about
Palladium-Catalyzed Synthesis of 2,3-Disubstituted Benzofurans: An Approach Towards the Synthesis of Deuterium Labeled Compounds.Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis.Mild silver-mediated geminal difluorination of styrenes using an air- and moisture-stable fluoroiodane reagent.Rhodium-Catalyzed Geminal Oxyfluorination and Oxytrifluoro-Methylation of Diazocarbonyl Compounds.Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine, and Oxetane Substrates: Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates.Palladium-catalyzed synthesis and isolation of functionalized allylboronic acids: selective, direct allylboration of ketones.Catalytic Intramolecular Aminofluorination, Oxyfluorination, and Carbofluorination with a Stable and Versatile Hypervalent Fluoroiodine Reagent.Fluorinative ring-opening of cyclopropanes by hypervalent iodine reagents. An efficient method for 1,3-oxyfluorination and 1,3-difluorination.Catalytic Asymmetric Allylboration of Indoles and Dihydroisoquinolines with Allylboronic Acids: Stereodivergent Synthesis of up to Three Contiguous Stereocenters.Regio- and stereoselective allylic trifluoromethylation and fluorination using CuCF3 and CuF reagents.Copper-mediated cyanotrifluoromethylation of styrenes using the Togni reagent.Palladium-catalyzed electrophilic substitution of allyl chlorides and acetates via bis-allylpalladium intermediates.Origin of the regio- and stereoselectivity in palladium-catalyzed electrophilic substitution via bis(allyl)palladium complexes.Palladium pincer complex-catalyzed trimethyltin substitution of functionalized propargylic substrates. An efficient route to propargyl- and allenyl-stannanes.Palladium pincer complex catalyzed stannyl and silyl transfer to propargylic substrates: synthetic scope and mechanism.Palladium pincer complex catalyzed cross-coupling of vinyl epoxides and aziridines with organoboronic acids.Palladium pincer complex catalyzed substitution of vinyl cyclopropanes, vinyl aziridines, and allyl acetates with tetrahydroxydiboron. An efficient route to functionalized allylboronic acids and potassium trifluoro(allyl)borates.Synthesis of Allenes by Catalytic Coupling of Propargyl Carbonates with Aryl Iodides in the Presence of Diboron Species.Catalytic performance of symmetrical and unsymmetrical sulfur-containing pincer complexes: synthesis and tandem catalytic activity of the first PCS-pincer palladium complex.Petasis Borono-Mannich reaction and allylation of carbonyl compounds via transient allyl boronates generated by palladium-catalyzed substitution of allyl alcohols. an efficient one-pot route to stereodefined alpha-amino acids and homoallyl alcohols.Efficient DBU accelerated synthesis of 18F-labelled trifluoroacetamides.Trifluoromethylthiolation-Based Bifunctionalization of Diazocarbonyl Compounds by Rhodium Catalysis.Copper-catalyzed synthesis of allenylboronic acids. Access to sterically encumbered homopropargylic alcohols and amines by propargylboration.Mechanisms of Rh-Catalyzed Oxyaminofluorination and Oxyaminotrifluoromethylthiolation of Diazocarbonyl Compounds with Electrophilic ReagentsCatalytic asymmetric propargyl- and allylboration of hydrazonoesters: a metal-free approach to sterically encumbered chiral α-amino acid derivativesMechanism and Stereoselectivity of the BINOL-Catalyzed Allylboration of SkatolesSynthesis of Benzyl-, Allyl-, and Allenyl-boronates via Copper-Catalyzed Borylation of AlcoholsPalladium-catalyzed tandem bis-allylation of isocyanatesPalladium-catalyzed electrophilic substitution via monoallylpalladium intermediatesPalladium-catalyzed coupling of allyl acetates with aldehyde and imine electrophiles in the presence of Bis(pinacolato)diboronRegioselective palladium-catalyzed electrophilic allylic substitution in the presence of hexamethylditinStereoselective Pincer-complex catalyzed C-H functionalization of benzyl nitriles under mild conditions. An efficient route to beta-aminonitrilesPalladium-catalyzed coupling of allylboronic acids with iodobenzenes. Selective formation of the branched allylic product in the absence of directing groupsRegio- and stereoselective palladium-pincer complex catalyzed allylation of sulfonylimines with trifluoro(allyl)borates and allylstannanes: a combined experimental and theoretical studyPalladium pincer complex-catalyzed allylic stannylation with hexaalkylditin reagentsPincer complex-catalyzed allylation of aldehyde and imine substrates via nucleophilic eta1-allyl palladium intermediatesFactors influencing the selectivity in asymmetric oxidation of sulfides attached to nitrogen containing heterocyclesSynthesis and catalytic application of chiral 1,1'-Bi-2-naphthol- and biphenanthrol-based pincer complexes: selective allylation of sulfonimines with allyl stannane and allyl trifluoroborateSelective one-pot carbon-carbon bond formation by catalytic boronation of unactivated cycloalkenes and subsequent couplingPalladium pincer-complex catalyzed allylation of tosylimines by potassium trifluoro(allyl)borates
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description
researcher
@en
wetenschapper
@nl
name
Kálmán J Szabó
@en
Kálmán J Szabó
@nl
type
label
Kálmán J Szabó
@en
Kálmán J Szabó
@nl
prefLabel
Kálmán J Szabó
@en
Kálmán J Szabó
@nl
P106
P31
P496
0000-0002-9349-7137