Room-temperature catalytic hydrodefluorination of C(sp3)-F bonds.
about
Hydrosilation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η-Silane Iridium(III) ComplexTriethylsilyl Perfluoro-Tetraphenylborate, [Et(3)Si][F(20)-BPh(4)], a widely used Non-Existent Compound.Electrophilic Activation of Lewis Base Complexes of Borane with Trityl Tetrakis(pentafluorophenyl)borate.Synthesis of fluorinated building blocks by transition-metal-mediated hydrodefluorination reactions.Hydrodefluorination of carbon-fluorine bonds by the synergistic action of a ruthenium-palladium catalyst.Selective C-F/C-H bond activation of fluoroarenes by cobalt complex supported with phosphine ligands.Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts.Mild and selective activation and substitution of strong aliphatic C-F bonds.NHC-catalyzed [4+2] cycloaddition reactions for the synthesis of 3'-spirocyclic oxindoles via a C-F bond cleavage protocol.Transition-Metal-Free Catalytic Hydrodefluorination of Polyfluoroarenes by Concerted Nucleophilic Aromatic Substitution with a Hydrosilicate.Use of Trifluoromethyl Groups for Catalytic Benzylation and Alkylation with Subsequent Hydrodefluorination.An Isolable Potassium Salt of a Borasilene-Chloride Adduct.Organometallic chemistry using partially fluorinated benzenes.Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C-H and C-F Bond Activation.Consecutive Transformations of Tetrafluoropropenes: Hydrogermylation and Catalytic C-F Activation Steps at a Lewis Acidic Aluminum Fluoride.Palladium-Catalyzed Carbon-Fluorine and Carbon-Hydrogen Bond Alumination of Fluoroarenes and Heteroarenes.Lewis Acid Promoted Single C-F Bond Activation of the CF3 Group: SN 1'-Type 3,3-Difluoroallylation of Arenes with 2-Trifluoromethyl-1-alkenes.Ligand versus Complex: C-F and C-H Bond Activation of Polyfluoroaromatics at a Cyclic (Alkyl)(Amino)Carbene.Niobium(v)-catalyzed defluorinative triallylation of α,α,α-trifluorotoluene derivatives by triple C-F bond activation.Silyl Chalconium Ions: Synthesis, Structure and Application in Hydrodefluorination Reactions.C-F Bond Activation by Silylium Cation/Phosphine Frustrated Lewis Pairs: Mono-Hydrodefluorination of PhCF3 , PhCF2 H and Ph2 CF2.Chiral Memory in Silylium Ions.Conversion of a (sp3)C-F bond of alkyl fluorides to (sp3)C-X (X = Cl, C, H, O, S, Se, Te, N) bonds using organoaluminium reagents.Facile Access to Stable Silylium Ions Stabilized by N-Heterocyclic Imines.Single C-F Bond Cleavage of Trifluoromethylarenes with an ortho-Silyl Group.A facile access to a novel NHC-stabilized silyliumylidene ion and C-H activation of phenylacetylene.Titanium-catalyzed vinylic and allylic C-F bond activation-scope, limitations and mechanistic insight.The pentamethylcyclopentadienylsilicon(II) cation as a catalyst for the specific degradation of oligo(ethyleneglycol) diethers.Competing reaction pathways of 3,3,3-trifluoropropene at rhodium hydrido, silyl and germyl complexes: C-F bond activation versus hydrogermylation.Use of Trifluoromethyl Groups for Catalytic Benzylation and Alkylation with Subsequent HydrodefluorinationSelf-regeneration of a silylium ion catalyst in carbonyl reduction
P2860
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P2860
Room-temperature catalytic hydrodefluorination of C(sp3)-F bonds.
description
2005 nî lūn-bûn
@nan
2005年の論文
@ja
2005年学术文章
@wuu
2005年学术文章
@zh
2005年学术文章
@zh-cn
2005年学术文章
@zh-hans
2005年学术文章
@zh-my
2005年学术文章
@zh-sg
2005年學術文章
@yue
2005年學術文章
@zh-hant
name
Room-temperature catalytic hydrodefluorination of C
@nl
Room-temperature catalytic hydrodefluorination of C(sp3)-F bonds.
@en
type
label
Room-temperature catalytic hydrodefluorination of C
@nl
Room-temperature catalytic hydrodefluorination of C(sp3)-F bonds.
@en
prefLabel
Room-temperature catalytic hydrodefluorination of C
@nl
Room-temperature catalytic hydrodefluorination of C(sp3)-F bonds.
@en
P2093
P356
P1476
Room-temperature catalytic hydrodefluorination of C(sp3)-F bonds.
@en
P2093
Oleg V Ozerov
Remle Celenligil-Cetin
Valerie J Scott
P304
P356
10.1021/JA0426138
P407
P577
2005-03-01T00:00:00Z