Singlet diradicals: from transition states to crystalline compounds.
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Substituent effect on the energy barrier for σ-bond formation from π-single-bonded species, singlet 2,2-dialkoxycyclopentane-1,3-diyls.A Puckered Singlet Cyclopentane-1,3-diyl: Detection of the Third Isomer in Homolysis.Thermally controlling the singlet-triplet energy gap of a diradical in the solid state.Stable cyclic carbenes and related species beyond diaminocarbenes.New perspectives for "non-classical" molecules: heavy [1.1.1]propellanes of group 14.The chemistry of localized singlet 1,3-diradicals (biradicals): from putative intermediates to persistent species and unusual molecules with a π-single bonded character.Carbene-Stabilized Main Group Radicals and Radical IonsRecent developments in and perspectives on three-coordinate boron materials: a bright future.Borylenes: An Emerging Class of Compounds.Stable singlet carbenes as mimics for transition metal centers.Substituents destabilize the molecule by increasing biradicaloid character and stabilize by intramolecular charge transfer in the derivatives of benzobis(thiadiazole) and thiadiazolothienopyrazine: a computational study.Kinetic stabilization and reactivity of π single-bonded species: effect of the alkoxy group on the lifetime of singlet 2,2-dialkoxy-1,3-diphenyloctahydropentalene-1,3-diyls.Reactivity of the dimesityl-1,8-naphthalenediylborate anion: isolation of the borataalkene isomer and synthesis of 1,8-diborylnaphthalenes.A polycyclic borazine radical cation: [1,2-B2{1,2-(MeN)2C6H4}2]˙(+).Triaminotriborane(3): A Homocatenated Boron Chain Connected by B-B Multiple Bonds.Reactions of heavier main-group compounds with hydrogen, ammonia, ethylene and related small molecules.(L)2 C2 P2 : Dicarbondiphosphide Stabilized by N-Heterocyclic Carbenes or Cyclic Diamido Carbenes.Direct Detection of a Chemical Equilibrium between a Localized Singlet Diradical and Its σ-Bonded Species by Time-Resolved UV/Vis and IR Spectroscopy.How diradicaloid is a stable diradical?Diradical character from the local spin analysis.Study of the Air-Tolerant 1,3-Diphosphacyclobutane-2,4-diyl through the Direct Arylation.Hydroboration of Phosphaalkynes by HB(C6 F5 )2.N-Heterocyclic Vinylidene-Stabilized Phosphorus Biradicaloid.An Isolable Diboron-Centered Diradical with a Triplet Ground State.Origin of the enhancement of the second hyperpolarizability of singlet diradical systems with intermediate diradical character.Computational insights into intriguing vibration-induced pulsing diradical character in perfluoropentacene and the perfluorination effect.Variational fractional-spin density-functional theory for diradicals.Silyl effects on 1,3-diphosphacyclobutane-2,4-diyl: ring-opening of tetrahydrofuran and promotion of reductive P-C cleavage.Theoretical study on the relationship between diradical character and second hyperpolarizabilities of four-membered-ring diradicals involving heavy main-group elements.Zwitterionic and biradicaloid heteroatomic cyclopentane derivatives containing different group 15 elements.Stable Radicals of the Heavy p-Block ElementsStudies on Stable 1,3-Diphosphacyclobutane-2,4-diylsDiverse Reactions of Sterically Protected 1,3-Diphosphacyclobutane-2,4-diyls with HydrideModeling the Direct Activation of Dihydrogen by a P2C2-Cyclic Biradical: Formation of a Cyclic Bis(P-H λ5-phosphorane)
P2860
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P2860
Singlet diradicals: from transition states to crystalline compounds.
description
2002 nî lūn-bûn
@nan
2002年の論文
@ja
2002年学术文章
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2002年学术文章
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2002年学术文章
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2002年学术文章
@zh-my
2002年学术文章
@zh-sg
2002年學術文章
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name
Singlet diradicals: from transition states to crystalline compounds.
@en
Singlet diradicals: from transition states to crystalline compounds.
@nl
type
label
Singlet diradicals: from transition states to crystalline compounds.
@en
Singlet diradicals: from transition states to crystalline compounds.
@nl
prefLabel
Singlet diradicals: from transition states to crystalline compounds.
@en
Singlet diradicals: from transition states to crystalline compounds.
@nl
P2093
P356
P1433
P1476
Singlet diradicals: from transition states to crystalline compounds.
@en
P2093
David Scheschkewitz
Didier Bourissou
Heinz Gornitzka
Hideki Amii
Wolfgang W Schoeller
P304
P356
10.1126/SCIENCE.1068167
P407
P50
P577
2002-03-01T00:00:00Z