Biomimetic Total Synthesis of Cyanosporaside Aglycons from a Single Enediyne Precursor through Site-Selectivep-Benzyne Hydrochlorination

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Metal Free Bi(hetero)aryl Synthesis: A Benzyne Truce-Smiles Rearrangement Benzannulation of triynes to generate functionalized arenes by spontaneous incorporation of nucleophiles.

P2860

Q39845298-FD663D5D-90C2-408F-A4EC-C3E3C7792F51 Q53260903-C765BF6D-EC09-41E0-A64E-D33E2F56E486

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Biomimetic Total Synthesis of Cyanosporaside Aglycons from a Single Enediyne Precursor through Site-Selectivep-Benzyne Hydrochlorination

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article

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im Oktober 2014 veröffentlichter wissenschaftlicher Artikel

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наукова стаття, опублікована в жовтні 2014

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Biomimetic Total Synthesis of ...... ivep-Benzyne Hydrochlorination

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Biomimetic Total Synthesis of ...... ivep-Benzyne Hydrochlorination

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Biomimetic Total Synthesis of ...... ivep-Benzyne Hydrochlorination

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Biomimetic Total Synthesis of ...... ivep-Benzyne Hydrochlorination

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Ilya D. Gridnev

http://www.w3.org/2001/XMLSchema#string

Kei Yamada

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Martin J. Lear

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Masahiro Hirama

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Shuji Yamashita

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Takaya Yamaguchi

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Yujiro Hayashi

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Antitumor antibiotics: bleomycin, enediynes, and mitomycin

p-Benzyne. Generation as an intermediate in a thermal isomerization reaction and trapping evidence for the 1,4-benzenediyl structure

Cyanosporasides A and B, chloro- and cyano-cyclopenta[a]indene glycosides from the marine actinomycete "Salinispora pacifica".

Fijiolides A and B, inhibitors of TNF-alpha-induced NFkappaB activation, from a marine-derived sediment bacterium of the genus Nocardiopsis

Natural products: a continuing source of novel drug leads

Mechanisms of in situ activation for DNA-targeting antitumor agents.

Structures and comparative characterization of biosynthetic gene clusters for cyanosporasides, enediyne-derived natural products from marine actinomycetes.

The enediyne antibiotics.

Natural product synthesis: changes over time.

p-Benzyne derivatives that have exceptionally small singlet-triplet gaps and even a triplet ground state.

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14122-14126

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scholarly article

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10.1002/ANGE.201408416

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126

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2014-10-08T00:00:00Z

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Biomimetic Total Synthesis of Cyanosporaside Aglycons from a Single Enediyne Precursor through Site-Selectivep-Benzyne Hydrochlorination

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P2860

P2860

Biomimetic Total Synthesis of Cyanosporaside Aglycons from a Single Enediyne Precursor through Site-Selectivep-Benzyne Hydrochlorination

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P1476

P2093

P2860

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P1433

P1476

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P31

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P433

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