[(mu-L)[RuII(acac)2]2]n, n= 2+, +, 0, -, 2-, with L = 3,3',4,4'-tetraimino-3,3',4,4'-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediates.
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The triruthenium complex [[(acac)2Ru(II)]3(L)] containing a conjugated diquinoxaline[2,3-a:2',3'-c]phenazine (L) bridge and acetylacetonate (acac) as ancillary ligands. Synthesis, spectroelectrochemical and EPR investigation.Synthesis, structure, redox, NLO and DNA interaction aspects of [((L'-'")2RuII)3(mu3-L)]3+ and [(L')2RuII(NC5H4S-)]+[L3- = 1,3,5-triazine-2,4,6-trithiolato, L'-'" = arylazopyridine].3,6-bis(2'-pyridyl)pyridazine (L) and its deprotonated form (L - H+)- as ligands for {(acac)2Ru(n+)} or {(bpy)2Ru(m+)}: investigation of mixed valency in [{(acac)2Ru}2(mu-L - H+)]0 and [{(bpy)2Ru}2(mu-L - H+)]4+ by spectroelectrochemistry and EPR.Varying electronic structural forms of ruthenium complexes of non-innocent 9,10-phenanthrenequinonoid ligands.
P2860
[(mu-L)[RuII(acac)2]2]n, n= 2+, +, 0, -, 2-, with L = 3,3',4,4'-tetraimino-3,3',4,4'-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediates.
description
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name
[(mu-L)[RuII(acac)2]2]n, n= 2+ ...... he paramagnetic intermediates.
@en
[(mu-L)[RuII(acac)2]2]n, n= 2+ ...... he paramagnetic intermediates.
@nl
type
label
[(mu-L)[RuII(acac)2]2]n, n= 2+ ...... he paramagnetic intermediates.
@en
[(mu-L)[RuII(acac)2]2]n, n= 2+ ...... he paramagnetic intermediates.
@nl
prefLabel
[(mu-L)[RuII(acac)2]2]n, n= 2+ ...... he paramagnetic intermediates.
@en
[(mu-L)[RuII(acac)2]2]n, n= 2+ ...... he paramagnetic intermediates.
@nl
P2093
P2860
P356
P1433
P1476
[(mu-L)[RuII(acac)2]2]n, n= 2+ ...... he paramagnetic intermediates.
@en
P2093
Goutam Kumar Lahiri
Jan Fiedler
Sandeep Ghumaan
Srikanta Patra
Stanislav Zális
Wolfgang Kaim
P2860
P304
P356
10.1039/B315927M
P407
P577
2004-02-03T00:00:00Z