about
Density functional theory study of the mechanism and origins of stereoselectivity in the asymmetric Simmons-Smith cyclopropanation with Charette chiral dioxaborolane ligand.Covalently patterned graphene surfaces by a force-accelerated Diels-Alder reaction.Design, Synthesis, and Validation of an Effective, Reusable Silicon-Based Transfer Agent for Room-Temperature Pd-Catalyzed Cross-Coupling Reactions of Aryl and Heteroaryl Chlorides with Readily Available Aryl Lithium Reagents.1,2,4-Triazines Are Versatile Bioorthogonal Reagents.Total synthesis of (+)-asteriscanolide: further exploration of the rhodium(I)-catalyzed [(5+2)+1] reaction of ene-vinylcyclopropanes and CO.Mechanistic Insights into Two-Phase Radical C-H Arylations.Bioorthogonal Cycloadditions: Computational Analysis with the Distortion/Interaction Model and Predictions of Reactivities.Potassium tert-Butoxide-Catalyzed Dehydrogenative C-H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study.Isomeric cyclopropenes exhibit unique bioorthogonal reactivities.Diels-Alder reactions of graphene: computational predictions of products and sites of reaction.Ionic and Neutral Mechanisms for C-H Bond Silylation of Aromatic Heterocycles Catalyzed by Potassium tert-Butoxide.Diels-Alder reactivities of strained and unstrained cycloalkenes with normal and inverse-electron-demand dienes: activation barriers and distortion/interaction analysis.Mechanisms and origins of switchable chemoselectivity of Ni-catalyzed C(aryl)-O and C(acyl)-O activation of aryl esters with phosphine ligands.New insights into the torquoselectivity of the Staudinger reaction.Tautomerization and Dimerization of 6,13-Disubstituted Derivatives of Pentacene.Distortion-Controlled Reactivity and Molecular Dynamics of Dehydro-Diels-Alder Reactions.Type II Anion Relay Chemistry: Conformational Constraints To Achieve Effective [1,5]-Vinyl Brook Rearrangements.Diels-Alder Reactivities of Benzene, Pyridine, and Di-, Tri-, and Tetrazines: The Roles of Geometrical Distortions and Orbital Interactions.Why bistetracenes are much less reactive than pentacenes in Diels-Alder reactions with fullerenes.Control and design of mutual orthogonality in bioorthogonal cycloadditions.Theoretical elucidation of the origins of substituent and strain effects on the rates of Diels-Alder reactions of 1,2,4,5-tetrazines.Unexpected, Latent Radical Reaction of Methane Propagated by Trifluoromethyl Radicals.Computational and Experimental Studies of Phthaloyl Peroxide-Mediated Hydroxylation of Arenes Yield a More Reactive Derivative, 4,5-Dichlorophthaloyl Peroxide.Mechanism, regioselectivity, and the kinetics of phosphine-catalyzed [3+2] cycloaddition reactions of allenoates and electron-deficient alkenes.A versatile method for the synthesis of 3-alkoxycarbonyl beta-lactam derivatives.Highly diastereoselective construction of fused carbocycles from cyclopropane-1,1-dicarboxylates and cyclic enol silyl ethers: scope, mechanism, and origin of diastereoselectivity.Mechanistic twist of the [8+2] cycloadditions of dienylisobenzofurans and dimethyl acetylenedicarboxylate: stepwise [8+2] versus [4+2]/[1,5]-vinyl shift mechanisms revealed through a theoretical and experimental study.A computationally designed Rh(I)-catalyzed two-component [5+2+1] cycloaddition of ene-vinylcyclopropanes and CO for the synthesis of cyclooctenones.Iodoarene-Catalyzed Stereospecific Intramolecular sp(3) C-H Amination: Reaction Development and Mechanistic Insights.An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3 + 2) cycloaddition of allenoates and alkenes.Nitrene equivalent mediated metal-free ring expansions of alkylidenecyclopropanes and an alkylidenecyclobutane.Do reaction conditions affect the stereoselectivity in the Staudinger reaction?Origin of the relative stereoselectivity of the beta-lactam formation in the Staudinger reaction.Microwave- and photoirradiation-induced staudinger reactions of cyclic imines and ketenes generated from alpha-diazoketones. A further investigation into the stereochemical process.Chiral phosphoric acid catalyzed highly enantioselective desymmetrization of 2-substituted and 2,2-disubstituted 1,3-diols via oxidative cleavage of benzylidene acetals.Unconventional, chemically stable, and soluble two-dimensional angular polycyclic aromatic hydrocarbons: from molecular design to device applications.Gold-catalyzed intermolecular reactions of propiolic acids with alkenes: [4 + 2] annulation and enyne cross metathesis.Why Alkynyl Substituents Dramatically Accelerate Hexadehydro-Diels–Alder (HDDA) Reactions: Stepwise Mechanisms of HDDA CycloadditionsMolecular Basis for the Final Oxidative Rearrangement Steps in Chartreusin BiosynthesisDistortion-accelerated cycloadditions and strain-release-promoted cycloreversions in the organocatalytic carbonyl-olefin metathesis
P50
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P50
description
hulumtues
@sq
onderzoeker
@nl
researcher
@en
հետազոտող
@hy
name
Yong Liang
@ast
Yong Liang
@en
Yong Liang
@es
Yong Liang
@nl
Yong Liang
@sl
type
label
Yong Liang
@ast
Yong Liang
@en
Yong Liang
@es
Yong Liang
@nl
Yong Liang
@sl
prefLabel
Yong Liang
@ast
Yong Liang
@en
Yong Liang
@es
Yong Liang
@nl
Yong Liang
@sl
P1053
J-4541-2017
P106
P21
P31
P3829
P496
0000-0001-5026-6710