Thermodynamic control of asymmetric amplification in amino acid catalysis.
about
The origins of the RNA worldMineral surfaces, geochemical complexities, and the origins of lifeNMR spectroscopic detection of chirality and enantiopurity in referenced systems without formation of diastereomersOn the origin of terrestrial homochirality for nucleosides and amino acidsA route to enantiopure RNA precursors from nearly racemic starting materials.Enrichment of the amino acid L-isovaline by aqueous alteration on CI and CM meteorite parent bodiesSpontaneous transfer of chirality in an atropisomerically enriched two-axis system.L-amino acids catalyze the formation of an excess of D-glyceraldehyde, and thus of other D sugars, under credible prebiotic conditions.Extended high circular polarization in the Orion massive star forming region: implications for the origin of homochirality in the solar system.Expanding roles for diverse physical phenomena during the origin of life.The origin of biological homochirality.Kinetic isotope effects in asymmetric reactionsA cross-chiral RNA polymerase ribozymeAmplification of enantiomeric concentrations under credible prebiotic conditionsSupernovae, neutrinos and the chirality of amino acidsQuantum mechanical investigations of organocatalysis: mechanisms, reactivities, and selectivities.The direct catalytic asymmetric aldol reaction.Thermodynamic mechanism for solution phase chiral amplification via a lattice model.Solid-state-trapped reactive ammonium carbamate self-derivative salts of prolinamide.Kinetic trapping of metastable amino acid polymorphs.The role of natural selection in the origin of life.Exploring the role of chirality in nucleic acid recognition.Low-loading asymmetric organocatalysis.Processes to separate enantiomers.Enantioselective C-C bond formation as a result of the oriented prochirality of an achiral aldehyde at the single-crystal face upon treatment with a dialkyl zinc vapor.Chiral symmetry breaking in a microscopic model with asymmetric autocatalysis and inhibition.Caution in the Use of Nonlinear Effects as a Mechanistic Tool for Catalytic Enantioconvergent Reactions: Intrinsic Negative Nonlinear Effects in the Absence of Higher-Order Species.The basic reproductive ratio of life.Generation of absolute controlled crystal chirality by the removal of crystal water from achiral crystal of nucleobase cytosine.Chiral Sugars Drive Enantioenrichment in Prebiotic Amino Acid Synthesis.Inhabited or Uninhabited? Pitfalls in the Interpretation of Possible Chemical Signatures of Extraterrestrial Life.Emergence of single-molecular chirality from achiral reactants.Solution-phase racemization in the presence of an enantiopure solid phase.Propagation of biochirality: crossovers and nonclassical crystallization kinetics of aspartic acid in water.Catalysis of glyceraldehyde synthesis by primary or secondary amino acids under prebiotic conditions as a function of pH.Asymmetric amplification in the catalytic enantioselective 1,2-addition of Grignard reagents to enones.Selection of Amino Acid Chirality via Neutrino Interactions with (14)N in Crossed Electric and Magnetic Fields.Absolute asymmetric synthesis in enantioselective autocatalytic reaction networks: theoretical games, speculations on chemical evolution and perhaps a synthetic option."If pigs could fly" chemistry: a tutorial on the principle of microscopic reversibility.Prebiotic synthesis of 2-deoxy-d-ribose from interstellar building blocks promoted by amino esters or amino nitriles.
P2860
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P2860
Thermodynamic control of asymmetric amplification in amino acid catalysis.
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年学术文章
@wuu
2006年学术文章
@zh-cn
2006年学术文章
@zh-hans
2006年学术文章
@zh-my
2006年学术文章
@zh-sg
2006年學術文章
@yue
2006年學術文章
@zh
2006年學術文章
@zh-hant
name
Thermodynamic control of asymmetric amplification in amino acid catalysis.
@en
Thermodynamic control of asymmetric amplification in amino acid catalysis.
@nl
type
label
Thermodynamic control of asymmetric amplification in amino acid catalysis.
@en
Thermodynamic control of asymmetric amplification in amino acid catalysis.
@nl
prefLabel
Thermodynamic control of asymmetric amplification in amino acid catalysis.
@en
Thermodynamic control of asymmetric amplification in amino acid catalysis.
@nl
P2093
P2860
P356
P1433
P1476
Thermodynamic control of asymmetric amplification in amino acid catalysis.
@en
P2093
Alan Armstrong
David H Wells
Donna G Blackmond
Hiroshi Iwamura
Suju P Mathew
Urvish Pandya
P2860
P2888
P304
P356
10.1038/NATURE04780
P407
P577
2006-06-01T00:00:00Z
P5875
P6179
1036200117