Metal ion effect on the switch of mechanism from direct oxygen transfer to metal ion-coupled electron transfer in the sulfoxidation of thioanisoles by a non-heme iron(IV)-oxo complex.
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Strong Inhibition of O-Atom Transfer Reactivity for Mn(IV)(O)(π-Radical-Cation)(Lewis Acid) versus Mn(V)(O) Porphyrinoid ComplexesNon-redox metal ions can promote Wacker-type oxidations even better than copper(II): a new opportunity in catalyst design.Redox-inactive metal ions modulate the reactivity and oxygen release of mononuclear non-haem iron(III)-peroxo complexes.A Mononuclear Nonheme Iron(III)-Peroxo Complex Binding Redox-Inactive Metal IonsAlkali metal control over N-N cleavage in iron complexes.Tuning the Reactivity of Mononuclear Nonheme Manganese(IV)-Oxo Complexes by Triflic Acid.Spectroscopic capture and reactivity of a low-spin cobalt(IV)-oxo complex stabilized by binding redox-inactive metal ions.[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.Tuning the Redox Properties of a Nonheme Iron(III)-Peroxo Complex Binding Redox-Inactive Zinc Ions by Water Molecules.Sc3+-triggered oxoiron(IV) formation from O2 and its non-heme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate.Enhanced electron-transfer reactivity of nonheme manganese(IV)-oxo complexes by binding scandium ions.Mechanisms of metal ion-coupled electron transfer.The reactivity of the active metal oxo and hydroxo intermediates and their implications in oxidations.Mono- and binuclear non-heme iron chemistry from a theoretical perspective.Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes.Redox inactive metal ion triggered N-dealkylation by an iron catalyst with dioxygen activation: a lesson from lipoxygenases.Synthetic cluster models of biological and heterogeneous manganese catalysts for O2 evolutionCoordination site-dependent cation binding and multi-responsible redox properties of Janus-head metalloligand, [Mo(V)(1,2-mercaptophenolato)3].The effects of redox-inactive metal ions on the activation of dioxygen: isolation and characterization of a heterobimetallic complex containing a Mn(III)-(μ-OH)-Ca(II) core.Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size.Fine Control of the Redox Reactivity of a Nonheme Iron(III)-Peroxo Complex by Binding Redox-Inactive Metal Ions.Synergistic oxygen atom transfer by ruthenium complexes with non-redox metal ions.Non-redox metal ion promoted oxidative coupling of indoles with olefins by the palladium(ii) acetate catalyst through dioxygen activation: experimental results with DFT calculations.Halogen-Bonding-Assisted Iodosylbenzene Activation by a Homogenous Iron Catalyst.Redox-inactive metal ions promoted the catalytic reactivity of non-heme manganese complexes towards oxygen atom transfer.Metal- and additive-free oxygen-atom transfer reaction: an efficient and chemoselective oxidation of sulfides to sulfoxides with cyclic diacyl peroxides.Exceptionally Long-Lived Photodriven Multi-Electron Storage without Sacrificial Reagents.Photoinduced Electron Transfer in 9-Substituted 10-Methylacridinium Ions.Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates.Direct oxygen atom transfer versus electron transfer mechanisms in the phosphine oxidation by nonheme Mn(iv)-oxo complexes.Electron transfer and catalysis with high-valent metal-oxo complexes.Comparison of the reactivity of nonheme iron(IV)-oxo versus iron(IV)-imido complexes: which is the better oxidant?Incorporation of redox-inactive cations promotes iron catalyzed aerobic C-H oxidation at mild potentials.
P2860
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P2860
Metal ion effect on the switch of mechanism from direct oxygen transfer to metal ion-coupled electron transfer in the sulfoxidation of thioanisoles by a non-heme iron(IV)-oxo complex.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年学术文章
@wuu
2011年学术文章
@zh
2011年学术文章
@zh-cn
2011年学术文章
@zh-hans
2011年学术文章
@zh-my
2011年学术文章
@zh-sg
2011年學術文章
@yue
2011年學術文章
@zh-hant
name
Metal ion effect on the switch ...... hioanisoles by a non-heme iron
@nl
Metal ion effect on the switch ...... non-heme iron(IV)-oxo complex.
@en
type
label
Metal ion effect on the switch ...... hioanisoles by a non-heme iron
@nl
Metal ion effect on the switch ...... non-heme iron(IV)-oxo complex.
@en
prefLabel
Metal ion effect on the switch ...... hioanisoles by a non-heme iron
@nl
Metal ion effect on the switch ...... non-heme iron(IV)-oxo complex.
@en
P2093
P356
P1476
Metal ion effect on the switch ...... non-heme iron(IV)-oxo complex.
@en
P2093
Jiyun Park
Yong-Min Lee
Yuma Morimoto
P304
P356
10.1021/JA200901N
P407
P577
2011-03-16T00:00:00Z