about
The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters.Amidinatogermylene derivatives of ruthenium carbonyl: new insights into the reactivity of [Ru3(CO)12] with two-electron-donor reagents of high basicity.Reductive dimerization of triruthenium clusters containing cationic aromatic N-heterocyclic ligands.Formation of cyclopentadienyl and ruthenacyclopentadienyl derivatives through ynenyl-diyne and ynenyl-alkyne couplings onto a triruthenium cluster core.Expanding the coordination chemistry of donor-stabilized group-14 metalenes.Cationic heterocycles as ligands: synthesis and reactivity with anionic nucleophiles of cationic triruthenium clusters containing C-metalated N-methylquinoxalinium or N-methylpyrazinium ligands.Activation of two C-H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters.Deprotonation of C-alkyl groups of cationic triruthenium clusters containing cyclometalated C-alkylpyrazinium ligands: experimental and computational studies.QTAIM analysis of the bonding in Mo-Mo bonded dimolybdenum complexes.Octahedral manganese(i) and ruthenium(ii) complexes containing 2-(methylamido)pyridine-borane as a tripod κ3N,H,H-ligand.From a Diphosphanegermylene to Nickel, Palladium, and Platinum Complexes Containing Germyl PGeP Pincer Ligands.First Insertions of Carbene Ligands into Ge-N and Si-N Bonds.Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes.Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene.Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4, attempts to prepare the PSiP analogue, and the effect of the E atom on the molecular structures of E(NCH2PtBu2)2C6H4 (E = C, Si, Ge, Sn).Fully Borylated Methane and Ethane by Ruthenium-Mediated Cleavage and Coupling of CO.Theoretical topological analysis of the electron density in a series of triosmium carbonyl clusters: [Os3(CO)12], [Os3(μ-H)2(CO)10], [Os3(μ-H)(μ-OH)(CO)10], and [Os3(μ-H)(μ-Cl)(CO)10]Topological Analysis of the Electron Density in the N-Heterocyclic Carbene Triruthenium Cluster [Ru3(μ-H)2(μ3-MeImCH)(CO)9] (Me2Im = 1,3-dimethylimidazol-2-ylidene)Crystallographic report: [N,N′-Bis-(6-methylpyrid-2-ylium)-(1R,2R)-1,2-diaminocyclohexane] bis-[(p-cymene)- trichlororuthenate(II)]Dichlorobis[(S)-2,3,5,6-tetrahydro-6-phenylimidazo[2,1-b]thiazole]nickel(II)Triruthenium, Hexaruthenium, and Triosmium Carbonyl Derivatives of 2-Amino-6-phenylpyridine†Methylidyne–diyne coupling reactions onto a triruthenium cluster coreTriruthenium and triosmium carbonyl clusters containing chiral bidentate NHC-thiolate ligands derived from levamisoleReactions of mu3-alkenyl triruthenium carbonyl clusters with alkynes: synthesis of trinuclear mu-//-alkyne, mu-vinylidene, and mu-dienoyl derivativesHigh-nuclearity ruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine: synthesis of nonanuclear derivatives containing mu4- and mu5-oxo ligandsActivation of all bonds of a methyl group attached to an organic fragmentFrom an N-methyl N-heterocyclic carbene to carbyne and carbide ligands via multiple C-H and C-N bond activationsEasy activation of two C-H bonds of an N-heterocyclic carbene N-methyl groupA simple preparation of pyridine-derived N-heterocyclic carbenes and their transformation into bridging ligands by orthometalationSynthesis of mixed tin-ruthenium and tin-germanium-ruthenium carbonyl clusters from [Ru3(CO)12] and diaminometalenes (M = Sn, Ge)Triruthenium carbonyl clusters derived from chiral aminooxazolines: synthesis and catalytic activityDiaminogermylene and diaminostannylene derivatives of gold(I): novel AuM and AuM2 (M = Ge, Sn) complexesDeprotonation of C-alkyl groups of cationic N-heterocyclic ligandsReactions of phthalazine, quinazoline, 4,7-phenanthroline and 2,3'-bipyridine with ruthenium carbonylReactivity of diaminogermylenes with ruthenium carbonyl: Ru3Ge3 and RuGe2 derivativesSynthesis and reactivity of cationic triruthenium clusters derived from 2-methyl- and 4-methylpyrimidines: from conventional cyclometalated ligands to novel types of N-heterocyclic carbenesReactivity Studies on a Binuclear Ruthenium(0) Complex Equipped with a Bridging κ(2)N,Ge-Amidinatogermylene LigandConversion of a monodentate amidinate-germylene ligand into chelating imine-germanate ligands (on mononuclear manganese complexes)Ring opening and bidentate coordination of amidinate germylenes and silylenes on carbonyl dicobalt complexes: the importance of a slight difference in ligand volume2-(Methylamido)pyridine-Borane: A Tripod κ(3)-N,H,H Ligand in Trigonal Bipyramidal Rhodium(I) and Iridium(I) Complexes with an Asymmetric Coordination of Its BH3 Group
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description
researcher, ORCID id # 0000-0001-8563-9193
@en
wetenschapper
@nl
name
Javier A. Cabeza
@ast
Javier A. Cabeza
@en
Javier A. Cabeza
@es
Javier A. Cabeza
@nl
type
label
Javier A. Cabeza
@ast
Javier A. Cabeza
@en
Javier A. Cabeza
@es
Javier A. Cabeza
@nl
prefLabel
Javier A. Cabeza
@ast
Javier A. Cabeza
@en
Javier A. Cabeza
@es
Javier A. Cabeza
@nl
P106
P1153
7005402136
P21
P31
P496
0000-0001-8563-9193