Stabilization of anti-aromatic and strained five-membered rings with a transition metal. - Wikidata - awgldk - TriplyDB

Stabilization of anti-aromatic and strained five-membered rings with a transition metal.

Stabilization of anti-aromatic and strained five-membered rings with a transition metal.

http://www.wikidata.org/entity/Q45280349

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Planar Möbius aromatic pentalenes incorporating 16 and 18 valence electron osmiums Synthesis of aromatic aza-metallapentalenes from metallabenzene via sequential ring contraction/annulation.CCCCC pentadentate chelates with planar Möbius aromaticity and unique properties.Probing the Origin of Challenge of Realizing Metallaphosphabenzenes: Unfavorable 1,2-Migration in Metallapyridines Becomes Feasible in Metallaphosphabenzenes.Metallacyclopentadienes: synthesis, structure and reactivity.Planar tetracoordinate carbon in tungstenacyclobutadiene from alkyne metathesis and expanded structures.1,3-Butadienyl Dianions as Non-Innocent Ligands: Synthesis and Characterization of Aromatic Dilithio Rhodacycles.Dianions as Formal Oxidants: Synthesis and Characterization of Aromatic Dilithionickeloles from 1,4-Dilithio-1,3-butadienes and [Ni(cod)2].The novel link between planar möbius aromatic and third order nonlinear optical properties of metal-bridged polycyclic complexes.Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion.Barium dibenzopentalenide as a main-group metal η⁸ complex: facile synthesis from 1,4-dilithio-1,3-butadienes and Ba[N(SiMe₃)₂]₂, structural characterization, and reaction chemistry.Recent Advances in Metallaaromatic Chemistry.Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-membered Rings.Metallapentalenofurans and Lactone-Fused Metallapentalynes.Synthesis of aromatic ruthenabenzothiophenes via C-H activation of thiophenes.Triplet State Aromaticity: NICS Criterion, Hyperconjugation, and Charge Effects.Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla-aromatics.Multiyne chains chelating osmium via three metal-carbon σ bonds.Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity.Influence of the Transition-Metal Fragment on the Reactivity of Metallaanthracenes.Long Stokes shifts and vibronic couplings in perfluorinated polyanilines.Syntheses of Amino-Substituted Iridabenzofurans and Subsequent Selective N-Functionalisation."Aggregation induced phosphorescence" active "rollover" iridium(III) complex as a multi-stimuli-responsive luminescence material.Synthesis and Characterization of Dirhenadehydro[12]annulenes.σ Aromaticity Dominates in the Unsaturated Three-Membered Ring of Cyclopropametallapentalenes from Groups 7-9: A DFT Study.Unexpected higher stabilisation of two classical antiaromatic frameworks with a ruthenium fragment compared to the osmium counterpart: origin probed by DFT calculations.The Clar Structure in Inorganic BN Analogues of Polybenzenoid Hydrocarbons: Does it Exist or Not?A metal-bridged tricyclic aromatic system: synthesis of osmium polycyclic aromatic complexes.Syntheses, structural characterisation and electronic structures of ferrocenyl-osmafuran heterobinuclear organometallic complexes.σ-Aromaticity in an unsaturated ring: osmapentalene derivatives containing a metallacyclopropene unit.Unexpected 1,2-migration in metallasilabenzenes: theoretical evidence for reluctance of silicon to participate in π bonding.Intramolecular C-F and C-H bond cleavage promoted by butadienyl heavy Grignard reagents.Five-membered cyclic metal carbyne: synthesis of osmapentalynes by the reactions of osmapentalene with allene, alkyne, and alkene.The aromatic dianion metalloles.Synthesis, structure and aromaticity of carborane-fused carbo- and heterocycles.Constraint of a ruthenium-carbon triple bond to a five-membered ring.

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P2860

Stabilization of anti-aromatic and strained five-membered rings with a transition metal.

http://www.wikidata.org/entity/Q45280349

description

2013 nî lūn-bûn

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2013年の論文

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2013年学术文章

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2013年学术文章

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2013年学术文章

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2013年學術文章

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2013年學術文章

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2013年學術文章

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name

Stabilization of anti-aromatic and strained five-membered rings with a transition metal.

@en

Stabilization of anti-aromatic and strained five-membered rings with a transition metal.

@nl

type

label

Stabilization of anti-aromatic and strained five-membered rings with a transition metal.

@en

Stabilization of anti-aromatic and strained five-membered rings with a transition metal.

@nl

prefLabel

Stabilization of anti-aromatic and strained five-membered rings with a transition metal.

@en

Stabilization of anti-aromatic and strained five-membered rings with a transition metal.

@nl

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Nature Chemistry

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Stabilization of anti-aromatic and strained five-membered rings with a transition metal.

@en

P2093

Congqing Zhu

http://www.w3.org/2001/XMLSchema#string

Haiping Xia

http://www.w3.org/2001/XMLSchema#string

Jun Zhu

http://www.w3.org/2001/XMLSchema#string

Ming Luo

http://www.w3.org/2001/XMLSchema#string

Minglian Lin

http://www.w3.org/2001/XMLSchema#string

Paul V R Schleyer

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Shunhua Li

http://www.w3.org/2001/XMLSchema#string

Tingbin Wen

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Xiaoxi Zhou

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Xin Lu

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P2860

Möbius Aromaticity and Delocalization

Nucleus-Independent Chemical Shifts: A Simple and Efficient Aromaticity Probe.

Hűckel molecular orbitals of Mőbius-type conformations of annulenes

NIR dyes for bioimaging applications

Conceptual and computational DFT in the study of aromaticity.

From antenna to assay: lessons learned in lanthanide luminescence.

Aggregation-induced emission.

Progress in the chemistry of metallabenzynes.

Demonstration of "Möbius" aromaticity in planar metallacycles.

Formation of a 1-zircona-2,5-disilacyclopent-3-yne: coordination of 1,4-disilabutatriene to zirconocene?

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698-703

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scholarly article

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10.1038/NCHEM.1690

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8

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5

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2013-06-23T00:00:00Z

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251569702

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1038194538

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23881502

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