Enantioselective epoxidation of allylic alcohols by a chiral complex of vanadium: an effective controller system and a rational mechanistic model.
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Zirconium(IV)- and hafnium(IV)-catalyzed highly enantioselective epoxidation of homoallylic and bishomoallylic alcohols.Asymmetric synthesis of D-ribo-phytosphingosine from 1-tetradecyne and (4-methoxyphenoxy)acetaldehyde.Development and application of versatile bis-hydroxamic acids for catalytic asymmetric oxidation.Chiral epoxides via borane reduction of 2-haloketones catalyzed by spiroborate ester: application to the synthesis of optically pure 1,2-hydroxy ethers and 1,2-azido alcoholsExperimental lineage and functional analysis of a remotely directed peptide epoxidation catalyst.Tungsten-catalyzed regioselective and stereospecific ring opening of 2,3-epoxy alcohols and 2,3-epoxy sulfonamides.Gateway synthesis of daphnane congeners and their protein kinase C affinities and cell-growth activities.Crystal structure of (2-formyl-phenolato-κ(2) O,O')oxido(2-{[(2-oxidoeth-yl)imino]-meth-yl}phenolato-κ(3) O,N,O')vanadium(V)Studies on the regio- and diastereo-selective epoxidation of daphnanes and tiglianes.Synthesis of virtually enantiopure aminodiols with three adjacent stereogenic centers by epoxidation and ring-opening.Vanadium-catalyzed enantioselective desymmetrization of meso secondary allylic alcohols and homoallylic alcohols.Hf(IV)-catalyzed enantioselective epoxidation of N-alkenyl sulfonamides and N-tosyl iminesCombinatorial evolution of site- and enantioselective catalysts for polyene epoxidationSynthesis of enantiopure 1,2-azido and 1,2-amino alcohols via regio- and stereoselective ring-opening of enantiopure epoxides by sodium azide in hot water.Hydroxamic acids in asymmetric synthesis.Catalytic enantioselective epoxidation of tertiary allylic and homoallylic alcohols.Vanadium-catalyzed asymmetric epoxidation of homoallylic alcohols.Enantioselective epoxidation of nonconjugated cis-olefins by chiral dioxirane.Tungsten-catalyzed asymmetric epoxidation of allylic and homoallylic alcohols with hydrogen peroxide.Mg(II) -Catalyzed Desymmetrization Reaction of meso-Aziridines with Hydroxylamines: Synthesis of Novel Chiral 1,2-Diamine Skeletons.Concise stereocontrolled formal synthesis of (+/-)-quinine and total synthesis of (+/-)-7- hydroxyquinine via merged Morita-Baylis-Hillman-Tsuji-Trost cyclization.Catalytic asymmetric synthesis of CF3-substituted tertiary propargylic alcohols via direct aldol reaction of α-N3 amideBorane catalysed ring opening and closing cascades of furans leading to silicon functionalized synthetic intermediatesA Highly Selective Vanadium Catalyst for Benzylic C-H Oxidation.Regio- and stereoselective monoepoxidation of dienes using methyltrioxorhenium: synthesis of allylic epoxidesValidity of inorganic nanosheets as an efficient planar substituent to enhance the enantioselectivity of transition-metal-catalyzed asymmetric synthesis.Enzymatic cascades for the stereo-complementary epimerisation of in situ generated epoxy alcohols.Kinetic Resolution of Racemic Allylic Alcohols by Catalytic Asymmetric Substitution of the OH Group with Monosubstituted Hydrazines.α,β-Unsaturated Amides as Dipolarophiles: Catalytic Asymmetric exo-Selective 1,3-Dipolar Cycloaddition with Nitrones.On the role of thermal activation in selective photochemistry: mechanistic insight into the oxidation of propene on the V4O11- cluster.Total synthesis of (-)-ophiodilactone A and (-)-ophiodilactone B.
P2860
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P2860
Enantioselective epoxidation of allylic alcohols by a chiral complex of vanadium: an effective controller system and a rational mechanistic model.
description
2005 nî lūn-bûn
@nan
2005年の論文
@ja
2005年学术文章
@wuu
2005年学术文章
@zh
2005年学术文章
@zh-cn
2005年学术文章
@zh-hans
2005年学术文章
@zh-my
2005年学术文章
@zh-sg
2005年學術文章
@yue
2005年學術文章
@zh-hant
name
Enantioselective epoxidation o ...... a rational mechanistic model.
@en
Enantioselective epoxidation o ...... a rational mechanistic model.
@nl
type
label
Enantioselective epoxidation o ...... a rational mechanistic model.
@en
Enantioselective epoxidation o ...... a rational mechanistic model.
@nl
prefLabel
Enantioselective epoxidation o ...... a rational mechanistic model.
@en
Enantioselective epoxidation o ...... a rational mechanistic model.
@nl
P2093
P356
P1476
Enantioselective epoxidation o ...... d a rational mechanistic model
@en
P2093
Arindrajit Basak
Hisashi Yamamoto
Yuji Kosugi
P304
P356
10.1002/ANIE.200500938
P407
P577
2005-07-01T00:00:00Z