Facile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene Ligand
about
New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules.The unusual hydridicity of a cobalt bound Si-H moiety.Crystal structure of tricarbon-yl(N-di-phenyl-phosphanyl-N,N'-diisopropyl-P-phenyl-phospho-nous di-amide-κ(2) P,P')cobalt(I) tetra-carbonyl-cobaltate(-I) toluene 0.25-solvate.Expanding the coordination chemistry of donor-stabilized group-14 metalenes.Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems.Silylene-Functionalized N-Heterocyclic Carbene (Si-NHC).Facile access to silicon-functionalized bis-silylene titanium(II) complexes.Bis(silylenyl)- and bis(germylenyl)-substituted ferrocenes: synthesis, structure, and catalytic applications of bidentate silicon(II)-cobalt complexes.Mixed valence η6-arene cobalt(I) and cobalt(II) compound.On the Reactivity of the Silylene PhC(NtBu)2SiNPh2toward Organic SubstratesMetal free and selective activation of one C–F bond in a bound CF3 groupA début for base stabilized monoalkylsilylenes
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P2860
Facile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene Ligand
description
article
@en
im Januar 2012 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована в січні 2012
@uk
name
Facile Access to Transition-Me ...... abilized Chlorosilylene Ligand
@en
Facile Access to Transition-Me ...... abilized Chlorosilylene Ligand
@nl
type
label
Facile Access to Transition-Me ...... abilized Chlorosilylene Ligand
@en
Facile Access to Transition-Me ...... abilized Chlorosilylene Ligand
@nl
prefLabel
Facile Access to Transition-Me ...... abilized Chlorosilylene Ligand
@en
Facile Access to Transition-Me ...... abilized Chlorosilylene Ligand
@nl
P2860
P50
P356
P1476
Facile Access to Transition-Me ...... abilized Chlorosilylene Ligand
@en
P2093
Ramachandran Azhakar
P2860
P304
P356
10.1002/ASIA.201100722
P577
2012-01-13T00:00:00Z