Structure, reactivity, and density functional theory analysis of the six-electron reductant, [(C5Me5)2U]2(mu-eta6:eta6-C6H6), synthesized via a new mode of (C5Me5)3M reactivity.
about
The occurrence and representation of three-centre two-electron bonds in covalent inorganic compoundsSyntheses and structures of zirconium(IV) complexes supported by 2,6-di-adamantylaryloxide ligands and formation of arene-bridged dizirconium complexes with an inverse sandwich structure.Reductive assembly of cyclobutadienyl and diphosphacyclobutadienyl rings at uranium.Group 3 metal stilbene complexes: synthesis, reactivity, and electronic structure studies.A triamido-uranium(V) inverse-sandwich 10π-toluene tetraanion arene complex.Distortions of π-coordinated arenes with anionic character.Scandium and yttrium metallocene borohydride complexes: comparisons of (BH4)1- vs. (BPh4)1- coordination and reactivity.A six-carbon 10π-electron aromatic system supported by group 3 metals.Synthesis of a thorium tuck-in complex, [(eta(5):eta(1)-C(5)Me(4)CH(2))(eta(5)-C(5)Me(5))Th{iPrNC(Me)NiPr}], by C-H bond activation initiated by (C(5)Me(5))(-).Rare-earth metal π-complexes of reduced arenes, alkenes, and alkynes: bonding, electronic structure, and comparison with actinides and other electropositive metals.A delocalized arene-bridged diuranium single-molecule magnet.The importance of a single methyl group in determining the reaction chemistry of pentamethylcyclopentadienyl cyclooctatetraenyl uranium metallocenes.Evaluating f-element bonding from structure and thermodynamics.Molecular quadrangle formation from a diuranium μ-η6,η6-toluene complex.Harnessing redox activity for the formation of uranium tris(imido) compounds.Synthesis and reactions of beta-diketiminato divanadium(I) inverted-sandwich complexes.Theoretical treatment of one electron redox transformation of a small molecule using f-element complexes.Molecular magnetism: uranium memory.The role of uranium-arene bonding in H2O reduction catalysis.Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings.Isolation of +2 rare earth metal ions with three anionic carbocyclic rings: bimetallic bis(cyclopentadienyl) reduced arene complexes of La2+ and Ce2+ are four electron reductants.Synthesis and Characterization of a Uranium(II) Monoarene Complex Supported byδ BackbondingCoordination and Redox Isomerization in the Reduction of a Uranium(III) Monoarene Complex
P2860
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P2860
Structure, reactivity, and density functional theory analysis of the six-electron reductant, [(C5Me5)2U]2(mu-eta6:eta6-C6H6), synthesized via a new mode of (C5Me5)3M reactivity.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年学术文章
@wuu
2004年学术文章
@zh
2004年学术文章
@zh-cn
2004年学术文章
@zh-hans
2004年学术文章
@zh-my
2004年学术文章
@zh-sg
2004年學術文章
@yue
2004年學術文章
@zh-hant
name
Structure, reactivity, and den ...... mode of (C5Me5)3M reactivity.
@en
Structure, reactivity, and den ...... mode of (C5Me5)3M reactivity.
@nl
type
label
Structure, reactivity, and den ...... mode of (C5Me5)3M reactivity.
@en
Structure, reactivity, and den ...... mode of (C5Me5)3M reactivity.
@nl
prefLabel
Structure, reactivity, and den ...... mode of (C5Me5)3M reactivity.
@en
Structure, reactivity, and den ...... mode of (C5Me5)3M reactivity.
@nl
P2093
P356
P1476
Structure, reactivity, and den ...... mode of (C5Me5)3M reactivity.
@en
P2093
Joseph W Ziller
Stosh A Kozimor
William J Evans
P304
14533-14547
P356
10.1021/JA0463886
P407
P577
2004-11-01T00:00:00Z