Synthetic development and chemical reactivity of transition-metal silylene complexes.
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New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules.Mechanisms of metal-catalyzed dehydrocoupling reactions.Donor-acceptor chemistry in the main group.New bonding modes of carbon and heavier group 14 atoms Si-Pb.Group 14 inorganic hydrocarbon analogues.Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations.Synthesis and characterization of five-coordinate, 16-electron Ru(II) complexes supported by tridentate bis(phosphino)silyl ligation.Metal-ligand multiple bonds as frustrated Lewis pairs for C-H functionalization.Reductive borylene-CO coupling with a bulky arylborylene complex.Stepwise degradation of trifluoromethyl platinum(II) compounds.Two-dimensional liquid chromatography of PDMS-PS block copolymers.Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene.Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2(=GeRR')]+.From a decomposition product to an efficient and versatile catalyst: the [Ru(η5-indenyl)(PPh3)2Cl] story.Reactivity of an amidinato silylene and germylene toward germanium(ii), tin(ii) and lead(ii) halides.Manganese Silylene Hydride Complexes: Synthesis and Reactivity with Ethylene to Afford Silene Hydride Complexes.Silylene-Nickel Promoted Cleavage of B-O Bonds: From Catechol Borane to the Hydroborylene Ligand.From a Diphosphanegermylene to Nickel, Palladium, and Platinum Complexes Containing Germyl PGeP Pincer Ligands.Iron(II), Cobalt(II), Nickel(II), and Zinc(II) Silylene Complexes: Reaction of the Silylene [iPrNC(NiPr2 )NiPr]2 Si with FeBr2 , CoBr2 , NiBr2 ⋅MeOCH2 CH2 OMe, ZnCl2 , and ZnBr2.Planar PtPd3 Complexes Stabilized by Three Bridging Silylene Ligands.Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application.An NHC-Silyl-NHC Pincer Ligand for the Oxidative Addition of C-H, N-H, and O-H Bonds to Cobalt(I) Complexes.Dehydrogenative B-H/C(sp3 )-H Benzylic Borylation within the Coordination Sphere of Platinum(II).A Bis(silylene)-Substituted ortho-Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes.Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex.Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes.An iron germylene complex having Fe-H and Ge-H bonds: synthesis, structure and reactivity.Hydrodealkoxylation reactions of silyl ligands at platinum: reactivity of SiH₃ and SiH₂Me complexes.Examining the role of Rh/Si cooperation in alkene hydrogenation by a pincer-type [P2Si]Rh complex.Facile access to silicon-functionalized bis-silylene titanium(II) complexes.Bis(silylenyl)- and bis(germylenyl)-substituted ferrocenes: synthesis, structure, and catalytic applications of bidentate silicon(II)-cobalt complexes.Synthesis and unexpected coordination of a silicon(II)-based SiCSi pincerlike arene to palladium.Parent heavy methylenes: chemical tricks to access isolable complexes of elusive H2E: species (E=Ge and Sn).Bonding in cationic MCH2+ (M=K-La, Hf-Rn): a theoretical study on periodic trends.Reductive Cleavage of Carbon Monoxide by a Disilenide.Transition-Metal-Mediated Cleavage of a Si=Si Double Bond.Stepwise isolation of an unprecedented silylene supported dinuclear gold(i) cation with aurophilic interaction.1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl) complexes of iron: switching between borylenes and silylenes just by changing the alkyl group.Synthesis of mixed silylene-carbene chelate ligands from N-heterocyclic silylcarbenes mediated by nickel.A Pt(0) complex with cyclic (alkyl)(amino)silylene and 1,3-divinyl-1,1,3,3-tetramethyldisiloxane ligands: synthesis, molecular structure, and catalytic hydrosilylation activity.
P2860
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P2860
Synthetic development and chemical reactivity of transition-metal silylene complexes.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年学术文章
@wuu
2007年学术文章
@zh-cn
2007年学术文章
@zh-hans
2007年学术文章
@zh-my
2007年学术文章
@zh-sg
2007年學術文章
@yue
2007年學術文章
@zh
2007年學術文章
@zh-hant
name
Synthetic development and chemical reactivity of transition-metal silylene complexes.
@en
Synthetic development and chemical reactivity of transition-metal silylene complexes.
@nl
type
label
Synthetic development and chemical reactivity of transition-metal silylene complexes.
@en
Synthetic development and chemical reactivity of transition-metal silylene complexes.
@nl
prefLabel
Synthetic development and chemical reactivity of transition-metal silylene complexes.
@en
Synthetic development and chemical reactivity of transition-metal silylene complexes.
@nl
P2093
P356
P1476
Synthetic development and chemical reactivity of transition-metal silylene complexes.
@en
P2093
Paul G Hayes
Rory Waterman
T Don Tilley
P304
P356
10.1021/AR700028B
P407
P577
2007-05-03T00:00:00Z