Enantioselective Cyclopropenation of Alkynes with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis
about
Regioselective synthesis of multisubstituted furans via metalloradical cyclization of alkynes with α-diazocarbonyls: construction of functionalized α-oligofurans.Substrate-dependent divergent outcomes from catalytic reactions of silyl-protected enol diazoacetates with nitrile oxides: azabicyclo[3.1.0]hexanes or 5-arylaminofuran-2(3H)-onesVinylogous reactivity of enol diazoacetates with donor-acceptor substituted hydrazones. Synthesis of substituted pyrazole derivatives.Dirhodium(II)-catalyzed formal [3+2+1]-annulation of azomethine imines with two molecules of a diazo ketone.Metalloradical approach to 2H-chromenes.Applications of Palladium-Catalyzed C-N Cross-Coupling Reactions.Metalloradical activation of α-formyldiazoacetates for the catalytic asymmetric radical cyclopropanation of alkenes.Enantioselective allylic alkylation of stereodefined polysubstituted copper enolates as an entry to acyclic quaternary carbon stereocentres.Chiral cyclopropenyl ketones: reactive and selective Diels-Alder dienophilesEfficient one-pot synthesis of 1-arylcycloprop-2-ene-1-carboxamides.Stereoselective Radical C-H Alkylation with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis.Modulable and highly diastereoselective carbometalations of cyclopropenes.Hypervalent iodine(III)-mediated cyclopropa(e)nation of alkenes/alkynes under mild conditions.Dual rhodium/copper catalysis: synthesis of benzo[b]fluorenes and 2-naphthalenylmethanones via de-diazotized cycloadditions.Direct Synthesis of Chiral Allenoates from the Asymmetric C-H Insertion of α-Diazoesters into Terminal Alkynes.Cyclopropenation of internal alkynylsilanes and diazoacetates catalyzed by copper(i) N-heterocyclic carbene complexes.Brook Rearrangement as a Trigger for the Ring Opening of Strained Carbocycles.Enantioselective Radical Cyclization for Construction of 5-Membered Ring Structures by Metalloradical C-H Alkylation.Iodine-catalyzed diazo activation to access radical reactivity.Enantioselective radical process for synthesis of chiral indolines by metalloradical alkylation of diverse C(sp3)-H bonds.Enzymatic construction of highly strained carbocycles
P2860
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P2860
Enantioselective Cyclopropenation of Alkynes with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis
description
im März 2011 veröffentlichter wissenschaftlicher Artikel
@de
scientific article published on 18 February 2011
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована в березні 2011
@uk
name
Enantioselective Cyclopropenat ...... stituted Diazo Reagents via Co
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Enantioselective Cyclopropenat ...... Based Metalloradical Catalysis
@en
type
label
Enantioselective Cyclopropenat ...... stituted Diazo Reagents via Co
@nl
Enantioselective Cyclopropenat ...... Based Metalloradical Catalysis
@en
prefLabel
Enantioselective Cyclopropenat ...... stituted Diazo Reagents via Co
@nl
Enantioselective Cyclopropenat ...... Based Metalloradical Catalysis
@en
P2093
P50
P356
P1476
Enantioselective cyclopropenat ...... based metalloradical catalysis
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P2093
P304
P356
10.1021/JA111334J
P407
P577
2011-02-18T00:00:00Z