Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond
about
A tricyclic aromatic isomer of hexasilabenzene.Reversible reactions of ethylene with distannynes under ambient conditions.Bonding and structure of disilenes and related unsaturated group-14 element compounds.Chemical tricks to stabilize silanones and their heavier homologues with E=O bonds (E=Si-Pb): from elusive species to isolable building blocks.Group 14 inorganic hydrocarbon analogues.Cycloaddition of carbonyl compounds and alkynes to (di)silenes and (di)germenes: reactivity and mechanism.Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements.Reactivity of the Sterically Demanding Siloxanediol Mes2Si(OH)(µ-O)Si(OH)Mes2 Towards Water and Ether Molecules.Advances in Phosphasilene Chemistry.Experimental Observation of the Nature of Weak Chemical Bonds in Labile Compounds.SiCNN--a new stable isomer with Si(triple bond)C triple bonding.Reversible, complete cleavage of Si=Si double bonds by isocyanide insertion.Distinct stepwise reduction of a nickel-nickel-bonded compound containing an α-diimine ligand: from perpendicular to coaxial structures.A mechanistic analysis of the tetrasilyl-substituted trimetallaallenes, >E=E=E< (E = C, Si, Ge, Sn, and Pb).An experimental charge density study of two isomers of hexasilabenzene.Embryonic exposure to exogenous alpha- and gamma-tocopherol partially attenuates ethanol-induced changes in brain morphology and brain membrane fatty acid composition.New Pb-Pb bonds: syntheses and molecular structures of hexabiphenyldiplumbane and tri(trisbiphenylplumbyl)plumbate.Reduction of the dihalocyclopentasilanes. A quest for a homocyclic silylene.Activation of olefins with low-valent gallium compounds under ambient conditions.Brook silenes: inspiration for a generation.Reactions of heavier main-group compounds with hydrogen, ammonia, ethylene and related small molecules.A stable silicon(0) compound with a Si=Si double bond.A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural characterization of a silylsilylene.Doubly bonded systems between heavier Group 15 elements.Boron radical cations from the facile oxidation of electron-rich diborenes.Molecular tailoring: a possible synthetic route to hexasilabenzene.A Disilene Base Adduct with a Dative Si-Si Single Bond.Diverse Reactivity of an Electrophilic Phosphasilene towards Anionic Nucleophiles: Substitution or Metal-Amino Exchange.Resveratrol can only partially attenuate ethanol-induced oxidative stress in embryonic chick brains.Strait Gate: Special Issue on Advances in Silicon Chemistry.π-Electron systems containing Si=Si double bonds.Base-stabilized diborenes: selective generation and η2 side-on coordination to silver(I).Theoretical Study on the Second Hyperpolarizailities of Oligomeric Systems Composed of Carbon and Silicon π-Structures.Exploiting Electrostatics To Generate Unsaturation: Oxidative Ge=E Bond Formation Using a Non π-Donor Stabilized [R(L)Ge:](+) Cation.Diverse coordination modes in tin analogues of a cyclopentadienyl anion depending on the substituents on the tin atom.Parent heavy methylenes: chemical tricks to access isolable complexes of elusive H2E: species (E=Ge and Sn).Transition-Metal-Mediated Cleavage of a Si=Si Double Bond.Using N-Heterocyclic Vinyl Ligands to Access Stable Divinylgermylenes and a Germylium Cation.All-metallagermoxane with an adamantanoid cage structure: [(Cp*Ru(CO)2Ge)4(μ-O)6] (Cp* = η5-C5Me5)NHC-stabilized silagermenylidene: a heavier analogue of vinylidene.
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Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond
description
article publié dans la revue scientifique Science
@fr
im Dezember 1981 veröffentlichter wissenschaftlicher Artikel
@de
scientific article published in Science
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wetenschappelijk artikel
@nl
наукова стаття, опублікована в грудні 1981
@uk
name
Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond
@en
Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond
@nl
type
label
Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond
@en
Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond
@nl
prefLabel
Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond
@en
Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond
@nl
P2093
P1433
P1476
Tetramesityldisilene, a Stable Compound Containing a Silicon-Silicon Double Bond
@en
P2093
P304
P356
10.1126/SCIENCE.214.4527.1343
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P577
1981-12-18T00:00:00Z