Asymmetric catalytic coupling of organoboranes, alkynes, and imines with a removable (trialkylsilyloxy)ethyl group--direct access to enantiomerically pure primary allylic amines.
about
Large-scale asymmetric synthesis of the bioprotective agent JP4-039 and analogsAllylic Amines as Key Building Blocks in the Synthesis of (E)-Alkene Peptide IsosteresTriethylboraneRecent Advances in Nucleophilic Addition Reactions of Organoboronic Acids and Their Derivatives to Unsaturated CN FunctionalitiesOrigins of regioselectivity and alkene-directing effects in nickel-catalyzed reductive couplings of alkynes and aldehydesNickel-Catalyzed Coupling Reactions of AlkenesNickel-catalyzed coupling of alkenes, aldehydes, and silyl triflates.Formation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and IminesAsymmetric multicomponent reactions (AMCRs): the new frontier.Nickel Catalysis: Synergy between Method Development and Total SynthesisRegio- and stereoselective cross-coupling of substituted olefins and imines. A convergent stereoselective synthesis of saturated 1,5-amino-alcohols and substituted piperidines.Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.Recent developments in asymmetric multicomponent reactions.Applications and stereoselective syntheses of P-chirogenic phosphorus compounds.Hydrogen-mediated reductive coupling of conjugated alkynes with ethyl (N-Sulfinyl)iminoacetates: synthesis of unnatural alpha-amino acids via rhodium-catalyzed C-C bond forming hydrogenationSynthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.Strategic use of nickel(0)-catalyzed enyne-epoxide reductive coupling towards the synthesis of (-)-cyatha-3,12-diene.Regioselectivity and enantioselectivity in nickel-catalysed reductive coupling reactions of alkynes.Stereoisomerically pure trisubstituted vinylaluminum reagents and their utility in copper-catalyzed enantioselective synthesis of 1,4-dienes containing Z or E alkenes.An alkoxide-directed intermolecular [2+2+1] annulation: a three-component coupling reaction for the synthesis of tetrasubstituted alpha,beta-unsaturated gamma-lactams.Isoquinolinium salts from o-halobenzaldehydes, amines, and alkynes catalyzed by nickel complexes: synthesis and applications.Lewis acid mediated vinyl-transfer reaction of alkynes to N-alkylimines by using the N-alkyl residue as a sacrificial hydrogen donor.Transition-metal-free chemo- and regioselective vinylation of azaallyls.NHC Ligands Tailored for Simultaneous Regio- and Enantiocontrol in Nickel-Catalyzed Reductive Couplings.Ni(ii)-catalyzed asymmetric addition of arylboronic acids to cyclic imines.Rh-Catalyzed Chemo- and Enantioselective Hydrogenation of Allylic Hydrazones.Nickel-catalyzed, directing-group-assisted [2+2+2] cycloaddition of imine and alkynes.Enantioselective synthesis of β-substituted chiral allylic amines via Rh-catalyzed asymmetric hydrogenation.
P2860
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P2860
Asymmetric catalytic coupling of organoboranes, alkynes, and imines with a removable (trialkylsilyloxy)ethyl group--direct access to enantiomerically pure primary allylic amines.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年学术文章
@wuu
2004年学术文章
@zh-cn
2004年学术文章
@zh-hans
2004年学术文章
@zh-my
2004年学术文章
@zh-sg
2004年學術文章
@yue
2004年學術文章
@zh
2004年學術文章
@zh-hant
name
Asymmetric catalytic coupling ...... y pure primary allylic amines.
@en
Asymmetric catalytic coupling ...... y pure primary allylic amines.
@nl
type
label
Asymmetric catalytic coupling ...... y pure primary allylic amines.
@en
Asymmetric catalytic coupling ...... y pure primary allylic amines.
@nl
prefLabel
Asymmetric catalytic coupling ...... y pure primary allylic amines.
@en
Asymmetric catalytic coupling ...... y pure primary allylic amines.
@nl
P356
P1476
Asymmetric catalytic coupling ...... y pure primary allylic amines.
@en
P2093
Sejal J Patel
Timothy F Jamison
P304
P356
10.1002/ANIE.200460044
P407
P577
2004-07-01T00:00:00Z