Metal Silylenes Generated by Double Silicon-Hydrogen Activation: Key Intermediates in the Rhodium-Catalyzed Hydrosilylation of Ketones
about
Concise methods for the synthesis of chiral polyoxazolines and their application in asymmetric hydrosilylationKinetic isotope effects in asymmetric reactionsApplication of a C2-symmetric copper carbenoid in the enantioselective hydrosilylation of dialkyl and aryl-alkyl ketones.Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations.Organometallic chemistry.Heteroleptic rhodium NHC complexes with pyridine-derived ligands: synthetic accessibility and reactivity towards oxygen.Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene.Is the R3 Si Moiety in Metal-Silyl Complexes a Z ligand? An Answer from the Interaction Energy.Origins of enantioselectivity in the chiral diphosphine-ligated CuH-catalyzed asymmetric hydrosilylation of ketones.Stereospecific synthesis and catalytic activity of L-histidylidene metal complexes.Dehydrogenation of formic acid by Ir-bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand.Effective Formylation of Amines with Carbon Dioxide and Diphenylsilane Catalyzed by Chelating bis(tzNHC) Rhodium Complexes.Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex.A Mechanistic Study of Direct Activation of Allylic Alcohols in Palladium Catalyzed Amination ReactionsPropagation and termination steps in Rh-mediated carbene polymerisation using diazomethaneMultiple Reaction Pathways in Rhodium-Catalyzed Hydrosilylations of KetonesSynthesis of Olefin-Oxazoline Ligands (OlefOx) by Rhodium(III)-Catalyzed Oxidative Olefination
P2860
Q33867988-26CA1B1D-69C4-4623-8BB6-C427590EF6A7Q34374723-82C48ACB-2D78-4DE8-B2E4-958D8D18E0DDQ35601957-ADA8C949-C31B-491C-B2C1-DB2617C8C16BQ38957956-CEB2E52D-B960-4DE4-B6E0-943C082BD0C5Q42379473-2665D21C-F255-483C-A17B-48593B707776Q46009581-716E9A15-E601-44FC-9D2F-4DDB5F26EA46Q46683720-9A197CD5-33ED-406C-82DE-333559DF3E24Q50213896-163DA876-1AD4-4DB4-A0E8-C7045AC3101AQ50507124-E065A026-1EB6-4DAB-90CE-B79DAD7BE5B8Q52739391-33593C7D-9D37-473A-8087-E48968F09030Q53237780-5C7254CA-2EE4-4A4E-B177-066C4A93D1B8Q53647599-1B455DC1-68ED-4058-8161-2E83250A8214Q54918516-AB58FF56-669B-4E5C-B9F6-77D76D1F4814Q56741660-23DAA3E9-33E1-40E9-A529-1A3C112226DBQ56743065-A406E495-D6AB-4402-BEE5-AF5FB0ED99EAQ57397443-73B1A3BF-E58C-466F-BD4A-942E01BF57C2Q57657288-6BDF6893-3E97-4E15-A729-128859F82C76
P2860
Metal Silylenes Generated by Double Silicon-Hydrogen Activation: Key Intermediates in the Rhodium-Catalyzed Hydrosilylation of Ketones
description
scientific article published on 01 January 2009
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована в січні 2009
@uk
name
Metal Silylenes Generated by D ...... zed Hydrosilylation of Ketones
@en
Metal Silylenes Generated by D ...... zed Hydrosilylation of Ketones
@nl
type
label
Metal Silylenes Generated by D ...... zed Hydrosilylation of Ketones
@en
Metal Silylenes Generated by D ...... zed Hydrosilylation of Ketones
@nl
prefLabel
Metal Silylenes Generated by D ...... zed Hydrosilylation of Ketones
@en
Metal Silylenes Generated by D ...... zed Hydrosilylation of Ketones
@nl
P2093
P356
P1476
Metal silylenes generated by d ...... zed hydrosilylation of ketones
@en
P2093
Christian Haferkemper
Lutz H Gade
Markus Finger
Peter Hofmann
Stéphane Bellemin-Laponnaz
P304
P356
10.1002/ANIE.200804993
P407
P577
2009-01-01T00:00:00Z