about
The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters.Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc synergistic effects.Amidinatogermylene derivatives of ruthenium carbonyl: new insights into the reactivity of [Ru3(CO)12] with two-electron-donor reagents of high basicity.Direct C-H metalation with chromium(II) and iron(II): transition-metal host/benzenediide guest magnetic inverse-crown complexes.Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture.Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures.Diisopropylamide and TMP turbo-Grignard reagents: a structural rationale for their contrasting reactivities.cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?Expanding the coordination chemistry of donor-stabilized group-14 metalenes.Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone.Deprotonation of C-alkyl groups of cationic triruthenium clusters containing cyclometalated C-alkylpyrazinium ligands: experimental and computational studies.Octahedral manganese(i) and ruthenium(ii) complexes containing 2-(methylamido)pyridine-borane as a tripod κ3N,H,H-ligand.From a Diphosphanegermylene to Nickel, Palladium, and Platinum Complexes Containing Germyl PGeP Pincer Ligands.First Insertions of Carbene Ligands into Ge-N and Si-N Bonds.Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene.“LiZn(TMP)3”, a Zincate or a Turbo-Lithium Amide Reagent? DOSY NMR Spectroscopic EvidenceMolecular Structures of THF-Solvated Alkali-Metal 2,2,6,6-Tetramethylpiperidides Finally Revealed: X-ray Crystallographic, DFT, and NMR (including DOSY) Spectroscopic StudiesStructural insights into mono-amido tris-alkyl potassium aluminatesSynergic Synthesis of Benzannulated Zincabicyclic Complexes, α-Zincated N Ylides, through Sodium-TMEDA-Mediated Zincation of a HaloareneUnmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser BasesSynthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†Expanding Mg-Zn Hybrid Chemistry: Inorganic Salt Effects in Addition Reactions of Organozinc Reagents to Trifluoroacetophenone and the Implications for a Synergistic Lithium-Magnesium-Zinc ActivationShedding New Light on ZnCl2-Mediated Addition Reactions of Grignard Reagents to Ketones: Structural Authentication of Key Intermediates and Diffusion-Ordered NMR StudiesSynthesis and characterization of an infinite sheet of metal–alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiateHexaruthenium cluster complexes of basal edge-bridged square pyramidal metallic skeleton. First efficient synthesis and reactivity studiesHigh-nuclearity ruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine: synthesis of nonanuclear derivatives containing mu4- and mu5-oxo ligandsSynthesis of mixed tin-ruthenium and tin-germanium-ruthenium carbonyl clusters from [Ru3(CO)12] and diaminometalenes (M = Sn, Ge)Diaminogermylene and diaminostannylene derivatives of gold(I): novel AuM and AuM2 (M = Ge, Sn) complexesDeprotonation of C-alkyl groups of cationic N-heterocyclic ligandsSynthesis and structural chemistry of alkali metal tris(HMDS) magnesiates containing chiral diamine donor ligandsReactivity of diaminogermylenes with ruthenium carbonyl: Ru3Ge3 and RuGe2 derivativesSynthesis and reactivity of cationic triruthenium clusters derived from 2-methyl- and 4-methylpyrimidines: from conventional cyclometalated ligands to novel types of N-heterocyclic carbenesReactivity Studies on a Binuclear Ruthenium(0) Complex Equipped with a Bridging κ(2)N,Ge-Amidinatogermylene LigandConversion of a monodentate amidinate-germylene ligand into chelating imine-germanate ligands (on mononuclear manganese complexes)Ring opening and bidentate coordination of amidinate germylenes and silylenes on carbonyl dicobalt complexes: the importance of a slight difference in ligand volume2-(Methylamido)pyridine-Borane: A Tripod κ(3)-N,H,H Ligand in Trigonal Bipyramidal Rhodium(I) and Iridium(I) Complexes with an Asymmetric Coordination of Its BH3 GroupComplexity in seemingly simple sodium magnesiate systemsUnexpected Zwitterionic Allenyls from Silylenes and a Fischer Alkynylcarbene: A Remarkable Silylene-Promoted RearrangementTwo Types of σ-Allenyl Complexes from Reactions of Silylenes and Germylenes with Chromium Fischer Alkynyl(alkoxy)carbenesA Germylene Supported by Two 2-Pyrrolylphosphane Groups as Precursor to PGeP Pincer Square-Planar Group 10 Metal(II) and T-Shaped Gold(I) Complexes
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description
researcher, ORCID id # 0000-0002-5024-3874
@en
wetenschapper
@nl
name
Pablo García-Álvarez
@ast
Pablo García-Álvarez
@en
Pablo García-Álvarez
@nl
type
label
Pablo García-Álvarez
@ast
Pablo García-Álvarez
@en
Pablo García-Álvarez
@nl
prefLabel
Pablo García-Álvarez
@ast
Pablo García-Álvarez
@en
Pablo García-Álvarez
@nl
P106
P21
P31
P496
0000-0002-5024-3874