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Extending the Study of the 6,8 Rearrangement in Flavylium Compounds to Higher pH Values: Interconversion between 6-Bromo and 8-Bromo-apigeninidinIonic exchange in p-sulfonatocalix[4]arene-mediated formation of metal-ligand complexes.Excited-state proton transfer in confined medium. 4-methyl-7-hydroxyflavylium and β-naphthol incorporated in cucurbit[7]uril.Insights into the structure of the supramolecular amphiphile formed by a sulfonated calix[6]arene and alkyltrimethylammonium surfactants.Analogs of Natural 3-Deoxyanthocyanins: O-Glucosides of the 4',7-Dihydroxyflavylium Ion and the Deep Influence of Glycosidation on Color.A journey from calix[4]arene to calix[6] and calix[8]arene reveals more than a matter of size. Receptor concentration affects the stability and stoichiometric nature of the complexes.Effect of β-Cyclodextrin on the Multistate Species Distribution of 3-Methoxy-4',7-dihydroxyflavylium. Discrimination of the Two Hemiketal Enantiomers.Novel catanionic vesicles from calixarene and single-chain surfactant.Using calixarenes to model polyelectrolyte surfactant nucleation sites.Chemistry and Photochemistry of Anthocyanins and Related Compounds: A Thermodynamic and Kinetic Approach.Effect of Methyl, Hydroxyl, and Chloro Substituents in Position 3 of 3',4',7-Trihydroxyflavylium: Stability, Kinetics, and Thermodynamics.Novel catalytic effects in ester aminolysis in chlorobenzene.Spatiotemporal control over the co-conformational switching in pH-responsive flavylium-based multistate pseudorotaxanes.Mimicking Positive and Negative Copigmentation Effects in Anthocyanin Analogues by Host-Guest Interaction with Cucurbit[7]uril and β-Cyclodextrins.Characterization of kinetic and thermodynamic parameters of cyanidin-3-glucoside methyl and glucuronyl metabolite conjugates.Flavylium network of chemical reactions in confined media: modulation of 3',4',7-trihydroxyflavilium reactions by host-guest interactions with cucurbit[7]uril.Drug Delivery by Controlling a Supramolecular Host-Guest Assembly with a Reversible Photoswitch.p-Sulfonatocalix[6]arene-dodecyltrimethylammonium Supramolecular Amphiphilic System: Relationship between Calixarene and Micelle Concentration.Photocaged Competitor Guests: A General Approach Toward Light-Activated Cargo Release From Cucurbiturils.Counterion-Controlled Self-Sorting in an Amphiphilic Calixarene Micellar System.Photochromism of the natural dye 7,4'-dihydroxy-5-methoxyflavylium (dracoflavylium) in the presence of (2-hydroxypropyl)-β-cyclodextrin.Rationalizing the Color in Heavenly Blue Anthocyanin. A Complete Kinetic and Thermodynamic Study.Self-organization of photo-active nanostructures: general discussion.Competitive counterion complexation allows the true host : guest binding constants from a single titration by ionic receptors.Impact of Lignosulfonates on the Thermodynamic and Kinetic Parameters of Malvidin-3-O-glucoside in Aqueous SolutionsLight-induced cargo release from a cucurbit[8]uril host by means of a sequential logic operationNitric oxide release from a cucurbituril encapsulated NO-donorOn the multistate of 2′-hydroxyflavylium-flavanone system. Illustrating the concept of a timer with reset at the molecular levelpH-Gated photoresponsive shuttling in a water-soluble pseudorotaxaneContrasting pKa Shifts in Cucurbit[7]uril Host–Guest Complexes Governed by an Interplay of Hydrophobic Effects and Electrostatic InteractionsTerpenes Show Nanomolar Affinity and Selective Binding with Cucurbit[8]urilpH-Driven self-sorting in a four component host–guest systemInside Cover: Counterion-Controlled Self-Sorting in an Amphiphilic Calixarene Micellar System (Chem. Eur. J. 19/2016)A Multistate Molecular Switch Based on the 6,8-Rearrangement in Bromo-apigeninidin Operated with pH and Host–Guest InputsInside Back Cover: Drug Delivery by Controlling a Supramolecular Host-Guest Assembly with a Reversible Photoswitch (Chem. Eur. J. 43/2016)Exploring the charged nature of supramolecular micelles based on p-sulfonatocalix[6]arene and dodecyltrimethylammonium bromideFlavylium based dual photochromism: addressing cis–trans isomerization and ring opening-closure by different light inputsLight activated molecular machines and logic gates: general discussionγ-Cyclodextrin modulates the chemical reactivity by multiple complexationPhotochromism of the complex between 4′-(2-hydroxyethoxy)-7-hydroxyflavylium and β-cyclodextrin, studied by 1H NMR, UV–Vis, continuous irradiation and circular dichroism
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description
onderzoeker
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researcher
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հետազոտող
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name
Nuno Basílio
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Nuno Basílio
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Nuno Basílio
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Nuno Basílio
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Nuno Basílio
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Nuno Basílio
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Nuno Basílio
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Nuno Basílio
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Nuno Basílio
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P106
P1153
8667280600
P31
P496
0000-0002-0121-3695