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Profile of William S. KnowlesSynthesis of a new class of chiral 1,5-diphosphanylferrocene ligands and their use in enantioselective hydrogenation.Highly modular P-OP ligands for asymmetric hydrogenation: synthesis, catalytic activity, and mechanism.Supramolecular catalysis beyond enzyme mimics."Black Swan events" in organic synthesis.Asymmetry on large scale: the roadmap to stereoselective processes.Asymmetric homogeneous hydrogenations at scale.Multidimensional steric parameters in the analysis of asymmetric catalytic reactions.Applications and stereoselective syntheses of P-chirogenic phosphorus compounds.Substrate structure-activity relationships guide rational engineering of modular polyketide synthase ketoreductases.Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis.Novel 1,4-diphosphanes with imidazolidin-2-one backbones as chiral ligands: highly enantioselective Rh-catalyzed hydrogenation of enamides.One-step synthesis of racemic α-amino acids from aldehydes, amine components, and gaseous CO2 by the aid of a bismetal reagent.From molecular complexes to complex metallic nanostructures--2H solid-state NMR studies of ruthenium-containing hydrogenation catalysts.Synthesis, characterization and reactivity of tetranuclear ruthenium hydrido clusters containing chiral phosphine ligands.Theoretical mechanism for selective catalysis of double hydrophosphination of terminal arylacetylenes by an iron complex.Nickel-catalyzed asymmetric hydrogenation of β-acylamino nitroolefins: an efficient approach to chiral amines.Pyrene-tagged carbohydrate-based mixed P/S ligand: spacer effect on the Rh(i)-catalyzed hydrogenation of methyl α-acetamidocinnamate.Automated Quantum Mechanical Predictions of Enantioselectivity in a Rhodium-Catalyzed Asymmetric Hydrogenation.Catalytic applications of small bite-angle diphosphorus ligands with single-atom linkers.Efficient cluster-based catalysts for asymmetric hydrogenation of α-unsaturated carboxylic acids.Pd-catalyzed enantiodivergent and regiospecific phospha-Michael addition of diphenylphosphine to 4-oxo-enamides: efficient access to chiral phosphinocarboxamides and their analogues.Copper-catalyzed α-amination of aliphatic aldehydes.Copper-catalyzed rearrangement of tertiary amines through oxidation of aliphatic C-H bonds in air or oxygen: direct synthesis of α-amino acetals.Chemoenzymatic synthesis of a mixed phosphine-phosphine oxide catalyst and its application to asymmetric allylation of aldehydes and hydrogenation of alkenes.Enantioselective synthesis of β-substituted chiral allylic amines via Rh-catalyzed asymmetric hydrogenation.A chiral 1,2-bisphospholane ligand with a novel structural motif: applications in highly enantioselective Rh-catalyzed hydrogenations.Organometallic Compounds and Homogeneous CatalysisHydrogenation in flow: Homogeneous and heterogeneous catalysis using Teflon AF-2400 to effect gas–liquid contact at elevated pressureCatalytic Hydrogenation Using Abnormal N-Heterocyclic Carbene Palladium Complexes: Catalytic Scope and Mechanistic InsightsSpectropolarimetric Assay of R(-)-EpinephrineSpectropolarimetric Assay of DextroamphetamineSpectropolarimetric Assay of Codeine Tablets and Cocaine HydrochlorideRhodium-Catalysed Hydrogenations Using Monodentate Ligands
P2860
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P2860
description
article
@en
im März 1983 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована в березні 1983
@uk
ലേഖനം
@ml
name
Asymmetric hydrogenation
@en
Asymmetric hydrogenation
@nl
type
label
Asymmetric hydrogenation
@en
Asymmetric hydrogenation
@nl
prefLabel
Asymmetric hydrogenation
@en
Asymmetric hydrogenation
@nl
P356
P1476
Asymmetric hydrogenation
@en
P2093
William S. Knowles
P304
P356
10.1021/AR00087A006
P407
P577
1983-03-01T00:00:00Z