about
Direct functionalization of unactivated C-H bonds catalyzed by group 3-5 metal alkyl complexes.C-H bond activation by f-block complexes.Iron-Catalyzed C-H Functionalization Processes.Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations.The unusual hydridicity of a cobalt bound Si-H moiety.Generation of low-valent tantalum species by reversible C-H activation in a cyclometallated tantalum hydride complex.Metal-Ligand Cooperativity in a Methandiide-Derived Iridium Carbene Complex.Computational insights into carbon-carbon homocoupling reactions mediated by organolanthanide(III) complexes.Terminal phosphanido rhodium complexes mediating catalytic P-P and P-C bond formation.Mechanism of the cooperative Si-H bond activation at Ru-S bonds.Regioselective addition of C(sp3)-H bonds of alkyl pyridines to olefins catalysed by cationic zirconium complexes.Competition of Nucleophilic Aromatic Substitution, σ-Bond Metathesis, and syn Hydrometalation in Titanium(III)-Catalyzed Hydrodefluorination of Arenes.Evidence for Iron-Catalyzed α-Phosphinidene Elimination with Phenylphosphine.C(sp(3) )-H Oxidative Addition and Transfer Hydrogenation Chemistry of a Titanium(II) Synthon: Mimicry of Late-Metal Type Reactivity.Calcium Hydride Cation [CaH]+ Stabilized by an NNNN-type Macrocyclic Ligand: A Selective Catalyst for Olefin Hydrogenation.Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes.The atomic level mechanism of white phosphorous demolition by di-iodine.Metal-free σ-bond metathesis in 1,3,2-diazaphospholene-catalyzed hydroboration of carbonyl compounds.N-Heterocyclic Carbene-Ytterbium Amide as a Recyclable Homogeneous Precatalyst for Hydrophosphination of Alkenes and Alkynes.Addition of dihydrogen to a borylborenium center.Formation of macrocyclic ring systems by carbonylation of trifunctional P/B/B frustrated Lewis pairs.
P2860
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P2860
description
im September 2013 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована у вересні 2013
@uk
name
σ-Bond Metathesis: A 30-Year Retrospective
@en
σ-Bond Metathesis: A 30-Year Retrospective
@nl
type
label
σ-Bond Metathesis: A 30-Year Retrospective
@en
σ-Bond Metathesis: A 30-Year Retrospective
@nl
prefLabel
σ-Bond Metathesis: A 30-Year Retrospective
@en
σ-Bond Metathesis: A 30-Year Retrospective
@nl
P356
P1433
P1476
σ-Bond Metathesis: A 30-Year Retrospective
@en
P304
P356
10.1021/OM400760K
P577
2013-09-30T00:00:00Z