[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2]+: a convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexes
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Interaction between anions and cationic metal complexes containing tridentate ligands with exo-C-H groups: complex stability and hydrogen bonding.C-C coupling of N-heterocycles at the fac-Re(CO)(3) fragment: synthesis of pyridylimidazole and bipyridine ligands.Enantioselective hydrogenations of arylalkenes mediated by [Ir(cod) (JM-Phos) ]+ complexes.Catalytic conversion of nitrogen to ammonia by an iron model complex.Agostic interaction and intramolecular proton transfer from the protonation of dihydrogen ortho metalated ruthenium complexes.Isomerization of the hydride complexes [HFe2(SR)2(PR3)(x)(CO)(6-x)]+ (x = 2, 3, 4) relevant to the active site models for the [FeFe]-hydrogenasesThe Synthesis, Characterization and Dehydrogenation of Sigma-Complexes of BN-Cyclohexanes.C-C and C-N Couplings Following Hydride Addition on Isocyanide Cyclopolyenyl Dimolybdenum Complexes to Give Tethered Aldimine and Aminocarbene Derivatives.N-Heterocyclic carbene adducts of the heavier group 15 tribromides. Normal to abnormal isomerism and bromide ion abstraction.Cationic rhenium(iii) complexes: synthesis, characterization, and reactivity for hydrosilylation of aldehydes.Protonation versus Oxonium Salt Formation: Basicity and Stability Tuning of Cyanoborate Anions.Catalytic enantioselective carboannulation with allylsilanes.Neutral thioether and selenoether macrocyclic coordination to Group 1 cations (Li-Cs) - synthesis, spectroscopic and structural properties.P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.Using Ylide Functionalization to Stabilize Boron Cations.Cyclopolymerization and copolymerization of functionalized 1,6-heptadienes catalyzed by Pd complexes: mechanism and application to physical-gel formation.Phase behaviour and conductivity study on multi-component mixtures for electrodeposition in supercritical fluids.Interaction between anions and molybdenum allyl dicarbonyl complexes of 1,4,7-trithiacyclononane.H(OEt2)2[P(1,2-O2C6Cl4)3]: synthesis, characterization, and application as a single-component initiator for the carbocationic polymerization of olefins.eta 6-Arene complexes of Ni(II), efficient catalysts for 1,3-butadiene and styrene polymerization.A five coordinate Pd(II) complex stable in solution and in the solid state.Heterolytic activation of dihydrogen by platinum and palladium complexes.Fe(iv) alkylidenes via protonation of Fe(ii) vinyl chelates and a comparative Mössbauer spectroscopic study.Synthesis of new copper(I) complexes with tris(2-pyridyl) ligands. Applications to carbene and nitrene transfer reactions.(CF3 )3 Au as a Highly Acidic Organogold(III) Fragment.Catalytic cross-coupling of diazo compounds with coinage metal-based catalysts: an experimental and theoretical study.C-H Bond activation and C-C bond formation in the reaction of 2,5-dimethylthiophene with TpMe2Ir compounds.Synthesis and characterization of thermally robust amidinato group 13 hydride complexes.Aza-macrocyclic complexes of the Group 1 cations - synthesis, structures and density functional theory study.Unique Group 1 cations stabilised by homoleptic neutral phosphine coordination.Highly stereoselective β-mannopyranosylation via the 1-α-glycosyloxy-isochromenylium-4-gold(I) intermediates.Cationic zinc organyls as precatalysts for hydroamination reactions.Expanded-ring N-heterocyclic carbenes for the stabilization of highly electrophilic gold(I) cations.Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2](-).Synthesis and characterization of β-triketimine cobalt complexes and their behaviour in the polymerization of 1,3-butadiene.Hydride transfer reactivity of tetrakis(trimethylphosphine)(hydrido)(nitrosyl)molybdenum(0).Modulating reactivity in iridium bis(N-heterocyclic carbene) complexes: influence of ring size on E-H bond activation chemistry.Catalytic (de)hydrogenation promoted by non-precious metals - Co, Fe and Mn: recent advances in an emerging field.Complexation Between (O-Methyl)6 -2,6-Helic[6]arene and Tertiary Ammonium Salts: Acid/Base- or Chloride-Ion-Responsive Host-Guest Systems and Synthesis of [2]Rotaxane.Catalytic Friedel-Crafts C-H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes.
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P2860
[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2]+: a convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexes
description
im November 1992 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована в листопаді 1992
@uk
name
[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2 ...... hilic organometallic complexes
@en
[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2 ...... hilic organometallic complexes
@nl
type
label
[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2 ...... hilic organometallic complexes
@en
[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2 ...... hilic organometallic complexes
@nl
prefLabel
[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2 ...... hilic organometallic complexes
@en
[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2 ...... hilic organometallic complexes
@nl
P2093
P356
P1433
P1476
[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2 ...... hilic organometallic complexes
@en
P2093
A. F. Volpe
M. Brookhart
P304
P356
10.1021/OM00059A071
P577
1992-11-01T00:00:00Z