about
Templated deprotonative metalation of polyaryl systems: Facile access to simple, previously inaccessible multi-iodoarenes.Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates.Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone.Structural Studies of Cesium, Lithium/Cesium, and Sodium/Cesium Bis(trimethylsilyl)amide (HMDS) Complexes.Monodentate coordination of the normally chelating chiral diamine (R,R)-TMCDA.Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS).Revealing the remarkable structural diversity of the alkali metal transfer agents of the trans-calix[2]benzene[2]pyrrolide ligand.Alkali-Metal-Mediated Magnesiations of an N-Heterocyclic Carbene: Normal, Abnormal, and “Paranormal” Reactivity in a Single Tritopic MoleculeDirected ortho-meta'- and meta-meta'-dimetalations: A template base approach to deprotonationDehydromethylation of alkali metal salts of the utility amide 2,2,6,6-tetramethylpiperidide (TMP)Modulation of σ-Alkane Interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) Systems by Variation of the Chelating Phosphine and Alkane: Access to η2,η2-σ-Alkane Rh(I), η1-σ-Alkane Rh(III) Complexes, and Alkane EncapsulaDancing of palladacycles around a "juggler" 2,2-diacetyl-1,1-ethylenedithiolato ligand in a trinuclear Pd(II) complexSynthesis of a family of 3-alkyl- or 3-aryl-substituted 1,2-dihydroquinazolinium salts and their isomerization to 4-iminium-1,2,3,4-tetrahydroquinolinesSynthetic and Structural Studies of Mixed Sodium Bis(trimethylsilyl)amide/Sodium Halide Aggregates in the Presence of η(2)-N,N-, η(3)-N,N,N/N,O,N-, and η(4)-N,N,N,N-Donor LigandsThe role of neutral Rh(PONOP)H, free NMe2H, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)(η2-H2)]+ catalystReversible Encapsulation of Xenon and CH2 Cl2 in a Solid-State Molecular Organometallic Framework (Guest@SMOM)A d10 Ag(i) amine-borane σ-complex and comparison with a d8 Rh(i) analogue: structures on the η1 to η2:η2 continuumTolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymerStructural and metal-halogen exchange reactivity studies of sodium magnesiate biphenolate complexesSolvent-free anhydrous Li+, Na+ and K+ salts of [B(3,5-(CF3)2C6H3)4]-, [BArF4]-. Improved synthesis and solid-state structuresSi-C(sp3) bond activation through oxidative addition at a Rh(i) centreA Potent Halogen-Bonding Donor Motif for Anion Recognition and Anion Template Mechanical Bond SynthesisSelective mono- and dimetallation of a group 3 sandwich complexA Structurally Characterized Cobalt(I) σ-Alkane ComplexRoom Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes
P50
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P50
description
onderzoeker
@nl
researcher, ORCID id # 0000-0002-0684-1244
@en
name
Antonio J Martínez-Martínez
@ast
Antonio J Martínez-Martínez
@en
Antonio J Martínez-Martínez
@es
Antonio J Martínez-Martínez
@nl
type
label
Antonio J Martínez-Martínez
@ast
Antonio J Martínez-Martínez
@en
Antonio J Martínez-Martínez
@es
Antonio J Martínez-Martínez
@nl
prefLabel
Antonio J Martínez-Martínez
@ast
Antonio J Martínez-Martínez
@en
Antonio J Martínez-Martínez
@es
Antonio J Martínez-Martínez
@nl
P106
P21
P31
P496
0000-0002-0684-1244