Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise.
about
Experimental and theoretical investigations on the high-electron donor character of pyrido-annelated N-heterocyclic carbenesIsolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction".Direct estimate of the internal π-donation to the carbene centre within N-heterocyclic carbenes and related moleculesHighly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence.α-Radical Phosphines: Synthesis, Structure, and Reactivity.A Remarkably Simple Class of Imidazolium-Based Lipids and Their Biological Properties.Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy of Functional Groups.Borylenes: An Emerging Class of Compounds.Cyclic (Alkyl)(Amino)Carbene Complexes of Rhodium and Nickel and Their Steric and Electronic Parameters.Generation of 1,2-azaboretidines via reduction of ADC borane adducts.Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolboraneRare-Earth- and Uranium-Mesoionic Carbenes: A New Class of f-Block Carbene Complex Derived from an N-Heterocyclic OlefinIsolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes.Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis.Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis.NHC-CAAC Heterodimers with Three Stable Oxidation States.Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals.Synthesis, structure and cytotoxicity of cyclic (alkyl)(amino) carbene and acyclic carbene complexes of group 11 metals.From Borane to Borylene without Reduction: Ambiphilic Behavior of a Monovalent Silylisonitrile Boron Species.Fusing Dicarbollide Ions with N-Heterocyclic Carbenes.Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes.Azido- and amido-substituted gallium hydrides supported by N-heterocyclic carbenes.A Masked Phosphinidene Trapped in a Fluxional NCN Pincer.Carbones as Ligands in Novel Main-Group Compounds E[C(NHC)2 ]2 (E=Be, B+ , C2+ , N3+ , Mg, Al+ , Si2+ , P3+ ): A Theoretical Study.Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square.Metal-Free Activation of Hydrogen, Carbon Dioxide, and Ammonia by the Open-Shell Singlet Biradicaloid [P(μ-NTer)]2.Neutral Diboron Analogues of Archetypal Aromatic Species by Spontaneous Cycloaddition.Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles.Serendipitous Observation of Al(I) Insertion into a CO Bond in L2 PhB: (L=oxazol-2-ylidene).Methyl-, Ethenyl-, and Ethynyl-Bridged Cationic Digold Complexes Stabilized by Coordination to a Bulky Terphenylphosphine Ligand.The synthesis and structure of a carbene-stabilized iminocarboranyl-boron(I) compound.Activation of boryl-, borylene and metalloborylene complexes by isonitriles.Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor.Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3.Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system.Crystalline Neutral Allenic Diborene.The Charge Transfer Approach to Heavier Main-Group Element Radicals in Transition-Metal Complexes.Modular Bidentate Hybrid NHC-Thioether Ligands for the Stabilization of Palladium Nanoparticles in Various Solvents.From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond.Migratory Insertion of Carbenes into Au(III)-C Bonds.
P2860
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P2860
Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise.
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年学术文章
@wuu
2014年学术文章
@zh
2014年学术文章
@zh-cn
2014年学术文章
@zh-hans
2014年学术文章
@zh-my
2014年学术文章
@zh-sg
2014年學術文章
@yue
2014年學術文章
@zh-hant
name
Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise.
@en
type
label
Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise.
@en
prefLabel
Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise.
@en
P356
P1476
Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise.
@en
P2093
Michèle Soleilhavoup
P304
P356
10.1021/AR5003494
P407
P50
P577
2014-12-17T00:00:00Z