes through Carbene Migratory Insertion/Tsuji-Trost Reaction.Mechanism of the rhodium(iii)-catalyzed alkenylation reaction of N-phenoxyacetamide with styrene or N-tosylhydrazone: a computational study.Rh(V) -Nitrenoid as a Key Intermediate in Rh(III) -Catalyzed Heterocyclization by C-H Activation: A Computational Perspective on the Cycloaddition of Benzamide and Diazo Compounds.Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp2 )-H Bonds: Access to Substituted 1H-Indenes.Iron-catalyzed intermolecular cycloaddition of diazo surrogates with hexahydro-1,3,5-triazines.Gold-catalyzed para-selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds.Synthesis of 1H-indole-3-sulfonates via palladium-catalyzed tandem reactions of 2-alkynyl arylazides with sulfonic acids.A general synthesis of arylindoles and (1-arylvinyl)carbazoles via a one-pot reaction from N-tosylhydrazones and 2-nitro-haloarenes and their potential application to colon cancer.Gold-catalysed facile access to indene scaffolds via sequential C-H functionalization and 5-endo-dig carbocyclization.Copper-catalyzed aerobic oxidative transformation of ketone-derived N-tosyl hydrazones: an entry to alkynes.Transition-metal-free cascade reaction of α-halo-N-tosylhydrazones, indoles and arylboronic acids.Pd-catalyzed cross-coupling of terminal alkynes with ene-yne-ketones: access to conjugated enynes via metal carbene migratory insertion.Gold(I)-catalyzed diazo coupling: strategy towards alkene formation and tandem benzannulation.Rhodium(I)-Catalyzed C-C Bond Activation of Siloxyvinylcyclopropanes with Diazoesters.Rhodium-catalyzed C-H activation of 3-(indolin-1-yl)-3-oxopropanenitriles with diazo compounds and tandem cyclization leading to hydrogenated azepino[3,2,1-hi]indoles.Pd(0)-catalyzed cross-coupling of allyl halides with α-diazocarbonyl compounds or N-mesylhydrazones: synthesis of 1,3-diene compounds.Copper(I)-catalyzed olefination of N-sulfonylhydrazones with sulfones.Metal-free oxidative cross-coupling of diazirines with arylboronic acids.Metal-Free Ring-Expansion Reaction of Six-membered Sulfonylimines with Diazomethanes: An Approach toward Seven-Membered Enesulfonamides.Base-Promoted/Gold-Catalyzed Intramolecular Highly Selective and Controllable Detosylative Cyclization.Reversible α-Hydrogen and α-Alkyl Elimination in PC(sp(3))P Pincer Complexes of Iridium.Access to polysubstituted indoles or benzothiophenes via palladium-catalyzed cross-coupling of furfural tosylhydrazones with 2-iodoanilines or 2-iodothiophenols.Rh(III)-catalyzed and alcohol-involved carbenoid C-H insertion into N-phenoxyacetamides using α-diazomalonates.Transition-metal-free intramolecular carbene aromatic substitution/Büchner reaction: synthesis of fluorenes and [6,5,7]benzo-fused rings.CuI-catalyzed cross-coupling of terminal alkynes with dialkoxycarbenes: a general method for the synthesis of unsymmetrical propargylic acetals.Structurally Diverse π-Extended Conjugated Polycarbo- and Heterocycles through Pd-Catalyzed Autotandem Cascades.A Pd-catalyzed cascade reaction of N-H insertion and oxidative dehydrogenative aromatization: a new entry to 2-amino-phenols.Practical access to spiroacetal enol ethers via nucleophilic dearomatization of 2-furylmethylenepalladium halides generated by Pd-catalyzed coupling of furfural tosylhydrazones with aryl halides.Palladium-catalyzed three-component reaction of N-tosylhydrazone, norbornene and aryl halide.Rh(III)-catalyzed synthesis of 1-aminoindole derivatives from 2-acetyl-1-arylhydrazines and diazo compounds in water.Synthesis of 1H-indazoles from N-tosylhydrazones and nitroaromatic compounds.Rhodium(III)-catalyzed ortho alkenylation of N-phenoxyacetamides with N-tosylhydrazones or diazoesters through C-H activation.Copper-Catalyzed Regioselective Cascade Alkylation and Cyclocondensation of Quinoline N-Oxides with Diazo Esters: Direct Access to Conjugated π-Systems.Origins of unique gold-catalysed chemo- and site-selective C–H functionalization of phenols with diazo compounds† †Electronic supplementary information (ESI) available: Data for new compounds, experimental procedures and theoretical studies on mechaRh(iii)-catalyzed regioselective intermolecular N-methylene Csp3-H bond carbenoid insertion.
P2860
Q33869691-128D3BF0-3690-4458-95C0-C1AEDA5ED2C7Q38844543-63C92737-79B1-4067-BE14-6B3BD67D622DQ38862551-04AB4BDE-E1EC-4991-A6FC-B24E6540D54AQ46315689-20E484F1-2F4C-4417-A90C-80B8CF216CDEQ46562516-78C020EA-0659-4A38-AB5A-8AB9237E5E61Q46727591-8F08ED59-0853-4388-957A-454C6B133221Q47409040-8F12D44D-2F7D-4FE0-84CF-B8BB1BF49989Q47700387-8542B6A3-8E1E-4547-93BD-9330B6079645Q47743567-FAF3FD5A-2BEA-4615-B7FF-FA2C323CCC32Q47949592-BF79B4F1-0688-4C0F-AA24-E75C873AAD80Q48272373-5BE8651E-AA40-4979-82F7-7C147BC3DD26Q50224824-30BE9209-F000-4DC0-B6CC-54EEDA786DC9Q50445313-CE4C21CD-82CE-4068-A663-B8B73A2F5C42Q50867730-423B6DD5-FF1C-4997-8A6C-88824A7BD3F6Q50963205-62EE6383-DBA0-45AF-A5BE-C0DA3CF498DFQ51061020-34D2992D-EED2-4B09-BAB8-C99EFB7A32C7Q51097779-4EC316B2-6237-4614-BAC6-7A8DD13598AAQ51098702-079FB92D-5D19-4BB8-A43E-9999B1CD4AA6Q51405566-558A9C1F-F940-4C2B-8A65-E5E019064B42Q51476160-5151FDB1-14EA-4D23-870F-EA6ACB5D1290Q51598992-303474E0-B768-4579-A9B4-0F4EB551C0DEQ51607881-EC81FB83-F793-45DB-B85E-E6DC54194494Q51828651-A675B4DA-7965-4AA2-85A8-18ADB9D8577FQ52934560-D0F28B47-3147-4810-8707-36A8879E9EC0Q53298858-ECC23BD9-E5FF-48AD-8606-806AAE2EB1EFQ53302745-C8DB7CF2-0539-462F-8B66-F99CCBBC9406Q53334567-22B8C6E3-4410-4C35-B2FB-58DDC3EDCA58Q53506365-7124A977-00E2-4D83-B3A4-01E7C53D0572Q53518851-5343E50D-561A-46A5-9765-A5C3745A2DB1Q53551803-9E0BE60A-8F0F-4DDF-AA2E-B3B3E50A78DAQ53562972-4C30A48C-9592-4CD8-B8FA-D721D9086B7FQ53564024-C115E73A-0B9A-4731-A264-3E70BEF1DCEFQ53564037-195AFB55-3968-4E8A-969E-B6D2720725C4Q53579102-50282056-8965-482C-A597-5886B99B35E4Q53652910-62765439-FF69-4AB8-9091-0908A5705E9AQ54451997-7A394DC6-1CF6-4BC4-A8F2-3D2044CD8984Q55043725-FAE37AE5-EC7C-4A6F-8D8F-92D5AC93D590Q55366299-D1D4B019-46F5-4D54-87C0-4AA3D9E151E2
P2860
Cross-coupling reactions involving metal carbene: from C═C/C-C bond formation to C-H bond functionalization.
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年学术文章
@wuu
2013年学术文章
@zh
2013年学术文章
@zh-cn
2013年学术文章
@zh-hans
2013年学术文章
@zh-my
2013年学术文章
@zh-sg
2013年學術文章
@yue
2013年學術文章
@zh-hant
name
Cross-coupling reactions invol ...... to C-H bond functionalization.
@en
Cross-coupling reactions invol ...... to C-H bond functionalization.
@nl
type
label
Cross-coupling reactions invol ...... to C-H bond functionalization.
@en
Cross-coupling reactions invol ...... to C-H bond functionalization.
@nl
prefLabel
Cross-coupling reactions invol ...... to C-H bond functionalization.
@en
Cross-coupling reactions invol ...... to C-H bond functionalization.
@nl
P356
P1476
Cross-coupling reactions invol ...... to C-H bond functionalization.
@en
P2093
Jianbo Wang
Zhenxing Liu
P304
10024-10030
P356
10.1021/JO401850Q
P407
P577
2013-09-19T00:00:00Z