Formal Synthesis of (−)-Aphanorphine Using Sequential Photomediated Radical Reactions of Dithiocarbamates
about
Carbamoyl radical-mediated synthesis and semipinacol rearrangement of β-lactam diols.Ethylene in organic synthesis: a new route to anticholenergic pyrrolidinoindolines, and other molecules with all carbon-quaternary centers via asymmetric hydrovinylation.Enantioconvergent synthesis of (+)-aphanorphine via asymmetric Pd-catalyzed alkene carboamination.Base-dependent stereodivergent intramolecular aza-Michael reaction: asymmetric synthesis of 1,3-disubstituted isoindolines.Endeavors to access molecular complexity: strategic use of free radicals in natural product synthesis.One-pot three-component route for the synthesis of S-trifluoromethyl dithiocarbamates using Togni's reagent.Synthesis of functionalized 5-substituted thiazolidine-2-thiones via adscititious xanthate-promoted radical cyclization of allyl(alkyl/aryl)dithiocarbamates.Dual-role of PtCl2 catalysis in the intramolecular cyclization of (hetero)aryl-allenes for the facile construction of substituted 2,3-dihydropyrroles and polyheterocyclic skeletons.
P2860
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P2860
Formal Synthesis of (−)-Aphanorphine Using Sequential Photomediated Radical Reactions of Dithiocarbamates
description
scientific article published on 01 January 2007
@en
наукова стаття, опублікована в липні 2007
@uk
name
Formal Synthesis of (−)-Aphano ...... Reactions of Dithiocarbamates
@en
type
label
Formal Synthesis of (−)-Aphano ...... Reactions of Dithiocarbamates
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prefLabel
Formal Synthesis of (−)-Aphano ...... Reactions of Dithiocarbamates
@en
P356
P1476
Formal synthesis of (-)-aphano ...... reactions of dithiocarbamates
@en
P2093
Emma J Welsh
P304
P356
10.1002/ANIE.200701055
P407
P577
2007-01-01T00:00:00Z