Two interconvertible structures that explain the spectroscopic properties of the oxygen-evolving complex of photosystem II in the S2 state.
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Mn4Ca cluster in photosynthesis: where and how water is oxidized to dioxygenArtificial photosynthesis: understanding water splitting in natureUse of electron paramagnetic resonance to solve biochemical problemsNative structure of photosystem II at 1.95 Å resolution viewed by femtosecond X-ray pulsesPathway for Mn-cluster oxidation by tyrosine-Z in the S2 state of photosystem II.Hydration of the oxygen-evolving complex of photosystem II probed in the dark-stable S1 state using proton NMR dispersion profiles.Inorganic chemistry. A synthetic Mn₄Ca-cluster mimicking the oxygen-evolving center of photosynthesis.Structural changes in the oxygen-evolving complex of photosystem II induced by the S1 to S2 transition: A combined XRD and QM/MM studyAmmonia binding to the oxygen-evolving complex of photosystem II identifies the solvent-exchangeable oxygen bridge (μ-oxo) of the manganese tetramer.Ca K-edge XAS as a probe of calcium centers in complex systems.Photosynthesis. Electronic structure of the oxygen-evolving complex in photosystem II prior to O-O bond formation.Simulation of the isotropic EXAFS spectra for the S2 and S3 structures of the oxygen evolving complex in photosystem II.High-spin Mn-oxo complexes and their relevance to the oxygen-evolving complex within photosystem II.An Mn(V)-oxo role in splitting water?Resolving the Differences Between the 1.9 Å and 1.95 Å Crystal Structures of Photosystem II: A Single Proton Relocation Defines Two Tautomeric Forms of the Water-Oxidizing Complex.Structural rearrangements preceding dioxygen formation by the water oxidation complex of photosystem II.A Spotlight on the Compatibility between XFEL and Ab Initio Structures of the Oxygen Evolving Complex in Photosystem II.The open-cubane oxo-oxyl coupling mechanism dominates photosynthetic oxygen evolution: a comprehensive DFT investigation on O-O bond formation in the S4 state.Removal of Ca(2+) from the Oxygen-Evolving Complex in Photosystem II Has Minimal Effect on the Mn4O5 Core Structure: A Polarized Mn X-ray Absorption Spectroscopy Study.Structural changes of the oxygen-evolving complex in photosystem II during the catalytic cycle.Quantum mechanics/molecular mechanics simulation of the ligand vibrations of the water-oxidizing Mn4CaO5 cluster in photosystem II.The protonation states of oxo-bridged Mn(IV) dimers resolved by experimental and computational Mn K pre-edge X-ray absorption spectroscopy.The MOD-QM/MM Method: Applications to Studies of Photosystem II and DNA G-Quadruplexes.The S2 state of the oxygen-evolving complex of photosystem II explored by QM/MM dynamics: spin surfaces and metastable states suggest a reaction path towards the S3 state.Rationalizing the 2.25 Å Resolution Crystal Structure of the Water Oxidising Complex of Photosystem II in the S3 State.How does ammonia bind to the oxygen-evolving complex in the S2 state of photosynthetic water oxidation? Theoretical support and implications for the W1 substitution mechanism.Interaction of methanol with the oxygen-evolving complex: atomistic models, channel identification, species dependence, and mechanistic implications.Understanding and tuning the properties of redox-accumulating manganese helicates.Structural Changes Correlated with Magnetic Spin State Isomorphism in the S2 State of the Mn4CaO5 Cluster in the Oxygen-Evolving Complex of Photosystem II.Photosynthetic water oxidation: binding and activation of substrate waters for O-O bond formation.Toward models for the full oxygen-evolving complex of photosystem II by ligand coordination to lower the symmetry of the Mn3CaO4 cubane: demonstration that electronic effects facilitate binding of a fifth metal.Synthetic cluster models of biological and heterogeneous manganese catalysts for O2 evolutionSubstrate-water exchange in photosystem II is arrested before dioxygen formation.Proton Matrix ENDOR Studies on Ca2+-depleted and Sr2+-substituted Manganese Cluster in Photosystem II.A combined experimental and theoretical spectroscopic protocol for determination of the structure of heterogeneous catalysts: developing the information content of the resonance Raman spectra of M1 MoVO xStructure, ligands and substrate coordination of the oxygen-evolving complex of photosystem II in the S2 state: a combined EPR and DFT study.Pulse electron paramagnetic resonance studies of the interaction of methanol with the S2 state of the Mn4O5Ca cluster of photosystem II.Metal oxidation states in biological water splitting† †Electronic supplementary information (ESI) available: Additional methodological details and discussion, Tables S1–S10, Fig. S1–S16, spin populations, parameters of optimized structures, experimeMetal oxidation states in biological water splitting.Discovery of Open Cubane Core Structures for Biomimetic LnCo3 (OR)4 Water Oxidation Catalysts.
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Two interconvertible structures that explain the spectroscopic properties of the oxygen-evolving complex of photosystem II in the S2 state.
description
2012 nî lūn-bûn
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2012年の論文
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2012年学术文章
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2012年学术文章
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2012年学术文章
@zh-cn
2012年学术文章
@zh-hans
2012年学术文章
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2012年学术文章
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2012年學術文章
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2012年學術文章
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name
Two interconvertible structure ...... hotosystem II in the S2 state.
@en
Two interconvertible structure ...... hotosystem II in the S2 state.
@nl
type
label
Two interconvertible structure ...... hotosystem II in the S2 state.
@en
Two interconvertible structure ...... hotosystem II in the S2 state.
@nl
prefLabel
Two interconvertible structure ...... hotosystem II in the S2 state.
@en
Two interconvertible structure ...... hotosystem II in the S2 state.
@nl
P2860
P50
P356
P1476
Two interconvertible structure ...... hotosystem II in the S2 state.
@en
P2093
William Ames
P2860
P304
P356
10.1002/ANIE.201204705
P407
P577
2012-08-21T00:00:00Z