The combination of deconvolution and density functional theory for the mid-infrared vibrational spectra of stable and unstable rhodium carbonyl clusters
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Spectral renormalization for multi-component fourier transform infrared absorbance data: importance to multivariate calibration and quantitative exploratory chemometrics studies.Experimental Raman spectra of dilute and laser-light-sensitive [Rh(4)(CO)(9)(mu-CO)(3)] and [(mu(4)-eta(2)-3-hexyne)Rh(4)(CO)(8)(mu-CO)(2)]. Comparison with theoretically predicted spectra.Exploring between the extremes: conversion-dependent kinetics of phosphite-modified hydroformylation catalysis.Formation of supported rhodium clusters from mononuclear rhodium complexes controlled by the support and ligands on rhodium.Surface-mediated synthesis of dimeric rhodium catalysts on MgO: tracking changes in the nuclearity and ligand environment of the catalytically active sites by X-ray absorption and infrared spectroscopies.DFT computations support the σ-complex assisted metathesis (σ-CAM) mechanism for the 1,4-Rh shift of Cp*Rh(III)-(η(1)-β-styryl) complexes.
P2860
The combination of deconvolution and density functional theory for the mid-infrared vibrational spectra of stable and unstable rhodium carbonyl clusters
description
article
@en
im Mai 2006 veröffentlichter wissenschaftlicher Artikel
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wetenschappelijk artikel
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наукова стаття, опублікована в травні 2006
@uk
ലേഖനം
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name
The combination of deconvoluti ...... able rhodium carbonyl clusters
@en
The combination of deconvoluti ...... able rhodium carbonyl clusters
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type
label
The combination of deconvoluti ...... able rhodium carbonyl clusters
@en
The combination of deconvoluti ...... able rhodium carbonyl clusters
@nl
prefLabel
The combination of deconvoluti ...... able rhodium carbonyl clusters
@en
The combination of deconvoluti ...... able rhodium carbonyl clusters
@nl
P2093
P1476
The combination of deconvoluti ...... able rhodium carbonyl clusters
@en
P2093
Ayman D. Allian
Gulnara M. Kuramshina
Marc Garland
Mark Saeys
Yezhong Wang
P304
P356
10.1016/J.VIBSPEC.2006.01.013
P577
2006-05-01T00:00:00Z