Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding
about
Metal-ligand multiple bonding in uranium: structure and reactivity.Uranium-mediated activation of small molecules.Characterizing pressure-induced uranium C-H agostic bonds.Syntheses and structures of zirconium(IV) complexes supported by 2,6-di-adamantylaryloxide ligands and formation of arene-bridged dizirconium complexes with an inverse sandwich structure.Multi-electron reduction facilitated by a trianionic pyridine(diimine) ligand.Reductive assembly of cyclobutadienyl and diphosphacyclobutadienyl rings at uranium.Univalent transition metal complexes of arenes stabilized by a bulky terphenyl ligand: differences in the stability of Cr(I), Mn(I) or Fe(I) complexes.Group 3 metal stilbene complexes: synthesis, reactivity, and electronic structure studies.A triamido-uranium(V) inverse-sandwich 10π-toluene tetraanion arene complex.Distortions of π-coordinated arenes with anionic character.A six-carbon 10π-electron aromatic system supported by group 3 metals.Rare-earth metal π-complexes of reduced arenes, alkenes, and alkynes: bonding, electronic structure, and comparison with actinides and other electropositive metals.A delocalized arene-bridged diuranium single-molecule magnet.Evaluating f-element bonding from structure and thermodynamics.Molecular quadrangle formation from a diuranium μ-η6,η6-toluene complex.Harnessing redox activity for the formation of uranium tris(imido) compounds.Synthesis and reactions of beta-diketiminato divanadium(I) inverted-sandwich complexes.Theoretical treatment of one electron redox transformation of a small molecule using f-element complexes.Evidence for single metal two electron oxidative addition and reductive elimination at uranium.Reduction of a Cerium(III) Siloxide Complex To Afford a Quadruple-Decker Arene-Bridged Cerium(II) Sandwich.Reversible Cleavage/Formation of the Chromium-Chromium Quintuple Bond in the Highly Regioselective Alkyne Cyclotrimerization.Synthesis and Reduction of Uranium(V) Imido Complexes with Redox-Active Substituents.Molecular magnetism: uranium memory.The role of uranium-arene bonding in H2O reduction catalysis.Theoretical investigation of low-valent uranium and transuranium complexes of a flexible small-cavity macrocycle: structural, formation reaction and redox properties.A Mononuclear Uranium(IV) Single-Molecule Magnet with an Azobenzene Radical Ligand.Synthesis of titanium and zirconium complexes supported by a p-terphenoxide ligand and their reactions with N2, CO2 and CS2.Electron localization in a mixed-valence diniobium benzene complex.Isolation of +2 rare earth metal ions with three anionic carbocyclic rings: bimetallic bis(cyclopentadienyl) reduced arene complexes of La2+ and Ce2+ are four electron reductants.Synthesis and Characterization of a Uranium(II) Monoarene Complex Supported byδ BackbondingCoordination and Redox Isomerization in the Reduction of a Uranium(III) Monoarene Complex
P2860
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P2860
Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding
description
im Juni 2000 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована в червні 2000
@uk
name
Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding
@en
Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding
@nl
type
label
Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding
@en
Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding
@nl
prefLabel
Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding
@en
Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding
@nl
P2093
P356
P1476
Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding
@en
P2093
Christopher C. Cummins
Daniel J. Mindiola
Paula L. Diaconescu
Thomas A. Baker
P304
P356
10.1021/JA994484E
P407
P50
P577
2000-06-01T00:00:00Z