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Refitted tetrahedral covalent radii for solidsA suggested periodic table up to Z ≤ 172, based on Dirac–Fock calculations on atoms and ionsQuadruple bonding in C2 and analogous eight-valence electron speciesThe significance of ionic bonding in sulfur dioxide: bond orders from X-ray diffraction data.Mechanisms of phosphine toxicity.Optical spectra of the silicon-terminated carbon chain radicals SiCnH (n = 3,4,5).Re-evaluation of the bond length-bond strength rule: The stronger bond is not always the shorter bond.Probing the Origin of Challenge of Realizing Metallaphosphabenzenes: Unfavorable 1,2-Migration in Metallapyridines Becomes Feasible in Metallaphosphabenzenes.New perspectives for "non-classical" molecules: heavy [1.1.1]propellanes of group 14.Polyimido sulfur anions and ylides.Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials.Group 14 inorganic hydrocarbon analogues.Saturated Heavier Group 14 Compounds as σ -Electron-Acceptor (Z-Type) Ligands.Reductive Insertion of Elemental Chalcogens into Boron-Boron Multiple Bonds.A spectroscopic case for SPSi detection: The third-row in a single molecule.Phosphorus-Containing Polycyclic Aromatic Hydrocarbons.Energetics, structure, and rovibrational spectroscopic properties of the sulfurous anions SNO(-) and OSN(.).Exploring hypervalency and three-centre, four-electron bonding interactions: reactions of acenaphthene chalcogen donors and dihalogen acceptors.Heavy atom nitroxyl radicals. I: An ab initio study of the ground and lower electronic excited states of the H(2)As=O free radical.A mechanistic analysis of the tetrasilyl-substituted trimetallaallenes, >E=E=E< (E = C, Si, Ge, Sn, and Pb).The essential role of charge-shift bonding in hypervalent prototype XeF₂.Characterization of the HSiN_HNSi system in its electronic ground state.Variationally determined electronic states for the theoretical analysis of intramolecular interaction. II. Qualitative nature of the P-O bond in phosphine oxides.Synthesis and characterization of a digermanium analogue of an alkyne.Two faces of triel bonds in boron trihalide complexes.Substituent Effects on the Stability of Thallium and Phosphorus Triple Bonds: A Density Functional Study.Diversity of Chemical Bonding and Oxidation States in MS4 Molecules of Group 8 Elements.Bonding trends across the series of tricarbonato-actinyl anions [(AnO2)(CO3)3]4- (An = U-Cm): the plutonium turn.Carbones as Ligands in Novel Main-Group Compounds E[C(NHC)2 ]2 (E=Be, B+ , C2+ , N3+ , Mg, Al+ , Si2+ , P3+ ): A Theoretical Study.Exploring the role of the 3-center-4-electron bond in hypervalent λ(3)-iodanes using the methodology of domain averaged Fermi holes.Ternary B2X2H2 (X = O and S) rhombic clusters and their potential use as inorganic ligands in sandwich-type (B2X2H2)2Ni complexes.Chalcogen-bonded complexes. Selenium-bound adducts of NH3, H2O, PH3, and H2S with OCSe, SCSe, and CSe2.A valence bond model for electron-rich hypervalent species: application to SFn (n=1, 2, 4), PF5 , and ClF3.Triple Bonds Between Iron and Heavier Group 15 Elements in AFe(CO)3- (A=As, Sb, Bi) Complexes.Topology vs. thermodynamics in chemical reactions: the instability of PH5.Planar lithium silolide: aromaticity, with significant contribution of non-classical resonance structures.Mapping the Trajectory of Nucleophilic Substitution at Silicon Using a peri-Substituted Acenaphthyl Scaffold.The effect of substituents on triply bonded boron[triple bond, length as m-dash]antimony molecules: a theoretical approach.The effect of substituents on the stability of triply bonded gallium[triple bond, length as m-dash]antimony molecules: a new target for synthesis.Highly Bent 1,3-Digerma-2-silaallene.
P2860
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P2860
description
wetenschappelijk artikel
@nl
наукова стаття, опублікована у квітні 1984
@uk
name
Chemical Bonding in Higher Main Group Elements
@en
Chemical Bonding in Higher Main Group Elements
@nl
type
label
Chemical Bonding in Higher Main Group Elements
@en
Chemical Bonding in Higher Main Group Elements
@nl
prefLabel
Chemical Bonding in Higher Main Group Elements
@en
Chemical Bonding in Higher Main Group Elements
@nl
P356
P1476
Chemical Bonding in Higher Main Group Elements
@en
P2093
Werner Kutzelnigg
P304
P356
10.1002/ANIE.198402721
P407
P577
1984-04-01T00:00:00Z