Cyanohydrins in Nature and the Laboratory: Biology, Preparations, and Synthetic Applications
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Comparative analysis of tertiary alcohol esterase activity in bacterial strains isolated from enrichment cultures and from screening strain libraries.Substrate specificity of mutants of the hydroxynitrile lyase from Manihot esculenta.Enantioselective synthesis of tertiary α-hydroxy phosphonates catalyzed by carbohydrate/cinchona alkaloid thiourea organocatalysts.Chiral imine copper chloride-catalyzed enantioselective desymmetrization of 2-substituted 1,2,3-propanetriols.Effect of carbonates/phosphates as nucleophilic catalysts in dimethylformamide for efficient cyanosilylation of aldehydes and ketones.Structural study-guided development of versatile phase-transfer catalysts for asymmetric conjugate additions of cyanide.1-Ethyl-3-methylimidazolium acetate as a highly efficient organocatalyst for cyanosilylation of carbonyl compounds with trimethylsilyl cyanide.Recent developments and perspectives in palladium-catalyzed cyanation of aryl halides: synthesis of benzonitriles.Modern Approaches to Discovering New Hydroxynitrile Lyases for Biocatalysis.A catalytic chemodosimetric approach for detection of nanomolar cyanide ions in water, blood serum and live cell imaging.Elucidation of the mode of substrate binding to hydroxynitrile lyase from Hevea brasiliensis.Asymmetric counteranion-directed Lewis acid organocatalysis for the scalable cyanosilylation of aldehydes.Dialkylamino cyclopentadienyl ruthenium(ii) complex-catalyzed alpha-alkylation of arylacetonitriles with primary alcohols.Asymmetric cyanation of aldehydes, ketones, aldimines, and ketimines catalyzed by a versatile catalyst generated from cinchona alkaloid, achiral substituted 2,2'-biphenol and tetraisopropyl titanate.One-dimensional alignment of strong Lewis acid sites in a porous coordination polymer.Development of a process model to describe the synthesis of (R)-mandelonitrile by Prunus amygdalus hydroxynitrile lyase in an aqueous-organic biphasic reactor.The development of new monometallic bifunctional catalysts with Lewis acid and Lewis base properties, and their application in asymmetric cyanation reactions.Development of (R)-4-hydroxymandelonitrile synthesis in an aqueous-organic biphasic stirred tank batch reactor.Aluminum-catalyzed asymmetric addition of TMSCN to aromatic and aliphatic ketones promoted by an easily accessible and recyclable peptide ligand.Stereochemistry of intramolecular Diels-Alder furan (IMDAF) reactions of furyl-substituted chiral ethanolamides.Inversion of stereoselectivity by applying mutants of the hydroxynitrile lyase from Manihot esculenta.Unearthing the mechanism of prebiotic nitrile bond reduction in hydrogen cyanide through a curious association of two molecular radical anions.Chiral phenoxyimino-amido aluminum complexes for the asymmetric cyanation of aldehydes.An R-selective hydroxynitrile lyase from Arabidopsis thaliana with an alpha/beta-hydrolase fold.Organocatalytic enantio- and diastereoselective cycloetherification via dynamic kinetic resolution of chiral cyanohydrins.Burning vegetation produces cyanohydrins that liberate cyanide and stimulate seed germination.Detection of metabolites of the new synthetic cannabinoid CUMYL-4CN-BINACA in authentic urine samples and human liver microsomes using high-resolution mass spectrometry.Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports.Highly Enantioselective α-Cyanation with 4-Acetylphenyl Cyanate.Enantioselective Cyanosilylation of Ketones with Lithium(I) Dicyanotrimethylsilicate(IV) Catalyzed by a Chiral Lithium(I) Phosphoryl Phenoxide.Oxidative radical 1,2-alkylarylation of alkenes with α-C(sp(3))-H bonds of acetonitriles involving 1,2-aryl migration.Controlled synthesis of high quality scandium-based nanocrystals as promising recyclable catalysts for silylcyanation reaction.Metal organic frameworks as catalysts in solvent-free or ionic liquid assisted conditionsLanthanide metal–organic frameworks containing a novel flexible ligand for luminescence sensing of small organic molecules and selective adsorptionPorous barium–organic frameworks with highly efficient catalytic capacity and fluorescence sensing abilityZinc(II) and Copper(II) Metal-Organic Frameworks Constructed from a Terphenyl-4,4′′-dicarboxylic Acid Derivative: Synthesis, Structure, and Catalytic Application in the Cyanosilylation of AldehydesSynthesis, structure and catalytic application of lead(ii) complexes in cyanosilylation reactionsHeating and separation using nanomagnet-functionalized metal–organic frameworksHydroxynitrile Lyase from Arabidopsis thaliana: Identification of Reaction Parameters for Enantiopure Cyanohydrin Synthesis by Pure and Immobilized CatalystRemarkable Acceleration of Benzimidazole Synthesis and Cyanosilylation Reactions in a Supramolecular Solid Catalyst
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Cyanohydrins in Nature and the Laboratory: Biology, Preparations, and Synthetic Applications
description
article
@en
im Dezember 1999 veröffentlichter wissenschaftlicher Artikel
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wetenschappelijk artikel
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наукова стаття, опублікована в грудні 1999
@uk
ലേഖനം
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name
Cyanohydrins in Nature and the ...... ns, and Synthetic Applications
@en
Cyanohydrins in Nature and the ...... ns, and Synthetic Applications
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type
label
Cyanohydrins in Nature and the ...... ns, and Synthetic Applications
@en
Cyanohydrins in Nature and the ...... ns, and Synthetic Applications
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prefLabel
Cyanohydrins in Nature and the ...... ns, and Synthetic Applications
@en
Cyanohydrins in Nature and the ...... ns, and Synthetic Applications
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P356
P1433
P1476
Cyanohydrins in Nature and the ...... ns, and Synthetic Applications
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P2093
Robert J. H. Gregory
P304
P356
10.1021/CR9902906
P577
1999-12-01T00:00:00Z