Facile oxy-functionalization of a nucleophilic metal alkyl with a cis-dioxo metal species via a (2+3) transition state.
about
C-H oxidation by platinum group metal oxo or peroxo species.C-H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity.A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M-R to vanadate oxo.The para-substituent effect and pH-dependence of the organometallic Baeyer-Villiger oxidation of rhenium-carbon bonds.
P2860
Facile oxy-functionalization of a nucleophilic metal alkyl with a cis-dioxo metal species via a (2+3) transition state.
description
2008 nî lūn-bûn
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name
Facile oxy-functionalization o ...... via a (2+3) transition state.
@en
Facile oxy-functionalization o ...... cis-dioxo metal species via a
@nl
type
label
Facile oxy-functionalization o ...... via a (2+3) transition state.
@en
Facile oxy-functionalization o ...... cis-dioxo metal species via a
@nl
prefLabel
Facile oxy-functionalization o ...... via a (2+3) transition state.
@en
Facile oxy-functionalization o ...... cis-dioxo metal species via a
@nl
P2093
P356
P1476
Facile oxy-functionalization o ...... via a (2+3) transition state.
@en
P2093
Brian L Conley
Daniel H Ess
Jason M Gonzales
Robert J Nielsen
Roy A Periana
Somesh K Ganesh
Vadim R Ziatdinov
William A Goddard
P304
P356
10.1002/ANIE.200802575
P407
P577
2008-01-01T00:00:00Z