about
Mechanistic insight into the CO2 capture by amidophosphoranes: interplay of the ring strain and the trans influence determines the reactivity of the frustrated Lewis pairs.Synthesis of aromatic aza-metallapentalenes from metallabenzene via sequential ring contraction/annulation.Aromaticity effects on the profiles of the lowest triplet-state potential-energy surfaces for rotation about the C=C bonds of olefins with five-membered ring substituents: an example of the impact of Baird's rule.Probing the Origin of Challenge of Realizing Metallaphosphabenzenes: Unfavorable 1,2-Migration in Metallapyridines Becomes Feasible in Metallaphosphabenzenes.Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliumsFacile η5-η1 ring slippage of the cycloolefin ligands in osmocene and bis(η5-indenyl)ruthenium(II).Synthesis of aromatic ruthenabenzothiophenes via C-H activation of thiophenes.Reactivity of Germylene toward Phosphorus-Containing Compounds: Nucleophilic Addition and Tautomerism.Mechanistic insight into the copper-catalyzed phosphorylation of terminal alkynes: a combined theoretical and experimental study.Multiyne chains chelating osmium via three metal-carbon σ bonds.Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity.Isolation of an 11-Atom Polydentate Carbon Chain Chelate via Cycloaddition of Cyclic Metal Carbyne with Alkynes.Probing the Most Aromatic and Antiaromatic Pyrrolium Rings by Maximizing Hyperconjugation and Push-Pull Effect.Synthesis of digermylene-stabilized linear tetraboronate and boroxine.σ Aromaticity Dominates in the Unsaturated Three-Membered Ring of Cyclopropametallapentalenes from Groups 7-9: A DFT Study.Unexpected higher stabilisation of two classical antiaromatic frameworks with a ruthenium fragment compared to the osmium counterpart: origin probed by DFT calculations.The Clar Structure in Inorganic BN Analogues of Polybenzenoid Hydrocarbons: Does it Exist or Not?Predicting an unconventional facile route to metallaanthracenes.Unexpected 1,2-migration in metallasilabenzenes: theoretical evidence for reluctance of silicon to participate in π bonding.The phosphaethynolate anion reacts with unsaturated bonds: DFT investigations into [2+2], [3+2] and [4+2] cycloadditions.Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of α-fluorophosphonates.Mechanism, reactivity, and selectivity in Rh(III)-catalyzed phosphoryl-directed oxidative C-H activation/cyclization: a DFT study.Double role of the hydroxy group of phosphoryl in palladium(II)-catalyzed ortho-olefination: a combined experimental and theoretical investigation.An isolable catenane consisting of two Möbius conjugated nanohoopsInsertion Reactions of Allenes with Palladium Aryl Complexes [PdI(Ph)(PPh3)]2and PdI(Ph)(dppe)A Metallanaphthalyne Complex from Zinc Reduction of a Vinylcarbyne ComplexLigand Effect on the Insertion Reactions of Allenes with MHCl(CO)(PPh3)3and MHCl(PPh3)3(M = Ru, Os)Understanding Nonplanarity in Metallabenzene ComplexesActivation of the S−S Bonds of Alkyl Disulfides RSSR (R = Me, Et, Pr, Bun) by Heterodinuclear Phosphido-Bridged CpW(CO)2(μ-PPh2)Mo(CO)5Osmabenzenes from the Reactions of a Dicationic Osmabenzyne ComplexReactions of [Cp*Ru(H2O)(NBD)]+with Dihydrogen, Silanes, Olefins, Alkynes, and AllenesTheoretical Investigation of Alkyne Metathesis Catalyzed by W/Mo Alkylidyne ComplexesInsertion Reactions of Allenes Giving Vinyl ComplexesRequirement for an Oxidant in Pd/Cu Co-Catalyzed Terminal Alkyne Homocoupling To Give Symmetrical 1,4-Disubstituted 1,3-DiynesTrans Influence of Boryl Ligands and Comparison with C, Si, and Sn LigandsReactions of Hydrotris(pyrazolyl)borate (Tp)-Supported Ruthenium Dihydrogen Complexes [TpRu(L2)(H2)]+(L2= dppm, dppp, (PPh3)2) with O2β-Hydrogen Elimination of Five-Membered-Ring Metallacycles. Is It Possible?An isotope (18O, 15N, and 2H) technique to investigate the metal ion interactions between the phosphoryl group and amino acid side chains by electrospray ionization mass spectrometrySilicon-containing formal 4π-electron four-membered ring systems: antiaromatic, aromatic, or nonaromatic?Conversions of osmabenzyne and isoosmabenzene
P50
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P50
description
onderzoeker
@nl
researcher ORCID ID = 0000-0002-2099-3156
@en
name
Jun Zhu
@ast
Jun Zhu
@en
Jun Zhu
@es
Jun Zhu
@nl
type
label
Jun Zhu
@ast
Jun Zhu
@en
Jun Zhu
@es
Jun Zhu
@nl
prefLabel
Jun Zhu
@ast
Jun Zhu
@en
Jun Zhu
@es
Jun Zhu
@nl
P106
P2456
P31
P496
0000-0002-2099-3156