A fragile zwitterionic phosphasilene as a transfer agent of the elusive parent phosphinidene (:PH).
about
Advances in Phosphasilene Chemistry.An Electrophilic Carbene-Anchored Silylene-Phosphinidene.HPCO-A Phosphorus-Containing Analogue of Isocyanic Acid.An NHC-phosphinidenyl as a synthon for new group 13/15 compounds.A Masked Phosphinidene Trapped in a Fluxional NCN Pincer.The synthesis, structure and reactivity of an imine-stabilized carboranylphosphorus(i) compound.From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene.Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species.Synthesis of a Metallo-Iminosilane via a Silanone-Metal π-Complex.Theoretical Evidence for the Utilization of Low-Valent Main-Group Complexes as Rare-Synthon Equivalents.A Persistent 1,2-Dihydrophosphasilene Adduct.Cleavage of a P=P Double Bond Mediated by N-Heterocyclic Carbenes.Facile Phenylphosphinidene Transfer Reactions from Carbene-Phosphinidene Zinc Complexes.A comparative study of the structure and bonding in heavier pnictinidene complexes [(ArE)M(CO)n] (E = As, Sb and Bi; M = Cr, Mo, W and Fe).Cyclic (Amino)(Phosphonium Bora-Ylide)Silanone: A Remarkable Room-Temperature-Persistent Silanone.Assembly of NHC-stabilized 2-hydrophosphasilenes from Si(iv) precursors: a Lewis acid-base complex.Facile rotation around a silicon-phosphorus double bond enabled through coordination to tungsten.Reaction of an N-heterocyclic carbene-stabilized silicon(II) monohydride with alkynes: [2+2+1] cycloaddition versus hydrogen abstraction.New route to access an acyl-functionalized phosphasilene and a four-membered Si-P-C-O heterocycle.A donor-stabilized zwitterionic "half-parent" phosphasilene and its unusual reactivity towards small molecules.Triamidoamine-uranium(IV)-stabilized terminal parent phosphide and phosphinidene complexes.Selective [3+1] Fragmentations of P4 by "P" Transfer from a Lewis Acid Stabilized [RP4 ]- Butterfly Anion.Anorganische Chemie 2013An Electrophilic Carbene-Anchored Silylene-PhosphinideneAn unprecedented 1,4-diphospha-2,3-disila butadiene (–PSi–SiP–) derivative and a 1,3-diphospha-2-silaallyl anion, each stabilized by the amidinate ligand
P2860
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P2860
A fragile zwitterionic phosphasilene as a transfer agent of the elusive parent phosphinidene (:PH).
description
2013 nî lūn-bûn
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2013年の論文
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2013年学术文章
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2013年学术文章
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name
A fragile zwitterionic phospha ...... ve parent phosphinidene (:PH).
@en
A fragile zwitterionic phospha ...... e elusive parent phosphinidene
@nl
type
label
A fragile zwitterionic phospha ...... ve parent phosphinidene (:PH).
@en
A fragile zwitterionic phospha ...... e elusive parent phosphinidene
@nl
prefLabel
A fragile zwitterionic phospha ...... ve parent phosphinidene (:PH).
@en
A fragile zwitterionic phospha ...... e elusive parent phosphinidene
@nl
P2093
P356
P1476
A fragile zwitterionic phospha ...... ve parent phosphinidene (:PH).
@en
P2093
Burgert Blom
Jan Epping
Kerstin Hansen
Tibor Szilvási
P304
11795-11798
P356
10.1021/JA4072699
P407
P577
2013-08-01T00:00:00Z