about
Heteroscorpionate magnesium alkyls bearing unprecedented apical σ-C(sp3)-mg bonds: heteroselective ring-opening polymerization of rac-lactide.Nitric oxide binding and photodelivery based on ruthenium(II) complexes of 4-arylazo-3,5-dimethylpyrazole.Guanidines: from classical approaches to efficient catalytic syntheses.Reactions of alkynes with phosphido niobocenes: a combined experimental and theoretical study.New achiral and chiral NNE heteroscorpionate ligands. Synthesis of homoleptic lithium complexes as well as halide and alkyl scandium and yttrium complexes.Synthesis, structures and ring-opening polymerization studies of new zinc chloride and amide complexes supported by amidinate heteroscorpionate ligands.Early-late heterobimetallic alkoxides as model systems for late-transition-metal catalysts supported on titania.Heteroscorpionate ligands based on bis(pyrazol-1-yl)methane: design and coordination chemistry.A pyrimidine thiolate Rh(I) complex: structure, bonding and one-dimensional interactions in solid and in solution.On the search for NNO-donor enantiopure scorpionate ligands and their coordination to group 4 metals.First complexes of scandium and yttrium with NNO and NNS heteroscorpionate ligands.Versatile scorpionates and new developments in the denticity changes of NNCp hybrid scorpionate/cyclopentadienyl ligands in Sc and Y compounds: from kappa1-Neta5-Cp to kappa2-NNeta5-Cp.One-Component Aluminum(heteroscorpionate) Catalysts for the Formation of Cyclic Carbonates from Epoxides and Carbon Dioxide.An Efficient and Versatile Lanthanum Heteroscorpionate Catalyst for Carbon Dioxide Fixation into Cyclic Carbonates.Mono- and binuclear chiral N,N,O-scorpionate zinc alkyls as efficient initiators for the ROP of rac-lactide.Synthesis of Cyclic Carbonates Catalysed by Aluminium Heteroscorpionate Complexes.Highly thermally stable and robust enantiopure zirconium NNN-scorpionates for the controlled ring-opening polymerization of rac-lactide.Advances in the chemistry of bis-cyclopentadienyl hydride derivatives of niobium and tantalumPreparation, X-ray crystal and electronic structure of the novel raft cluster [NbAuH2{C5H4(SiMe3)}2]3Amidinate Aluminium Complexes as Catalysts for Carbon Dioxide Fixation into Cyclic CarbonatesReactivity of a Super-Electron-Rich Olefin Derived from CyclamA ruthenium(II) complex with bis(3,5-dimethylpyrazol-1-yl)dithioacetate built layer-by-layer on silver and gold surfacesBuilding Layer-by-Layer a Bis(dithiocarbamato)copper(II) Complex on Au{111} SurfacesRuthenium Complexes of the Scorpionate Ligand Bis(3,5-dimethylpyrazol-1-yl)dithioacetate and the Effect of Nitric Oxide CoordinationInteraction of ruthenium(III) chloride with bis(3,5-dimethylpyrazol-1-yl)methane oxyanions, potential κ3-N,N,O scorpionatesSynthesis of new heteroscorpionate iridium(i) and iridium(iii) complexesSynthesis and Characterization of Palladium(II) Complexes with New Polydentate Nitrogen Ligands. Dynamic Behavior Involving Pd-N Bond Rupture. X-ray Molecular Structure of [{Pd(eta(3)-C(4)H(7))}(2)(Me-BPzTO)](4-MeC(6)H(4)SO(3)) [Me-BPzTO = 4,6-Bis(4An unprecedented hybrid scorpionate/cyclopentadienyl ligandNew complexes of zirconium(IV) and hafnium(IV) with heteroscorpionate ligands and the hydrolysis of such complexes to give a zirconium clusterPreparation of new monoanionic "scorpionate" ligands: synthesis and structural characterization of titanium(IV) complexes bearing this class of ligandChelating dialkoxide titanium complex: a versatile building block for the construction of heterometallic derivativesLithium, titanium, and zirconium complexes with novel amidinate scorpionate ligandsSynthesis and characterization of complexes containing Ti-O-Si moieties. Catalytic activity in olefin epoxidationA new titanium building block for early-late heterometallic complexes; preparation of a new tetrameric metallomacrocycle by self assemblyDesign of new heteroscorpionate ligands and their coordinative ability toward Group 4 transition metals; an efficient synthetic route to obtain enantiopure ligandsActivation of a CNXylyl ancillary ligand in the reaction of electron-deficient alkynes with a phosphido niobocene complexDirect synthesis of NNN-donor enantiopure scorpionate ligands by an efficient diastereoselective nucleophilic addition to iminesLigand-modification effects on the reactivity, solubility, and stability of organometallic tantalum complexes in waterLewis base character of the phosphorus atom in phosphanido-niobocene complexes. Synthesis of new early-early homo- and heterobimetallic entitiesHeteroscorpionate rare-earth initiators for the controlled ring-opening polymerization of cyclic esters
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Q30678520-8ACB3351-5993-471A-B006-732E4E684817Q31161142-D441797F-3881-4A0E-A7C3-89500148551FQ38195763-6812AD7C-95D3-43EE-B9A8-7F966996C35BQ43165811-2BB96E60-C36C-4459-A9E2-F0B61D3B5C7BQ43196993-DCCD3310-F406-46A9-BBE3-0CF200E47471Q43273275-8C4AC009-55C9-4DF9-B7DB-E9848B54C172Q44304096-FD761FBD-A5EA-4503-A17F-312308DE7FDEQ44977491-6A6FAEC6-D0E5-46C0-B819-AF9123AAE5EBQ45278975-0062BEBC-07F1-437B-A82B-A36F75850737Q46012443-C5219897-038C-4274-96A7-8F2AC6A978A9Q46602882-8AB13EEE-1483-47E9-9FB6-B06AC509E732Q46618701-658C0CBD-07AE-4740-AA64-E17A534D1621Q48214458-2B54CB6B-7395-4AA5-948F-DAFE90805A50Q48299695-E1D13D21-A3C4-4249-B3E5-A60AB80638F9Q50080044-EE4C390D-3F4E-4D0E-9F12-BEFADEE9A5BCQ50271251-F67EDD20-71CC-40E5-8F2E-87292A0387F5Q52659753-67F9065E-F3BE-47D8-BF77-26BEB1925ED9Q57362864-CD18876A-F488-4040-A6FD-3E672FB11B68Q57370608-4796B277-6D8A-4606-9594-FDDDAD9294BEQ59867741-7B36BA88-EC98-4619-9A66-B1CF708E515CQ60288463-94330C41-EE47-4A81-B312-97349A1DEE69Q60431494-CD686482-C3A2-4E82-94A6-A29A5F5C7639Q60431500-285AB904-26EF-42EA-9D4F-0D2E93C9DA4BQ60431519-5800D254-A2B7-41B3-BADB-CE5CD5E551A4Q60431532-B338C748-CC53-424A-9A8C-396E8E7562C8Q60668737-CF844598-7858-4E7F-B2F6-12D36A0C38ADQ74832607-75BF63F3-5972-4CAB-AA3D-4EAFB5243B13Q75399026-6A014D4F-DA18-4363-885B-7503AD8D8E3DQ76336403-003E9B7E-AEDD-4FFE-A601-0F36A8403BD8Q78297110-04D2458B-362C-408E-99FC-1D3D517B03CAQ79435544-A101AA2A-0B31-4DAD-BC78-9398778C6F5FQ79714263-7D8904D0-72D8-4F6E-A924-55228EB8A8A5Q79767414-C5124A09-E060-4D95-8534-88A0A89DA814Q79803624-F8EB9413-E146-4DEB-93D0-63E6076DC068Q80245092-4DA949CF-F0D0-4822-8B65-7A811390598FQ82830474-6E2900C7-A1A0-432C-AA60-C0B3F8BBF042Q83166387-4499EA74-17FE-41D9-942B-046F0B903D78Q83300840-608B3EE6-8588-4CD8-A402-538FC8EDEC28Q83379690-D3B545C0-91E1-4719-A3D5-27F9FEF7FA8FQ83586694-C837FB73-6330-4D4A-AD0B-FB3367A346D5
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description
onderzoeker
@nl
researcher ORCID ID = 0000-0002-2921-2184
@en
name
Antonio Otero
@ast
Antonio Otero
@en
Antonio Otero
@es
Antonio Otero
@nl
type
label
Antonio Otero
@ast
Antonio Otero
@en
Antonio Otero
@es
Antonio Otero
@nl
prefLabel
Antonio Otero
@ast
Antonio Otero
@en
Antonio Otero
@es
Antonio Otero
@nl
P106
P21
P31
P496
0000-0002-2921-2184